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Magnesium Nitrate Hexahydrate

HCID 202877
NotesReactions
Basic informationNames & identifiersPropertiesSafety & regulationChemistry & industryRelated reactionsCompound notes
Substructure searchFind similar structures

Basic information

CAS
13446-18-9
Standard SMILES
O.O.O.O.O.O.O=[N+]([O-])[O-].O=[N+]([O-])[O-].[Mg+2]
InChIKey
MFUVDXOKPBAHMC-UHFFFAOYSA-N
Molecular formula
H12MgN2O12
Average molar mass
256.41 g/mol
Monoisotopic mass
256.0240655

Names & identifiers

Preferred name
Magnesium Nitrate Hexahydrate
IUPAC
magnesium;dinitrate;hexahydrate
English name
Magnesium nitrate hexahydrate
Molecular formula
H12MgN2O12
Molecular weight
256.41

Names & synonyms

Magnesium nitrate hexahydrate13446-18-9Magnesium dinitrate hexahydrateDusicnan horecnatyDTXSID2047484V85K20LJMKMAGNESIUM(II) NITRATE (1:2), HEXAHYDRATEDTXCID0027484RefChem:1088727603-823-9630-458-2magnesium;dinitrate;hexahydrate
Show more names
MAGNESIUM TURNINGSMAGNESIUM METALMAGNESIUM RIBBONMAGNESIUM STANDARDMAGNESIUM IC STANDARDMG-1000ASHING ACIDMAGNESIUM METAdusicnanhorecnatyRIEKE(R) MAGNESIUM
MFCD00149779Dusicnan horecnaty [Czech]UNII-V85K20LJMKNitric acid, magnesium salt, hexahydrateMagnesium Matrix ModifierSCHEMBL94658H12MgN2O12Mg(NO3)2.6H2O

Database identifiers

CAS
13446-18-9
PubChem CID
202877
DTXSID
DTXSID2047484
ChEMBL
CHEMBL3185902
UNII

Properties

Computed structural properties

Topological polar surface area
132 Ų
Hydrogen bond donors
6
Hydrogen bond acceptors
12
Rotatable bonds
0
Heavy atoms
15
Formal charge
0
Complexity
18

Experimental & physicochemical properties

Density1.464 @25 °C
Melting Point89 °C
Physical Description · 2 items

Dry Powder

Colorless deliquescent solid; [Merck Index] White odorless solid; Hygroscopic; [Acros Organics MSDS]

Physicochemical properties

Melting point
89 °C · 89 °C
Boiling point
330 °C · 330 °C
Density
1.63 · 1.63
vapor density
6 · 6 (vs air)
vapor pressure
1 mm · 1 mm Hg ( 621 °C)
Flash point
26 °F · −26 °F
storage temp.
2 · 2-8°C
solubility
2 O: · H2O: 1 M at 20 °C, clear, colorless
form
turnings
color
White
Specific Gravity
1.64 · 1.64

Safety & regulation

Safety information is for reference only and does not replace the supplier’s Safety Data Sheet (SDS), applicable regulations, or professional assessment.

GHS classification

GHS Classification · 6 items

This chemical does not meet GHS hazard criteria for 40.9% (47 of 115) of reports.

Danger

H272 (55.7%): May intensify fire; oxidizer [Danger Oxidizing liquids; Oxidizing solids];H315 (10.4%): Causes skin irritation [Warning Skin corrosion/irritation];H319 (11.3%): Causes serious eye irritation [Warning Serious eye damage/eye irritation]

P210, P220, P264, P264+P265, P280, P302+P352, P305+P351+P338, P321, P332+P317, P337+P317, P362+P364, P370+P378, and P501 (click each P-code to see the statement)

Aggregated GHS information provided per 115 reports by companies from 11 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.;Reported as not meeting GHS hazard criteria per 47 of 115 reports by companies.;There are 9 notifications provided by 68 of 115 reports by companies with hazard statement code(s).;Information may vary between notifications depending on impurities, additives, and other factors. The percentage value in parenthesis indicates the notified classification ratio from companies that provide hazard codes. Only hazard codes with percentage values above 10% are shown. For more detailed information, please visit ECHA C&L website.

