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Pentaborane

HCID 178604530
NotesReactions
Basic informationNames & identifiersPropertiesSafety & regulationChemistry & industryRelated reactionsCompound notes
No structure available

Basic information

CAS
19624-22-7
Molecular formula
B5H9
Average molar mass
55.06 g/mol

Names & identifiers

Preferred name
Pentaborane
English name
Pentaborane
Molecular formula
B5H9
Molecular weight
55.06

Names & synonyms

pentaborane(9)Chebi:33591PentaboraneNido-pentaborane(9)2,3:2,5:3,4:4,5-Tetra-muh-nido-pentaborane(9)(2,3-Muh),(2,5-muh),(3,4-muh),(4,5-muh)-nido-pentaborane(9)

Database identifiers

CAS
19624-22-7

Properties

Physicochemical properties

Melting point
-46.6 ° · -46.6°
Boiling point
60 ° · bp 60°
Density
40 · d40 0.61
vapor density
2.2 · 2.2
solubility
2 O · reacts with hot H2O
form
flammable liquid
color
Colorless gas or liquid
Odor
bad odor
Water Solubility
88 · hydrolyzed if heated [COT88]
Specific Heat Capacity
2.74 J/ · Cp(liquid): 2.74 J/(g·K); Cp(gas): 1.81 J/(g·K), at 25℃
Dielectric constant
21 · 21.0(Ambient)
CAS DataBase Reference
19624 · 19624-22-7
EWG's Food Scores
1 · 1
FDA UNII
1 F0BN763J · P1F0BN763J
EPA Substance Registry System
Pentaborane (19624-22-7)
OEB
E
OEL
0.005 ppm · TWA: 0.005 ppm (0.01 mg/m3), STEL: 0.015 ppm (0.03 mg/m3)
RIDADR
1380 · UN 1380
TSCA
TSCA listed
HazardClass
4.2 · 4.2
PackingGroup
I
Hazardous Substances Data
19624 · 19624-22-7(Hazardous Substances Data)
Toxicity
50 ihl-rat: · LC50 ihl-rat: 6 ppm/4H AIHAAP 19,46,58
IDLA
1 ppm · 1 ppm

Safety & regulation

Safety information is for reference only and does not replace the supplier’s Safety Data Sheet (SDS), applicable regulations, or professional assessment.

Safety data

OEB
E
OEL
TWA: 0.005 ppm (0.01 mg/m3), STEL: 0.015 ppm (0.03 mg/m3)
IDLA
1 ppm
tsca
TSCA listed
ridadr
UN 1380
Toxicity
LC50 ihl-rat: 6 ppm/4H AIHAAP 19,46,58
hazard_class
4.2
packing_group
I
Hazardous Substances Data
19624-22-7(Hazardous Substances Data)

Chemistry & industry

Applications · 4 items

DescriptionPentaborane is a nonmetallic, colorless liquid with a pungent odor. It decomposes at 300°F (148°C), if it has not already ignited, and will ignite spontaneously in air if impure. It is a dangerous fire and explosion risk, with a flammable range of 0.46%–98% in air. Boiling point is 145°F (64°C), flash point is 86°F (30°C), and ignition temperature is 95°F (35°C), which is extremely low. Any object that is 95°F (35°C) or above can be an ignition source. Ignition sources can be ordinary objects on a hot day in the summer, such as the pavement, metal on vehicles, and even the air. In addition to extreme flammability, it is also toxic by ingestion or inhalation and is a strong irritant. TLV is 0.005 ppm in air, and it is immiscible in water. The four-digit UN identification number is 1380. The NFPA 704 designation for pentaborane is health 4, flammability 4, and reactivity 2. The primary uses are as fuel for air-breathing engines and as a propellant.

UsesThere appears to be no commercial market for pentaborane. In the 1950s it was explored as a potential rocket fuel.

UsesReducing agent in propellant fuels

General DescriptionA clear colorless liquid with a pungent odor like sour milk, and flammable.It is corrosive to natural rubber, some synthetic rubber, some greases, and some lubricants and gives off irritating or toxic fumes (or gases) in a fire. It reacts violently with fire. Pentaboron nonahydride incompatible with strong oxidants such as chromium anhydride, chlorate and potassium permanganate, and other contacts. Vapors toxic both under prolonged exposure to low concentrations and short exposure to high concentrations. Density 0.61 g / cm3. Under prolonged exposure to intense heat the containers may rupture violently and rocket.

Preparation methods

PreparationPentaborane is obtained by passing diborane through a hot tube. Careful control of temperature, pressure, and flow are required to obtain good yields and avoid further pyrolysis to higher hydrides.

Upstream & downstream products

Upstream raw materials

Related reactions

0 records
New reaction record

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Compound notes

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On this pageBasic informationNames & identifiersPropertiesSafety & regulationChemistry & industryRelated reactionsCompound notes
Pentaborane(9),1-iodo-