CAS 3144-16-9 Bicyclo[2.2.1]heptane-1-methanesulfonic acid, 7,7-dimethyl-2-oxo-, (1S)- (HCID 18462)

Overview

Camphorsulfonic acid is a sulfonic acid containing the camphorsulfonate anion. It is functionally related to a camphor. It is a conjugate acid of a camphorsulfonate anion.

Names & identifiers

Preferred name: Bicyclo[2.2.1]heptane-1-methanesulfonic acid, 7,7-dimethyl-2-oxo-, (1S)-
IUPAC: (7,7-dimethyl-2-oxo-1-bicyclo[2.2.1]heptanyl)methanesulfonic acid
English name: (1S)-(+)-Camphor-10-sulphonic acid
Molecular formula: C10H16O4S
Molecular weight: 232.3

Names & synonyms

Bicyclo[2.2.1]heptane-1-methanesulfonic acid, 7,7-dimethyl-2-oxo-, (1S)-Bicyclo(2.2.1)heptane-1-methanesulfonic acid, 7,7-dimethyl-2-oxo-, (1S)-RefChem:5681465872-08-2(7,7-Dimethyl-2-oxobicyclo[2.2.1]heptan-1-yl)methanesulfonic acidDL-10-Camphorsulfonic acid61380-66-3camphor sulfonic acid(7,7-dimethyl-2-oxo-1-bicyclo[2.2.1]heptanyl)methanesulfonic acid(+)-10-CAMPHORSULFONIC ACIDd-10-Camphorsulfonic acid7,7-Dimethyl-2-oxobicyclo[2.2.1]heptane-1-methanesulfonic acid

Show more names

CSAD-CAMPHORSULFONIC ACID(+)-CSA(1S)-(+)-10-CAMPHORSULFONIC ACIDCaMsylateMOT

DL-CAMPHORSULFONIC ACID(+/-)-10-Camphorsulfonic Acid(+)-Camphorsulfonic acidD-Camphor-10-sulfonic acid( inverted exclamation markA)-Camphor-10-sulfonic acidCamphor-10-sulfonic acidL-10-(-)-Camphor sulfonic acid(+/-)-Camphor-10-sulfonic acid

Database identifiers

CAS: 3144-16-9、5872-08-2、76-26-6
PubChem CID: 18462
DTXSID: DTXSID60863113
ChEMBL: CHEMBL5596548
ChEBI: CHEBI:55379
EC Number: 200-949-2
Nikkaji: J192.554G、J264.789C

Properties

Computed structural properties

XLogP: 0.5
Topological polar surface area: 79.8 Å²
Hydrogen bond donors: 1
Hydrogen bond acceptors: 4
Rotatable bonds: 2
Heavy atoms: 15
Formal charge: 0
Complexity: 404

