Orris oil

HCID 178694035CAS 8002-73-1
No structure available

Names & identifiers

Preferred name
Orris oil
English name
Orris oil
Molecular weight
0

Names & synonyms

orrisFEMA 2829ORRIS CONCRETEOrris oilOils,orrisOrrisresinorrisliquidIrisabsoluteResinoidirisOrrisrootoil

Database identifiers

CAS
8002-73-1

Properties

Physicochemical properties

Melting point
40 · 40-46 °C(lit.)
FEMA
2829 · 2829 | ORRIS CONCRETE LIQUID OIL (IRIS FLORENTINA L.)
Flash point
230 °F · >230 °F
color
Pale yellow to yellow oil
Odor
woody fatty violetfruity sweet floral
Odor Type
floral

Safety & regulation

Safety data

wgk
2
tsca
TSCA listed
rtecs
RM3440000
Toxicity
LD50 orl-rat: 9400 mg/kg FCTXAV 13,895,75

Chemistry & industry

Applications · 3 items

DescriptionPerennial herbaceous plant that grows wild or can be cultivated. The various species are native to the Far East, but they are well acclimated to the Mediterranean regions as well. Their cultivation in Italy represents a flourishing industry.I. pallida Lam. is the best variety for extractive purposes, followed by I. germanica and I. florentina (which is cultivated mainly for ornamental purposes). Depending on the variety, the plant exhibits blue, deep blue, or whitish-blue veined flowers. It has an erect stem and radical leaves. It has large, horizontal, highly branched, and fleshy rhizomes exhibiting a pleasant and persistent odor. The fragrance of I. pallida is most persistent. The peeled rhizomes (roots) are used after two years of aging. Commercial qualities include straight, twisted, and knotty rhizomes. Orris has a violet-like odor with a fruity undertone. Orris concrete: Orris butter, or orris concrete, is obtained by steam distillation of dried ground rhizomes with yields ranging between 0.2 to 0.3%. Special techniques and prolonged distillation are required. It contains 13% to 17% ketones (sometimes more) calculated as irone; 83 to 86% free or partially esterified fatty acids (e.g., myristic); terpene and sesquiterpene alcohols; aldehydes; and esters. The physical-chemical constants vary, depending on the origin of the rhizomes. At room temperature, orris concrete from 1. pallida Lam. is a light yellow-brown solid mass with a violetlike fragrance; at 40 to 50℃ the product melts to a yellow to yellow-brown liquid. Orris absolute: Obtained by alcoholic extraction of the concrete to separate the fatty acids and their esters. It may contain from 55 to 85% ketones (irone). Orris resinoid: The resinoid is prepared by extracting the comminuted rhizomes with yields of 2.4 to 3.3% using benzene, or 1 to 2% using petroleum ether. An absolute can be prepared from the resinoid; this contains 62 to 78% ketones (irone).The derivatives are fluid extract, concrete and absolute essence, resinoid, and the tincture (20% in 50 to 60% ethanol or 30% in 55% ethanol).

OccurrenceFound in the rhizomes of Iris pallida. Lam. (Fam. Iridaceae) (Guenther. 1952; Naves, 1974).

UsesGB 2760—96 specifies orris oil as a permitted edible flavoring. It is used to formulate flavorings for strawberries, peaches, raspberries, etc. It is mainly used in soft drinks, candies, and gelatin-based confectionery.

Preparation methods

PreparationBy alcoholic extraction of the concrete (Fenarolis Handbook of Flavor Ingredients. 1971).

Upstream & downstream products

Upstream raw materials

Suppliers36 total

北京华美互利生物化工010-56205725 · [email protected]
湖北成丰化工有限公司13125175253 · [email protected]
武汉欣扬瑞和化学科技有限公司13720274133 · [email protected]
武汉欣扬瑞和化学科技有限公司153-07155313 15307155313 · [email protected]
武汉绿景丰华生物科技有限公司19972070065 · [email protected]

Additional notes

DefinitionExtractives and their physically modified derivatives. Iris pallida, Iridaceae.

Related reactions

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