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Tridecyl acrylate

HCID 18316
NotesReactions
Basic informationNames & identifiersPropertiesSafety & regulationChemistry & industryRelated reactionsCompound notes
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Basic information

CAS
3076-04-8
Standard SMILES
C=CC(=O)OCCCCCCCCCCCCC
InChIKey
XOALFFJGWSCQEO-UHFFFAOYSA-N
Molecular formula
C16H30O2
Average molar mass
254.41 g/mol
Monoisotopic mass
254.2245802

Names & identifiers

Preferred name
Tridecyl acrylate
IUPAC
tridecyl prop-2-enoate
English name
TRIDECYL ACRYLATE
Molecular formula
C16H30O2
Molecular weight
254.41

Names & synonyms

TRIDECYL ACRYLATE2-Propenoic acid, tridecyl esterAcrylic acid, tridecyl esterAcrylic acid tridecyl ester3B65OMU9HJ2-Propenoic acid tridecyl esterHSDB 6078NSC 6130NSC-6130EINECS 221-351-8UNII-3B65OMU9HJBRN 1780909
Show more names
Tridecyl2-propenoateridecylprop-2-enoate2-Triadecyl acrylatetridecyl prop-2-enoateacrylicacidtridecylesteracrylicacid,tridecylester2-propenoicacidtridecylesterTridecyl acrylate (homologue)2-Propenoiccaid,tridecylester
1-TRIDECANOL, ACRYLATEDTXSID1051987TRIDECYL ACRYLATE [HSDB]2-Propenoic acid, n-tridecyl ester4-02-00-01468 (Beilstein Handbook Reference)RefChem:1914522Propenoic acid tridecyl ester2Propenoic acid, tridecyl ester

Database identifiers

CAS
3076-04-8
PubChem CID
18316
DTXSID
DTXSID1051987
UNII
3B65OMU9HJ
EC Number
221-351-8
Nikkaji
J55.138D

Properties

Computed structural properties

XLogP
6.7
Topological polar surface area
26.3 Ų
Hydrogen bond donors
0
Hydrogen bond acceptors
2
Rotatable bonds
14
Heavy atoms
18
Formal charge
0
Complexity
199

Experimental & physicochemical properties

PolymersPlastics & Rubber -> (Meth)acrylates
SpringerMaterials PropertiesDensity
Density0.9
SolubilityINSOL IN WATER
Flash Point132 °C (OPEN CUP)
Boiling Point150 °C @ 10 MM HG
DecompositionWhen heated to decomp it emit acrid smoke & fumes.
Physical DescriptionClear liquid; [MSDSonline]
Other Experimental PropertiesReact readily with electrophilic, free-radical, and nucleophilic agent /Acrylic acid & esters/

Physicochemical properties

Boiling point

Safety & regulation

Safety information is for reference only and does not replace the supplier’s Safety Data Sheet (SDS), applicable regulations, or professional assessment.

GHS classification

GHS Classification · 4 items

Danger

H300 (21.5%): Fatal if swallowed [Danger Acute toxicity, oral]

P260, P261, P264, P264+P265, P270, P271, P272, P273, P280, P301+P316, P301+P330+P331, P302+P352, P302+P361+P354, P304+P340, P305+P351+P338, P305+P354+P338, P316, P319, P321, P330, P332+P317, P333+P317, P337+P317, P362+P364, P363, P391, P403+P233, P405, and P501 (click each P-code to see the statement)

Aggregated GHS information provided per 181 reports by companies from 12 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.

Hazard information

Regulatory Information · 2 items

Chemical: 2-Propenoic acid, tridecyl ester

Tridecyl acrylate: Does not have an individual approval but may be used as a component in a product covered by a group standard. It is not approved for use as a chemical in its own right.

Hazards Summary · 1 item

External application to rabbit eyes scored 2 on a scale of 1-10 (10 being most severe) for degree of injury after 24 hours; [HSDB] May polymerize hazardously; May cause irritation; Suspected skin sensitization hazard; [MSDSonline] See ACRYLIC RESINS (MONOMERS).

TSCA RequirementsSection 8(a) of TSCA requires manufacturers of this chemical substance to report preliminary assessment information concerned with production, use, and exposure to EPA as cited in the preamble of the 51 FR 41329.
NFPA Hazard Classification · 3 items

1 - Materials that, under emergency conditions, can cause significant irritation.

1 - Materials that must be preheated before ignition can occur. Materials require considerable preheating, under all ambient temperature conditions, before ignition and combustion can occur.

