Names & identifiers
- Preferred name
- Orris oil
- English name
- Orris oil
- Molecular weight
- 0
Names & synonyms
Database identifiers
- CAS
8002-73-1
Properties
Physicochemical properties
- Melting point
- 40 · 40-46 °C(lit.)
- FEMA
- 2829 · 2829 | ORRIS CONCRETE LIQUID OIL (IRIS FLORENTINA L.)
- Flash point
- 230 °F · >230 °F
- color
- Pale yellow to yellow oil
- Odor
- woody fatty violetfruity sweet floral
- Odor Type
- floral
- FDA UNII
- 60 YYT168M · C60YYT168M
- EPA Substance Registry System
- Oils, orris (8002-73-1)
- WGK Germany
- 2 · 2
- RTECS
- 3440000 · RM3440000
- TSCA
- TSCA listed
- Toxicity
- 50 orl-rat: · LD50 orl-rat: 9400 mg/kg FCTXAV 13,895,75
Safety & regulation
Safety data
- wgk
- 2
- tsca
- TSCA listed
- rtecs
- RM3440000
- Toxicity
- LD50 orl-rat: 9400 mg/kg FCTXAV 13,895,75
Chemistry & industry
Applications
DescriptionPerennial herbaceous plant that grows wild or can be cultivated. The various species are native to the Far East, but they are well acclimated to the Mediterranean regions as well. Their cultivation in Italy represents a flourishing industry.I. pallida Lam. is the best variety for extractive purposes, followed by I. germanica and I. florentina (which is cultivated mainly for ornamental purposes). Depending on the variety, the plant exhibits blue, deep blue, or whitish-blue veined flowers. It has an erect stem and radical leaves. It has large, horizontal, highly branched, and fleshy rhizomes exhibiting a pleasant and persistent odor. The fragrance of I. pallida is most persistent. The peeled rhizomes (roots) are used after two years of aging. Commercial qualities include straight, twisted, and knotty rhizomes. Orris has a violet-like odor with a fruity undertone. Orris concrete: Orris butter, or orris concrete, is obtained by steam distillation of dried ground rhizomes with yields ranging between 0.2 to 0.3%. Special techniques and prolonged distillation are required. It contains 13% to 17% ketones (sometimes more) calculated as irone; 83 to 86% free or partially esterified fatty acids (e.g., myristic); terpene and sesquiterpene alcohols; aldehydes; and esters. The physical-chemical constants vary, depending on the origin of the rhizomes. At room temperature, orris concrete from 1. pallida Lam. is a light yellow-brown solid mass with a violetlike fragrance; at 40 to 50℃ the product melts to a yellow to yellow-brown liquid. Orris absolute: Obtained by alcoholic extraction of the concrete to separate the fatty acids and their esters. It may contain from 55 to 85% ketones (irone). Orris resinoid: The resinoid is prepared by extracting the comminuted rhizomes with yields of 2.4 to 3.3% using benzene, or 1 to 2% using petroleum ether. An absolute can be prepared from the resinoid; this contains 62 to 78% ketones (irone).The derivatives are fluid extract, concrete and absolute essence, resinoid, and the tincture (20% in 50 to 60% ethanol or 30% in 55% ethanol).
OccurrenceFound in the rhizomes of Iris pallida. Lam. (Fam. Iridaceae) (Guenther. 1952; Naves, 1974).
UsesGB 2760—96 specifies orris oil as a permitted edible flavoring. It is used to formulate flavorings for strawberries, peaches, raspberries, etc. It is mainly used in soft drinks, candies, and gelatin-based confectionery.
Preparation methods
PreparationBy alcoholic extraction of the concrete (Fenarolis Handbook of Flavor Ingredients. 1971).
Upstream & downstream products
Upstream raw materials
Downstream products
Suppliers36 total
Additional notes
DefinitionExtractives and their physically modified derivatives. Iris pallida, Iridaceae.
Related reactions
No reaction records under the current filter.
Linked notes
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