Hazard information

Regulatory Information · 3 items

Chemical: Nitric acid, magnesium salt, hexahydrate

Nitric acid, magnesium salt, hydrate (2:1:6) is listed on the EPA's Chemical Data Reporting (CDR) system. Manufacturers and importers of Nitric acid, magnesium salt, hydrate (2:1:6) are required to report information about their production and use of this chemical to the EPA under the Toxic Substances Control Act (TSCA). (40 eCFR Part 711)

Magnesium nitrate, hexahydrate: Non hazardous

Other Safety InformationIMAP assessments - Nitric acid, magnesium salt, hexahydrate: Human health tier I assessment
Hazards Summary

Chemistry & industry

Uses & manufacturing

Uses · 2 items

Occurs naturally in the mineral nitromagnesite; Used in pyrotechnics and in the concentration of nitric acid; [Merck Index] Used as a catalyst in petrochemical production, as a sensitizer for lithographic plates, and as a preservative; [ExPub: EPA - Inert Reassessment] Permitted for use as an inert ingredient in non-food pesticide products; [EPA]

Lithography printing [Category: Hobbies]

U.S. Production2023: 33,951 lb;2021: <50,000 lb;2020: 50,000 - <250,000 lb
Consumer UsesFiller
Industry UsesFiller
Household ProductsInformation on 6 consumer products that contain Magnesium nitrate hexahydrate in the following categories is provided:;• Home Office
Use Classification · 2 items

EPA Safer Chemical Functional Use Classes -> Preservatives and Antioxidants

Safer Chemical Classes -> Yellow triangle - The chemical has met Safer Choice Criteria for its functional ingredient-class, but has some hazard profile issues

General Manufacturing InformationPaint and Coating Manufacturing
Applications · 3 items

UsesSodium bisulfate is used for pickling metals; bleaching leather; carbonizing wool; in carbonic acid baths, and manufacturing magnesia cements.

UsesMagnesium nitrate hexahydrate may be used as a starting material for the synthesis of Mg-Al spinel precursors, required for the preparation of magnesium aluminate spinel (MgAl2O4) powder.

General DescriptionMagnesium nitrate hexahydrate is a hydrated magnesium salt. A mixture of magnesium nitrate hexahydrate and magnesium chloride hexahydrate has been reported as a potential phase change material (PCM) for the storage of latent thermal energy. It has been employed as a base material in this mixture to evaluate the storage and effective utilization of urban waste heat from emerged co-generation systems. Its crystals belong to the monoclinic crystal system.

Related reactions

11 records
New reaction record
HRID 1086022 reaction equation
HRID 1086022As productuspto-grants-1991_04
HRID 1086023 reaction equation
HRID 1086023As reactantuspto-grants-1991_04
HRID 1086024 reaction equation
HRID 1086024As productuspto-grants-1991_04
HRID 1086025 reaction equation
HRID 1086025As reactantuspto-grants-1991_04
HRID 1166034 reaction equation
HRID 1166034As reactantuspto-grants-2003_09
HRID 1413031 reaction equation
HRID 1413031As reactantuspto-grants-1981_02
HRID 1577901 reaction equation
HRID 1577901As reactantuspto-grants-1981_09
HRID 1771914 reaction equation
HRID 1771914As reactantuspto-grants-2016_02
Page 1 of 2

