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Hydrazine, dihydrochloride

HCID 17548
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Basic informationNames & identifiersPropertiesSafety & regulationChemistry & industryRelated reactionsCompound notes
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Basic information

CAS
5341-61-7
Standard SMILES
Cl.Cl.NN
InChIKey
LIAWOTKNAVAKCX-UHFFFAOYSA-N
Molecular formula
Cl2H6N2
Average molar mass
104.96 g/mol
Monoisotopic mass
103.9908036

Names & identifiers

Preferred name
Hydrazine, dihydrochloride
IUPAC
hydrazine;dihydrochloride
English name
Hydrazine dihydrochloride
Molecular formula
Cl2H6N2
Molecular weight
104.97

Names & synonyms

Hydrazine dihydrochloride5341-61-7Hydrazine, dihydrochlorideHydrazine, hydrochloride (1:2)KM8DD9J0C8DTXSID9063798NSC-2122RefChem:146995DTXCID0041432226-283-2Hydrazine hydrochlorideHydrazine HCl
Show more names
Hydrazine2HClHydrazine dihydrochlHydrazinumDichlorideDiamine hydrochlorideHydrazine dihydrochloridDihydrazine Hydrochloride
hydrazine 2HClhydrazine;dihydrochlorideHydrazinium dichloridediamine dihydrochlorideMFCD00064543HYDRAZINE di HClNH2NH2 2HClCl2H6N2

Database identifiers

CAS
5341-61-7
PubChem CID
17548
DTXSID
DTXSID9063798
ChEMBL
CHEMBL542171
UNII
KM8DD9J0C8
EC Number
226-283-2

Properties

Computed structural properties

Topological polar surface area
52 Ų
Hydrogen bond donors
4
Hydrogen bond acceptors
2
Rotatable bonds
0
Heavy atoms
4
Formal charge
0
Complexity
0

Experimental & physicochemical properties

Chemical ClassesNitrogen Compounds -> Hydrazines
Density1.42 @25 °C
Physical DescriptionWhite solid; [Merck Index] White odorless crystals; [Alfa Aesar MSDS]

Physicochemical properties

Melting point
200 °C · 200 °C (dec.)(lit.)
Boiling point
200 °C · 200 °C
Density
1.42 g/mL · 1.42 g/mL at 25 °C(lit.)
bulk density
770 kg/m3 · 770kg/m3
Flash point
200 °C · 200°C
storage temp.
30 °C · Store below +30°C.
solubility
water: soluble(lit.)
form
white orthorhombic crystals
Specific Gravity
1.42 · 1.42
color
White crystalline
PH
0.5 · 0.5 (50g/l, H2O, 20℃)

Safety & regulation

Safety information is for reference only and does not replace the supplier’s Safety Data Sheet (SDS), applicable regulations, or professional assessment.

GHS classification

GHS Classification · 6 items

Danger

H301+H311+H331 (11.8%): Toxic if swallowed, in contact with skin or if inhaled [Danger Acute toxicity, oral; acute toxicity, dermal; acute toxicity, inhalation]

P203, P261, P262, P264, P270, P271, P272, P273, P280, P301+P316, P302+P352, P304+P340, P316, P318, P321, P330, P333+P317, P361+P364, P362+P364, P391, P403+P233, P405, and P501 (click each P-code to see the statement)

Aggregated GHS information provided per 17 reports by companies from 8 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.

Danger

H301: Toxic if swallowed [Danger Acute toxicity, oral]

Hazard information

Regulatory Information · 3 items

Chemical: Hydrazine, dihydrochloride

REACH registered substance: Hydrazine dihydrochloride (EC: 226-283-2)

Hydrazinium dichloride: Does not have an individual approval but may be used under an appropriate group standard

Other Safety InformationIMAP assessments - Hydrazine salts: Human health tier II assessment
Hazards Summary · 1 item

Causes other degenerative changes to brain, fatty liver degeneration, and other changes in urine in acute oral studies of rats; [RTECS] Toxic and corrosive; [Merck Index] Causes burns; Inhalation may cause corrosive injuries to upper respiratory tract and lungs; May cause skin sensitization; Highly toxic by ingestion, inhalation, and skin absorption; Possible carcinogen; [Alfa Aesar MSDS] See Hydrazine.

Hazard Classes and Categories · 2 items

Acute Tox. 3 (94.1%)

Acute toxicity - category 3

Safety & protection

Chemistry & industry

Pharmacology

MeSH Pharmacological Classification · 2 items

Substances that inhibit or prevent the proliferation of NEOPLASMS.

Substances that increase the risk of NEOPLASMS in humans or animals. Both genotoxic chemicals, which affect DNA directly, and nongenotoxic chemicals, which induce neoplasms by other mechanism, are included.

Uses & manufacturing

UsesUsed as a chlorine scavenger; [Merck Index]
General Manufacturing InformationHydrazine, hydrochloride (1:2): ACTIVE

Applications

UsesHydrazine dihydrochloride is used as chlorine scavenger in HCl gas streams.

