dichlororuthenium;(1S,2S)-1,2-diphenylethane-1,2-diamine;[3-(4-diphenylphosphanyl-2,6-dimethoxy-3-pyridinyl)-2,6-dimethoxy-4-pyridinyl]-diphenylphosphane
(S)-P-Phos RuCl2 (S · (S)-P-Phos RuCl2 (S,S)-DPEN, Ru 9.8% · Dichloro[(S)-(-)-2,2',6,6'-tetramethoxy-4,4'-bis(diphenylphosphino)-3,3'-bipyridine][(1S,2S)-(-)-1,2-diphenylethylenediamine]ruthenium(II) · Dichloro[(S)-(-)-2,2',6,6'-tetramethoxy-4,4'-bis(di-phenylphosphino)-3,3'-bipyridine][(1S,2S)-(-)-1,2-diphenylethylenediamine]ruthenium(II) · Dichloro[(S)-(-)-2,2'',6,6''-tetramethoxy-4,4''-bis(diphenylphosphino)-3,3''-bipyridine][(1S,2S)-(-)-1,2-diphenylethylenediamine]ruthenium(II) · Dichloro[(S)-(-)-2,2',6,6'-tetramethoxy-4,4'-bis(diphenylphosphino)-3,3'-bipyridine][(1S,2S)-(-)-1,2-diphenylethylenediamine]ruthenium(II),min.95% · Dichloro[(S)-(-)-2,2',6,6'-tetramethoxy-4,4'-bis(diphenylphosphino)-3,3'-bipyridine][(1S,2S)-(-)-1,2-diphenylethylenediamine]ruthenium(II), min. 95%
![dichlororuthenium;(1S,2S)-1,2-diphenylethane-1,2-diamine;[3-(4-diphenylphosphanyl-2,6-dimethoxy-3-pyridinyl)-2,6-dimethoxy-4-pyridinyl]-diphenylphosphane molecular structure](/img/chemical/178955152.png)
Identifiers & Physical Properties
| CAS No. | 821793-36-6 |
|---|---|
| Molecular formula | C52H50Cl2N4O4P2Ru |
| Average molar mass | 1,028.9 g/mol |
| SMILES | COc1cc(P(c2ccccc2)c2ccccc2)c(-c2c(P(c3ccccc3)c3ccccc3)cc(OC)nc2OC)c(OC)n1.N[C@@H](c1ccccc1)[C@@H](N)c1ccccc1.[Cl][Ru][Cl] |
| InChIKey | AKMYBLAYOREDRA-LISIALKWSA-L |
Chemical & Physical Properties
| Topological polar surface area | 115 |
|---|---|
| Hydrogen bond donors | 2 |
| Hydrogen bond acceptors | 8 |
| Rotatable bonds | 14 |
| Heavy atoms | 65 |
| Formal charge | 0 |
| Complexity | 944 |
| Physical state | solid |
| Color | yellow |
| Sensitivity | air sensitive |
Applications & Uses
Uses
Effective catalyst for the highly enantioselective hydrogenation of a diverse range of simple aromatic ketones.