p-tert-Butylphenyl glycidyl ether

HCID 18360CAS 3101-60-8

Basic information

Standard SMILES
CC(C)(C)c1ccc(OCC2CO2)cc1
InChIKey
HHRACYLRBOUBKM-UHFFFAOYSA-N
Molecular formula
C13H18O2
Average molar mass
206.28 g/mol
Monoisotopic mass
206.13067982

Overview

P-tert-butylphenyl glycidyl ether is a clear light yellow liquid. (NTP, 1992)

Names & identifiers

Preferred name
p-tert-Butylphenyl glycidyl ether
IUPAC
2-[(4-tert-butylphenoxy)methyl]oxirane
English name
ARALDITE M
Molecular formula
C13H18O2
Molecular weight
206.28

Names & synonyms

3101-60-84-tert-Butylphenyl glycidyl etherp-tert-Butylphenyl glycidyl ether2-[(4-tert-Butylphenoxy)methyl]oxiranetert-Butyl phenyl glycidyl ethertert-Butylphenol glycidyl ethertert-Butylphenyl glycidyl etherCCRIS 2638p-tert-Butylphenyl 1-(2,3-epoxy)propyl etherDTXSID10247023-(p-tert-Butylphenoxy)-1,2-epoxypropaneOxirane, [[4-(1,1-dimethylethyl)phenoxy]methyl]-
Show more names
r1007XY693Heloxy 65ARALDITE MARALDITE 502ARALDITE 506ARALDITE 507
EINECS 221-453-2DUA9665YBGPropane, 1-(p-tert-butylphenoxy)-2,3-epoxy-R 10072,3-Epoxypropyl-4-t-butylphenyl etherBRN 0007417Oxirane, ((4-(1,1-dimethylethyl)phenoxy)methyl)-AI3-52800

Database identifiers

CAS
3101-60-8
PubChem CID
18360
DTXSID
DTXSID1024702
ChEMBL
CHEMBL1890780
UNII
DUA9665YBG
EC Number
221-453-2、682-371-4
Nikkaji
J64.262B

Properties

Computed structural properties

XLogP
3.3
Topological polar surface area
21.8 Ų
Hydrogen bond donors
0
Hydrogen bond acceptors
2
Rotatable bonds
4
Heavy atoms
15

Experimental & physicochemical properties

PolymersPlastics & Rubber -> Glycidyl Ethers
Density1.038 at 68 °F (NTP, 1992) - Denser than water; will sink
Solubilityless than 1 mg/mL at 72 °F (NTP, 1992)
Flash Point215 °F (NTP, 1992)
Boiling Point329 to 338 °F at 14 mmHg (NTP, 1992)
Physical Description · 3 items

P-tert-butylphenyl glycidyl ether is a clear light yellow liquid. (NTP, 1992)

Liquid

Clear light yellow liquid; [CAMEO] Colorless liquid with a mild odor; [Sigma-Aldrich MSDS]

Physicochemical properties

Boiling point
165 · 165-170 °C14 mm Hg(lit.)
Density
1.038 g/mL · 1.038 g/mL at 25 °C(lit.)
vapor pressure
0.025 Pa · 0.025Pa at 20℃
refractive index
20 · n20/D 1.515(lit.)
Flash point
215 °F · 215 °F
storage temp.
Inert atmosphere,Room Temperature

Safety & regulation

GHS classification

GHS Classification · 6 items

This chemical does not meet GHS hazard criteria for 0.7% (7 of 1042) of reports.

Danger

H314 (44.7%): Causes severe skin burns and eye damage [Danger Skin corrosion/irritation]

P260, P261, P264, P264+P265, P272, P273, P280, P301+P330+P331, P302+P352, P302+P361+P354, P304+P340, P305+P351+P338, P305+P354+P338, P316, P321, P332+P317, P333+P317, P337+P317, P362+P364, P363, P391, P405, and P501 (click each P-code to see the statement)

Aggregated GHS information provided per 1042 reports by companies from 16 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.

Warning

Hazard information

Regulatory Information · 5 items

Chemical: Oxirane, [[4-(1,1-dimethylethyl)phenoxy]methyl]-

Oxirane, 2-[[4-(1,1-dimethylethyl)phenoxy]methyl]- is listed on the EPA's Chemical Data Reporting (CDR) system. Manufacturers and importers of Oxirane, 2-[[4-(1,1-dimethylethyl)phenoxy]methyl]- are required to report information about their production and use of this chemical to the EPA under the Toxic Substances Control Act (TSCA). (40 eCFR Part 711)

TP - indicates a substance that is the subject of a proposed TSCA section 4 test rule.