Chemistry & industry

Uses & manufacturing

Uses · 3 items

Used as comonomer (e.g. for lubricating oil additives); [HSDB]

Plastic Composites Manufacturing [Category: Industry]

COMONOMER, EG, FOR LUBRICATING OIL ADDITIVES

U.S. Imports(1983) 1.36x10+9 g /Acrylates & Acrylic Acid/
U.S. Production(1977) AT LEAST 4.54X10+6 G
Methods of Manufacturing · 3 items

TRANSESTERIFICATION OR ESTERIFICATION OF TRIDECYL ALCOHOL WITH EITHER METHYL ACRYLATE OR ACRYLIC ACID

ACRYLATES CAN BE PREPARED BY ... DEHYDRATION OF THE CORRESPONDING HYDROXYALKANOIC ACID, SAPONIFICATION OF THE ALKENE NITRILE, CATALYTIC HYDRATION OF ACETYLENE AND CARBON MONOXIDE, OR THE REACTION OF ACETONE WITH HYDROCYANIC ACID. /ACRYLATES/

In ... propylene oxidation process acrolein is first formed by the catalytic oxidation of propylene vapor at high temp in the presence of steam. The acrolein is then oxidized to acrylic acid. ... The acrylic acid is esterified with alcohol to the ... acrylic ester in a separate process. /Acrylic ester monomers/

Formulations/Preparations... Hydroquinone or monomethyl ether hydroquinone are added to acrylic monomers to stabilize them ... . /Acrylic ester monomers/
General Manufacturing Information2-Propenoic acid, tridecyl ester: ACTIVE

Suppliers38 total

上海利卡斯实业有限公司19821976800 · [email protected]
江苏艾康生物医药研发有限公司025-58851090 19370895928 · [email protected]
武汉欣扬瑞和化学科技有限公司153-07155313 15307155313 · [email protected]

Related reactions

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Compound notes

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On this pageBasic informationNames & identifiersPropertiesSafety & regulationChemistry & industryRelated reactionsCompound notes
150 °C · 150°C 10mm
Density
0 · 0,881 g/cm3
refractive index
1.4342 · 1.4342 (estimate)
Flash point
270 · >270
form
Liquid
Viscosity
10 cp · 10cp (25C)
FDA UNII
3 B65OMU9HJ · 3B65OMU9HJ
EPA Substance Registry System
Tridecyl acrylate (3076-04-8)
Symbol(GHS)
6 · GHS06,GHS09
Signal word
Danger
Hazard statements
300 · H300-H315-H319-H335-H411
Precautionary statements
261 · P261-P264-P273-P301+P310-P302+P352-P305+P351+P338
Hazard Codes
T
Risk Statements
22 · 22-34-41
Safety Statements
26 · 26-36/37/39-45
TSCA
TSCA listed
Hazardous Substances Data
3076 · 3076-04-8(Hazardous Substances Data)

0 - Materials that in themselves are normally stable, even under fire conditions.

Hazard Classes and CategoriesAcute Tox. 2 (21.5%)
Skin, Eye, and Respiratory IrritationsTHE LOWER-MOL-WT ESTERS OF ACRYLIC ACIDS ARE IRRITANTS TO SKIN, EYES, & MUCOUS MEMBRANES. /ACRYLIC ACID ESTERS/

Safety & protection

Storage Conditions · 1 item

The effectiveness of phenolic inhibitors is dependent on the presence of oxygen and the monomers must be stored under air rather than an inert atmosphere. Temp must be kept low to minimize formation of peroxides and other products. ... The acrylic esters may be stored in mild or stainless steel, or aluminum. /Acrylic acid & derivatives/

Disposal Methods · 1 item

SRP: At the time of review, criteria for land treatment or burial (sanitary landfill) disposal practices are subject to significant revision. Prior to implementing land disposal of waste residue (including waste sludge), consult with environmental regulatory agencies for guidance on acceptable disposal practices.

Preventive Measures · 3 items

Awareness of the dangers and of good engineering design are essential to safety. Employees should be instructed about the necessity of cleansing the skin if it is contaminated by materials which are irritants or skin-absorbed. With careful design, however, and complete enclosure of those processes where toxic chemicals or intermediates occur, dangerous exposures can be avoided. /Acrylic acid & derivatives/

SRP: Contaminated protective clothing should be segregated in such a manner so that there is no direct personal contact by personnel who handle, dispose, or clean the clothing. Quality assurance to ascertain the completeness of the cleaning procedures should be implemented before the decontaminated protective clothing is returned for reuse by the workers. Contaminated clothing should not be taken home at end of shift, but should remain at employee's place of work for cleaning.

SRP: The scientific literature for the use of contact lenses in industry is conflicting. The benefit or detrimental effects of wearing contact lenses depend not only upon the substance, but also on factors including the form of the substance, characteristics and duration of the exposure, the uses of other eye protection equipment, and the hygiene of the lenses. However, there may be individual substances whose irritating or corrosive properties are such that the wearing of contact lenses would be harmful to the eye. In those specific cases, contact lenses should not be worn. In any event, the usual eye protection equipment should be worn even when contact lenses are in place.