Upstream & downstream products

Downstream products

3,6-DibromopyridazideEthyl 3-(trifluoromethyl)pyrazole-4-carboxylatePyridazine-3,6-diol6-Bromo-3-pyridazinamine

Related reactions

64 records
New reaction record
HRID 38133 reaction equation
HRID 38133As reactantuspto-grants-2013_09
HRID 217706 reaction equation
HRID 217706As reactantuspto-grants-2012_06
HRID 253223 reaction equation
HRID 253223As reactantuspto-grants-2011_01
HRID 253226 reaction equation
HRID 253226As reactantuspto-grants-2011_01
HRID 253243 reaction equation
HRID 253243As reactantuspto-grants-2011_01
HRID 253250 reaction equation
HRID 253250As reactantuspto-grants-2011_01
HRID 253257 reaction equation
HRID 253257As reactantuspto-grants-2011_01
HRID 253306 reaction equation
HRID 253306As reactantuspto-grants-2011_01
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Compound notes

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On this pageBasic informationNames & identifiersPropertiesSafety & regulationChemistry & industryRelated reactionsCompound notes
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Odor
Odorless
Water Solubility
SOLUBLE
Merck
14 · 14,4770
Stability
Stable. Incompatible with most common metals, organic materials, strong bases, strong oxidizing agents.
InChI
1S/2ClH.H4N2/c;;1-2/h2*1H;1-2H2
InChIKey
LIAWOTKNAVAKCX-UHFFFAOYSA-N
SMILES
Cl[H].Cl[H].NN
CAS DataBase Reference
5341 · 5341-61-7(CAS DataBase Reference)
FDA UNII
8 DD9J0C8 · KM8DD9J0C8
EPA Substance Registry System
Hydrazine, dihydrochloride (5341-61-7)
UNSPSC Code
12352301 · 12352301
NACRES
22 · NA.22
Symbol(GHS)
6 · GHS06,GHS08,GHS09
Signal word
Danger
Hazard statements
301 · H301+H311+H331-H317-H350-H410
Precautionary statements
201 · P201-P273-P280-P301+P310+P330-P302+P352+P312-P304+P340+P311
Hazard Codes
T,N
Risk Statements
45 · 45-23/24/25-43-50/53
Safety Statements
53 · 53-45-60-61
RIDADR
2811 · UN 2811 6.1/PG 3
WGK Germany
3 · 3
RTECS
2298000 · MV2298000
F
3 · 3-10-21
TSCA
TSCA listed
HS Code
2825 · 2825 10 00
HazardClass
6.1 · 6.1
PackingGroup
II
Storage Class
6.1 C · 6.1C - Combustible acute toxic Cat.3toxic compounds or compounds which causing chronic effects
Hazard Classifications
3 DermalAcute · Acute Tox. 3 DermalAcute Tox. 3 InhalationAcute Tox. 3 OralAquatic Acute 1Aquatic Chronic 1Carc. 1BSkin Sens. 1
Toxicity
50 orally · LD50 orally in Rabbit: 129 mg/kg LD50 dermal Rabbit 91 mg/kg
REACH Registrations
Inactive
Limited Quantities
5 L · 5.0 L (1.3 gallons) (liquid) or 5.0 kg (11 lbs) (solid)
Excepted Quantities
Max Inner Pack (30g or 30ml) and Max Outer Pack (1Kg or 1L)
Protective Action Criteria (PAC) · 3 items

0.10 [ppm]

13 [ppm]

35 [ppm]

Toxicology

Adverse EffectsNeurotoxin - Other CNS neurotoxin

Safety data

F
3-10-21
wgk
3
tsca
TSCA listed
rtecs
MV2298000
ridadr
UN 2811 6.1/PG 3
hs_code
2825 10 00
Toxicity
LD50 orally in Rabbit: 129 mg/kg LD50 dermal Rabbit 91 mg/kg
risk_code
45-23/24/25-43-50/53
Signal word
Danger
Symbol(GHS)
GHS06,GHS08,GHS09
hazard_code
T,N
safety_code
53-45-60-61
hazard_class
6.1
Storage Class
6.1C - Combustible acute toxic Cat.3toxic compounds or compounds which causing chronic effects
packing_group
II
Hazard statements
H301+H311+H331-H317-H350-H410
Limited Quantities
5.0 L (1.3 gallons) (liquid) or 5.0 kg (11 lbs) (solid)
Excepted Quantities
Max Inner Pack (30g or 30ml) and Max Outer Pack (1Kg or 1L)
REACH Registrations
Inactive
Hazard Classifications
Acute Tox. 3 DermalAcute Tox. 3 InhalationAcute Tox. 3 OralAquatic Acute 1Aquatic Chronic 1Carc. 1BSkin Sens. 1
Precautionary statements
P201-P273-P280-P301+P310+P330-P302+P352+P312-P304+P340+P311