Compound notes

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On this pageBasic informationNames & identifiersPropertiesSafety & regulationChemistry & industryRelated reactionsCompound notes
V85K20LJMK
EC Number
603-823-9
PH
5 · 5.0-8.2 (25℃, 50mg/mL in H2O)
Water Solubility
420 g/L · 420 g/L (20 ºC)
Sensitive
Hygroscopic
Merck
14 · 14,5674
BRN
4948473 · 4948473
Stability
Stable. Strong oxidizer - contact with organic material may lead to fire. Do not store near combustible materials. Incompatible with combustible materials, organics, strong reducing agents.
InChI
1S/Mg.2NO3.6H2O/c;2*2-1(3)4;;;;;;/h;;;6*1H2/q+2;2*-1;;;;;;
InChIKey
MFUVDXOKPBAHMC-UHFFFAOYSA-N
SMILES
O.O.O.O.O.O.[Mg++].[O-][N+]([O-])=O.[O-][N+]([O-])=O
CAS DataBase Reference
13446 · 13446-18-9(CAS DataBase Reference)
FDA UNII
85 K20LJMK · V85K20LJMK
EPA Substance Registry System
Magnesium (II) nitrate, hexahydrate (13446-18-9)
Absorption
333 nm · cut-off at 333nm in H2O at 1M
UNSPSC Code
41116107 · 41116107
NACRES
24 · NB.24
Symbol(GHS)
3 · GHS03,GHS05,GHS07
Signal word
Danger
Hazard statements
272 · H272-H290-H314-H332
Precautionary statements
210 · P210-P220-P280-P303+P361+P353-P304+P340+P310-P305+P351+P338
Hazard Codes
C,Xi,O,T
Risk Statements
34 · 34-8-36/37/38-23/24/25
Safety Statements
43 · 43-7/8-37/39-36-17-26-45-36/37/39-23-27
RIDADR
2056 · UN 2056 3/PG 2
WGK Germany
-
RTECS
3756000 · OM3756000
F
3 · 3-9
TSCA
Yes
HazardClass
8 · 8
PackingGroup
III
HS Code
28342980 · 28342980
Storage Class
11 · 11 - Combustible Solids
Toxicity
50 orally · LD50 orally in Rabbit: 5440 mg/kg
· 1 item

A mild skin and eye irritant; [RTECS] An oxidizing agent; [Merck Index] A mild mucous membrane irritant; May cause smarting and reddening of skin if spilled and allowed to remain on clothes; [CHRIS] An oxidizer and irritant; [Acros Organics MSDS] See Magnesium nitrate.

EPA Safer Chemical · 1 item

Chemical: Magnesium (II) nitrate, hexahydrate; Yellow triangle - The chemical has met Safer Choice Criteria for its functional ingredient-class, but has some hazard profile issues. Specifically, a chemical with this code is not associated with a low level of hazard concern for all human health and environmental endpoints. (See Safer Choice Criteria). While it is a best-in-class chemical and among the safest available for a particular function, the function fulfilled by the chemical should be considered an area for safer chemistry innovation.

Hazard Classes and Categories · 3 items

Ox. Liq. 2 (55.7%);Skin Irrit. 2 (10.4%);Eye Irrit. 2 (11.3%)

Oxidizing solids - Category 3;Serious eye damage/eye irritation - Category 2B;Specific target organ toxicity - Single exposure - Category 1 (blood);Specific target organ toxicity - Repeated exposure - Category 1 (blood)

Specific target organ toxicity - Single exposure - Category 1 (haemal system);Specific target organ toxicity - Repeated exposure - Category 1 (haemal system)

Safety & protection

Protective Action Criteria (PAC) · 3 items

16 [mg/m3]

180 [mg/m3]

1100 [mg/m3]

Toxicology

Adverse EffectsMethemoglobinemia - The presence of increased methemoglobin in the blood; the compound is classified as secondary toxic effect

Regulatory information

Regulatory Information · 3 items

Chemical: Nitric acid, magnesium salt, hexahydrate

Nitric acid, magnesium salt, hydrate (2:1:6) is listed on the EPA's Chemical Data Reporting (CDR) system. Manufacturers and importers of Nitric acid, magnesium salt, hydrate (2:1:6) are required to report information about their production and use of this chemical to the EPA under the Toxic Substances Control Act (TSCA). (40 eCFR Part 711)

Magnesium nitrate, hexahydrate: Non hazardous

Safety data

F
3-9
wgk
-
tsca
Yes
rtecs
OM3756000
ridadr
UN 2056 3/PG 2
hs_code
28342980
Toxicity
LD50 orally in Rabbit: 5440 mg/kg
risk_code
34-8-36/37/38-23/24/25
Signal word
Danger
Symbol(GHS)
GHS03,GHS05,GHS07
hazard_code
C,Xi,O,T
safety_code
43-7/8-37/39-36-17-26-45-36/37/39-23-27
hazard_class
8
Storage Class
11 - Combustible Solids
packing_group
III
Hazard statements
H272-H290-H314-H332
Precautionary statements
P210-P220-P280-P303+P361+P353-P304+P340+P310-P305+P351+P338

Upstream & downstream products

Upstream raw materials

Magnesium nitrateMagnesiteNitric acidMagnesium oxide