Personal Protective Equipment (PPE) · 2 items

SUITABLE PROTECTIVE CLOTHING & SELF-CONTAINED RESP PROTECTIVE APPARATUS SHOULD BE AVAILABLE FOR USE OF THOSE WHO MAY HAVE TO RESCUE PERSONS OVERCOME BY FUMES. /ACRYLIC ACID & DERIVATIVES/

Protection required for safe handling of acrylic acid and esters commonly includes use of impervious gloves, shoe soles, and clothing; splash-proof goggles ... /Acrylic acid & derivatives/

Toxicology

Adverse EffectsSkin Sensitizer - An agent that can induce an allergic reaction in the skin.
Human Toxicity Excerpts · 1 item

THE TOXICITY OF THE ACRYLATES DECREASES WITH INCREASING MOLECULAR WEIGHT. ... HUMAN SIGNS & SYMPTOMS FOLLOWING INGESTION OF ACRYLIC MONOMERS INCL COLLAPSE, SEVERE RESPIRATORY DIFFICULTIES, & CNS STIMULATION. INHALATION OF HIGHER CONCN MAY CAUSE MARKED IRRITATION, SALIVATION, CONJUNCTIVAL IRRITATION, & PRONOUNCED PULMONARY IRRITATION OR EDEMA. PROLONGED SKIN OR EYE CONTACT MAY RESULT IN SEVERE TISSUE DAMAGE. THE PATHOLOGY FROM SINGLE EXPOSURE IS CONTRARY TO REPEATED EXPOSURE EFFECTS, WHICH INCL PULMONARY CONGESTION OR HEMORRHAGE & CLOUDY SWELLING OF LIVER & KIDNEY. /ACRYLATES/

Non-Human Toxicity Excerpts · 2 items

Acrylic acid tridecyl ester has been tested externally on the eyes of rabbits & ... rated 2 on scale of 1 to 10 according to the degree of injury observed after 24 hr. The most severely injurious substances have been rated 10.

Contact sensitivity was produced in guinea pigs with mono-, di-, and tri- acrylate compounds. /Mono-, di-, and tri- acrylate compounds/

Regulatory information

TSCA RequirementsSection 8(a) of TSCA requires manufacturers of this chemical substance to report preliminary assessment information concerned with production, use, and exposure to EPA as cited in the preamble of the 51 FR 41329.

Safety data

tsca
TSCA listed
risk_code
22-34-41
Signal word
Danger
Symbol(GHS)
GHS06,GHS09
hazard_code
T
safety_code
26-36/37/39-45
Hazard statements
H300-H315-H319-H335-H411
Precautionary statements
P261-P264-P273-P301+P310-P302+P352-P305+P351+P338
Hazardous Substances Data
3076-04-8(Hazardous Substances Data)
上海毕得医药科技股份有限公司
400-1647117 13681763483 · [email protected]
Dayang Chem (Hangzhou) Co.,Ltd.+86-0571-88938639 17705817739 · [email protected]
上海赛可锐生物科技有限公司021-58000709 13120558703 · [email protected]
山东利腾生物科技有限公司+86-18663721413 +86-15552573001 · [email protected]
Aladdin Scientific[email protected]
陕西纬宇新材料有限公司13772052144 13772052144 · [email protected]
上海维亦特生物科技有限公司15317051735 · [email protected]
湖北广奥生物科技有限公司027-02702759223056 18162699093 · [email protected]
武汉丰泰威远科技有限公司+86-27-8746-5837 +86-18627785180 · [email protected]
天津狄克特科技有限公司22-58627059 13920586291 · [email protected]
武汉丰泰威远科技有限公司027-87465837 19945049750 · [email protected]
广东元丰化学试剂有限公司0751-2829979 13376591640 · [email protected]
Shanghai Scibiotron Pharmaceutical Co., Ltd+86-16621589600 · [email protected]
PT CHEM GROUP LIMITED+86-85511178; +86-85511178 · [email protected]
山东利腾生物科技有限公司15020019777 18663721413 · [email protected]
韶关新润合生物科技有限公司19022763608 19022763608 · [email protected]
上海阿拉丁生化科技股份有限公司6206333 13167063860 · [email protected]
陕西缔都医药化工有限公司029-029-81120477 17792793610 · [email protected]
南通市苏北化工原料有限公司0513-85290972 18762756250 · [email protected]
上海源叶生物科技有限公司18916372613 · [email protected]
安泰精细化工技术有限公司18503026267 · [email protected]
上海睿升化工科技有限公司15026594951 · [email protected]
杭州洁汉化工有限公司+86-571-86217390; +8618058761490 · [email protected]
深圳市丽晶生化科技有限公司0755-85201366 18938635012 · [email protected]
山东千里宏生物科技股份有限公司0543-17705431882 13696309696 · [email protected]
深圳利斯康医药科技有限公司+86-755-89396905 +86-15013857715 · [email protected]
郑州艾克姆化工有限公司13303867194 · [email protected]
镇江博润生物医药科技有限公司15862994627 · [email protected]
湖北拓邦化工有限公司027-59106185 13986192185 · [email protected]
SUZHOU SENFEIDA CHEMICAL CO.,LTD+86-0512-83500002 +86-15195660023 · [email protected]
上海杰股生物科技有限公司021-51698675 · [email protected]
广东翁江化学试剂有限公司0751-2815983 13927872582 · [email protected]
武汉万鉴生物科技有限公司13277087647 · [email protected]
湖北鑫红利化工有限公司027-027-59106151 15172325309 · [email protected]
山东彬睿特新材料有限公司0533-2866658 15615638350 · [email protected]