Status: Active Update: 25-11-2021 https://echa.europa.eu/registration-dossier/-/registered-dossier/10438

Oxirane, 4-(1,1-dimethylethyl)phenoxymethyl-: Does not have an individual approval but may be used under an appropriate group standard

Fire HazardsThis chemical is combustible. (NTP, 1992)
Hazards SummaryMay form unstable peroxides; [CAMEO] A skin and strong eye irritant; May cause skin sensitization; [Sigma-Aldrich MSDS] Danger of skin sensitization; [MAK] See p-Cresyl glycidyl ether.
Reactive GroupEthers
Reactivity AlertsPeroxidizable Compound
Reactivity Profile · 1 item

P-TERT-BUTYLPHENYL GLYCIDYL ETHER, an ether, can act as a base. They form salts with strong acids and addition complexes with Lewis acids. The complex between diethyl ether and boron trifluoride is an example. Ethers may react violently with strong oxidizing agents. In other reactions, which typically involve the breaking of the carbon-oxygen bond, ethers are relatively inert.

Safety & protection

Fire FightingFires involving this chemical can be controlled with a dry chemical, carbon dioxide or Halon extinguisher. (NTP, 1992)
First Aid · 1 item

EYES: First check the victim for contact lenses and remove if present. Flush victim's eyes with water or normal saline solution for 20 to 30 minutes while simultaneously calling a hospital or poison control center. Do not put any ointments, oils, or medication in the victim's eyes without specific instructions from a physician. IMMEDIATELY transport the victim after flushing eyes to a hospital even if no symptoms (such as redness or irritation) develop.

Nonfire Spill Response · 1 item

SMALL SPILLS AND LEAKAGE: If you spill this chemical, FIRST REMOVE ALL SOURCES OF IGNITION. Then, use absorbent paper to pick up all liquid spill material. Your contaminated clothing and absorbent paper should be sealed in a vapor-tight plastic bag for eventual disposal. Solvent wash all contaminated surfaces with 60-70% ethanol followed by washing with a soap and water solution. Do not reenter the contaminated area until the Safety Officer (or other responsible person) has verified that the area has been properly cleaned.

Personal Protective Equipment (PPE) · 1 item

RECOMMENDED RESPIRATOR: Where the neat test chemical is weighed and diluted, wear a NIOSH-approved half face respirator equipped with an organic vapor/acid gas cartridge (specific for organic vapors, HCl, acid gas and SO2) with a dust/mist filter. (NTP, 1992)

Toxicology

Adverse EffectsSkin Sensitizer - An agent that can induce an allergic reaction in the skin.

Safety data

wgk
3
tsca
TSCA listed
rtecs
TX4250000
hs_code
2910.90.2000
risk_code
36/37/38-43-36/38-22-62-51/53-61
Signal word
Warning

Chemistry & industry

Uses & manufacturing

U.S. Production2023: 250,000 - <400,000 lb
Consumer UsesNot Known or Reasonably Ascertainable
Industry UsesMonomers
Household ProductsInformation on 3 consumer products that contain 4-tert-Butylphenyl glycidyl ether in the following categories is provided:
General Manufacturing Information · 2 items

Custom Compounding of Purchased Resins

Oxirane, 2-[[4-(1,1-dimethylethyl)phenoxy]methyl]-: ACTIVE

Applications

Uses4-tert-Butylphenyl glycidyl ether is used in paint industry and serves as organic coating in Paint, boat Paint, building coating material. It is also used as an epoxy reactive diluent.

General DescriptionClear light yellow liquid.

Upstream & downstream products

Suppliers50 total

常州市弘裕化工有限公司0519-89996110 13813691203 · [email protected]
郑州阿尔法化工有限公司+86-18530059196 · [email protected]
苏州道澜生物医药科技有限公司15952404857 · [email protected]
湖北永阔科技有限公司027-59223108 15972152991 · [email protected]
上海阿拉丁生化科技股份有限公司400-6206333 13167063860 · [email protected]

Related reactions

15 records

Linked notes

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