CAS 139353-88-1 1-Butanaminium, N,N,N-tributyl-, (TB-5-11)-difluorotriphenylstannate(1-) (1:1) (HCID 178449042)

Names & identifiers

Preferred name: 1-Butanaminium, N,N,N-tributyl-, (TB-5-11)-difluorotriphenylstannate(1-) (1:1)
IUPAC: difluoro(triphenyl)stannanuide;tetrabutylazanium
English name: Tetrabutylammonium difluorotriphenylstannate
Molecular formula: C34H51F2NSn
Molecular weight: 630.48

Names & synonyms

1-Butanaminium, N,N,N-tributyl-, (TB-5-11)-difluorotriphenylstannate(1-) (1:1)RefChem:430811623-960-8139353-88-1Tetrabutylammonium difluorotriphenylstannateTetrabutylammonium difluorotriphenylstannate(IV)difluoro(triphenyl)stannanuide;tetrabutylazaniumMFCD00192465Tetrabutylammonium difluorotriphenyltinDTXSID00369785ODMXVCNGZGLSRS-UHFFFAOYSA-Ltetrabutylammonium triphenyldifluorotin

Show more names

TBAF-SNSKL1127Gingras'GINGRAS REAGENTTetrabutylammonium difluorotriphenylstaateTetrabutylammonium difluorotriphenylstannaneTETRABUTYLAMMONIUM TRIPHENYLDIFLUOROSTANNATE

AKOS015912125SY109499DB-042468tetrabutylam-monium triphenyldifluorostannatetetrabutylammonium difluorotriphenyl stannateTetrabutylammonium (difluorotriphenylstannate)tetra-n-butylammonium difluorotriphenylstannateTetrabutylammoniumdifluorotriphenylstannate(IV)

Database identifiers

CAS: 139353-88-1
PubChem CID: 2733194

Properties

Computed structural properties

Topological polar surface area: 0 Å²
Hydrogen bond donors: 0
Hydrogen bond acceptors: 3
Rotatable bonds: 15
Heavy atoms: 38
Formal charge: 0
Complexity: 401

Physicochemical properties

Melting point: 192 · 192-193 °C (lit.)
solubility: Soluble in most organic solvents.
form: solid
color: White to Almost white
Sensitive: Hygroscopic
BRN: 8668854 · 8668854
InChI: 1S/C16H36N.3C6H5.2FH.Sn/c1-5-9-13-17(14-10-6-2,15-11-7-3)16-12-8-4;3*1-2-4-6-5-3-1;;;/h5-16H2,1-4H3;3*1-5H;2*1H;/q+1;;;;;;+1/p-2
InChIKey: ODMXVCNGZGLSRS-UHFFFAOYSA-L
SMILES: CCCC[N+](CCCC)(CCCC)CCCC.F[Sn-](F)(c1ccccc1)(c2ccccc2)c3ccccc3
CAS DataBase Reference: 139353 · 139353-88-1(CAS DataBase Reference)
UNSPSC Code: 12352101 · 12352101
NACRES: 22 · NA.22
Symbol(GHS): 6 · GHS06,GHS09
Signal word: Danger
Hazard statements: 301 · H301+H311+H331-H410
Precautionary statements: 273 · P273-P280-P301+P310+P330-P302+P352+P312-P304+P340+P311
PPE: 95 · dust mask type N95 (US), Eyeshields, Faceshields, Gloves, type P2 (EN 143) respirator cartridges
Hazard Codes: T,N,Xi
Risk Statements: 23 · 23/24/25-50/53
Safety Statements: 26 · 26-27-28-45-60-61
RIDADR: 3146 · UN 3146 6.1/PG 3
WGK Germany: 3 · 3
F: 9 · 9-21
TSCA: No
HazardClass: 6.1 · 6.1
PackingGroup: III
HS Code: 29310099 · 29310099
Storage Class: 6.1 C · 6.1C - Combustible acute toxic Cat.3toxic compounds or compounds which causing chronic effects
Hazard Classifications: 3 DermalAcute · Acute Tox. 3 DermalAcute Tox. 3 InhalationAcute Tox. 3 OralAquatic Acute 1Aquatic Chronic 1

Safety & regulation

GHS classification

GHS Classification · 5 items

Danger

H301 (88.9%): Toxic if swallowed [Danger Acute toxicity, oral]；H311 (88.9%): Toxic in contact with skin [Danger Acute toxicity, dermal]；H331 (88.9%): Toxic if inhaled [Danger Acute toxicity, inhalation]；H400 (97.8%): Very toxic to aquatic life [Warning Hazardous to the aquatic environment, acute hazard]；H410 (97.8%): Very toxic to aquatic life with long lasting effects [Warning Hazardous to the aquatic environment, long-term hazard]

P261, P262, P264, P270, P271, P273, P280, P301+P316, P302+P352, P304+P340, P316, P321, P330, P361+P364, P391, P403+P233, P405, and P501 (click each P-code to see the statement)

Aggregated GHS information provided per 45 reports by companies from 5 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.；Information may vary between notifications depending on impurities, additives, and other factors. The percentage value in parenthesis indicates the notified classification ratio from companies that provide hazard codes. Only hazard codes with percentage values above 10% are shown. For more detailed information, please visit ECHA C&L website.

Hazard information

Hazard Classes and CategoriesAcute Tox. 3 (88.9%)；Acute Tox. 3 (88.9%)；Acute Tox. 3 (88.9%)；Aquatic Acute 1 (97.8%)；Aquatic Chronic 1 (97.8%)

Safety data

F: 9-21
PPE: dust mask type N95 (US), Eyeshields, Faceshields, Gloves, type P2 (EN 143) respirator cartridges
wgk: 3
tsca: No
ridadr: UN 3146 6.1/PG 3
hs_code: 29310099
risk_code: 23/24/25-50/53
Signal word: Danger
Symbol(GHS): GHS06,GHS09
hazard_code: T,N,Xi
safety_code: 26-27-28-45-60-61
hazard_class: 6.1
Storage Class: 6.1C - Combustible acute toxic Cat.3toxic compounds or compounds which causing chronic effects
packing_group: III
Hazard statements: H301+H311+H331-H410
Hazard Classifications: Acute Tox. 3 DermalAcute Tox. 3 InhalationAcute Tox. 3 OralAquatic Acute 1Aquatic Chronic 1
Precautionary statements: P273-P280-P301+P310+P330-P302+P352+P312-P304+P340+P311

Chemistry & industry

Applications · 1 item

UsesTetrabutylammonium difluorotriphenylstannate is an organometallic reagent used in the preparation of disilene fluoride adducts. Tetrabutylammonium difluorotriphenylstannate has inorganic applications as well, used as a source of carbon or fluorine ligands via hypercoordination.