Physicochemical properties

Melting point: 196 · 196-200 °C (dec.)(lit.)
alpha: 22 · 22 º (589nm, c=20, H2O 25 ºC)
Boiling point: 344.46 °C · 344.46°C (rough estimate)
Density: 1.2981 · 1.2981 (rough estimate)
refractive index: 21.5 ° · 21.5 ° (C=5, H2O)
storage temp.: 30 °C · Store below +30°C.
solubility: Exhibit moderate solubility in HCCl.
form: Crystalline Powder
pka: 1.17 · 1.17±0.50(Predicted)
color: White to off-white
PH: 0.3 · 0.3 (200g/l, H2O)
biological source: human
optical activity: 20 · [α]20/D +21.5±1°, c = 10% in H2O
Water Solubility: SOLUBLE
Sensitive: Hygroscopic
Merck: 14 · 14,1734
BRN: 2809675 · 2809675
Stability: Stable. Protect from moisture. Incompatible with strong oxidizing agents, strong bases.
InChI: 1S/C10H16O4S/c1-9(2)7-3-4-10(9,8(11)5-7)6-15(12,13)14/h7H,3-6H2,1-2H3,(H,12,13,14)/t7-,10-/m1/s1
InChIKey: MIOPJNTWMNEORI-GMSGAONNSA-N
SMILES: [H][C@@]12CC[C@@](CS(O)(=O)=O)(C(=O)C1)C2(C)C
CAS DataBase Reference: 3144 · 3144-16-9(CAS DataBase Reference)
FDA UNII: 9 TLZ01S15L · 9TLZ01S15L
EPA Substance Registry System: 2.2 · Bicyclo[2.2.1]heptane-1-methanesulfonic acid, 7,7-dimethyl-2-oxo-, (1S,4R)- (3144-16-9)
UNSPSC Code: 41116107 · 41116107
NACRES: 32 · NA.32
Symbol(GHS): 5 · GHS05
Signal word: Danger
Hazard statements: 290 · H290-H314
Precautionary statements: 234 · P234-P260-P280-P303+P361+P353-P304+P340+P310-P305+P351+P338
PPE: 3 · Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges
Hazard Codes: C
Risk Statements: 34 · 34
Safety Statements: 26 · 26-36/37/39-45-25-27
RIDADR: 3261 · UN 3261 8/PG 2
WGK Germany: 3 · 3
RTECS: 1550000 · ED1550000
F: 3 · 3-10
TSCA: TSCA listed
HazardClass: 8 · 8
PackingGroup: III
HS Code: 29147090 · 29147090
Storage Class: 8 A · 8A - Combustible corrosive hazardous materials
Hazard Classifications: 1 Met · Eye Dam. 1Met. Corr. 1Skin Corr. 1B
REACH Registrations: Active
Limited Quantities: 5 kg · 5.0 kg (11 lbs) (solid)
Excepted Quantities: Max Inner Pack (30g or 30ml) and Max Outer Pack (1Kg or 1L)

Safety & regulation

Hazard information

Regulatory InformationChemical: Bicyclo[2.2.1]heptane-1-methanesulfonic acid, 7,7-dimethyl-2-oxo-, (1S)-

Safety data

F: 3-10
PPE: Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges
wgk: 3
tsca: TSCA listed
rtecs: ED1550000
ridadr: UN 3261 8/PG 2
hs_code: 29147090
risk_code: 34
Signal word: Danger
Symbol(GHS): GHS05
hazard_code: C
safety_code: 26-36/37/39-45-25-27
hazard_class: 8
Storage Class: 8A - Combustible corrosive hazardous materials
packing_group: III
Hazard statements: H290-H314
Limited Quantities: 5.0 kg (11 lbs) (solid)
Excepted Quantities: Max Inner Pack (30g or 30ml) and Max Outer Pack (1Kg or 1L)
REACH Registrations: Active
Hazard Classifications: Eye Dam. 1Met. Corr. 1Skin Corr. 1B
Precautionary statements: P234-P260-P280-P303+P361+P353-P304+P340+P310-P305+P351+P338

Chemistry & industry

Applications · 2 items

UsesUsed as a resolving agent, and as a catalyst for coupling dipeptides.

Uses(1S)-(+)-Camphor-10-sulfonic acid is used as stabilizer. (+)-(1S)-camphor-10-sulfonic acid being a very effective resolving agent. . Chiral polyaniline(PANI) nanofibers were synthesized via facilely potentiostatic electropolymerization method without template in the presence of(1S)-(+)camphor-10-sulfonic acid(D-CSA) or(1R)-(-)camphor-10-sulfonic acid(L-CSA) as the dopant. Synthesis of QUATs derived from (1S)-(+)camphor-10-sulfonic acid.

Upstream & downstream products

Downstream products

Suppliers100 total

国药集团化学试剂有限公司86-21-63210123 · [email protected]

北京华美互利生物化工010-56205725 · [email protected]

梯希爱(上海)化成工业发展有限公司021-67121386 · [email protected]

衢州润东化工有限公司0570-8789886 18892685668 · [email protected]

上海阿拉丁生化科技股份有限公司400-6206333 13167063860 · [email protected]

Additional notes

DefinitionChEBI: (S)-camphorsulfonic acid is the S enantiomer of camphorsulfonic acid. It is a conjugate acid of a (S)-camphorsulfonate. It is an enantiomer of a (R)-camphorsulfonic acid.