CAS 7003-32-9 2-Methylcyclohexylamine (HCID 23432)

Names & identifiers

Preferred name: 2-Methylcyclohexylamine
IUPAC: 2-methylcyclohexan-1-amine
English name: 2-Methylcyclohexylamine
Molecular formula: C7H15N
Molecular weight: 113.2

Names & synonyms

2-METHYLCYCLOHEXYLAMINE7003-32-9Cyclohexanamine, 2-methyl-2-Methylcyclohexanamineo-MethylcyclohexylamineCyclohexylamine, 2-methyl-UNII-YBG36S1N5J2-Methylcyclohexylamine,c&t1-Amino-2-methylcyclohexaneEINECS 230-277-5NSC 27455YBG36S1N5J

Show more names

2-MCHAAKOS BB-88212-MethylcyclohexylamHEXAHYDRO-O-TOLUIDINE2-methyl-cyclohexanamin

DTXSID20884349NSC-27455RefChem:88296DTXCID20835235230-277-5FEUISMYEFPANSS-UHFFFAOYSA-N2-methylcyclohexan-1-amineMFCD00001492

Database identifiers

CAS: 7003-32-9
PubChem CID: 23432
DTXSID: DTXSID20884349
EC Number: 230-277-5
Nikkaji: J86.568K

Properties

Computed structural properties

XLogP: 1.6
Topological polar surface area: 26 Å²
Hydrogen bond donors: 1
Hydrogen bond acceptors: 1
Rotatable bonds: 0
Heavy atoms: 8
Formal charge: 0
Complexity: 70.8

Physicochemical properties

Melting point: -8.5 °C · -8.5°C (estimate)
Boiling point: 149 · 149-150 °C(lit.)
Density: 0.859 g/mL · 0.859 g/mL at 20 °C(lit.)
refractive index: 20 · n20/D 1.457
Flash point: 71 °F · 71 °F
storage temp.: Flammables area
pka: 10.72 · 10.72±0.70(Predicted)
form: clear liquid
color: Colorless to Almost colorless
Water Solubility: slightly soluble
Sensitive: Air Sensitive
BRN: 2689073 · 2689073
InChI: 1S/C7H15N/c1-6-4-2-3-5-7(6)8/h6-7H,2-5,8H2,1H3
InChIKey: FEUISMYEFPANSS-UHFFFAOYSA-N
SMILES: CC1CCCCC1N
CAS DataBase Reference: 7003 · 7003-32-9(CAS DataBase Reference)
FDA UNII: 36 S1N5J · YBG36S1N5J
NIST Chemistry Reference: 2 · 2-Methylcyclohexylamine(7003-32-9)
EPA Substance Registry System: 2 · Cyclohexanamine, 2-methyl- (7003-32-9)
UNSPSC Code: 12352100 · 12352100
NACRES: 22 · NA.22
Symbol(GHS): 2 · GHS02,GHS05,GHS07
Signal word: Danger
Hazard statements: 226 · H226-H302-H314
Precautionary statements: 210 · P210-P233-P280-P301+P312-P303+P361+P353-P305+P351+P338
PPE: Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
Hazard Codes: C,F
Risk Statements: 10 · 10-34-37-35-20/21/22-11-22
Safety Statements: 16 · 16-26-36/37/39-45-28A
RIDADR: 2733 · UN 2733 3/PG 2
WGK Germany: 3 · 3
TSCA: TSCA listed
HazardClass: 8 · 8
PackingGroup: II
HS Code: 29213000 · 29213000
Storage Class: 3 · 3 - Flammable liquids
Hazard Classifications: 4 OralFlam · Acute Tox. 4 OralFlam. Liq. 3Skin Corr. 1B
Limited Quantities: 1 L · 1.0 L (0.3 gallons) (liquid) or 1 Kg (2.2 lbs) (solid)
Excepted Quantities: Max Inner Pack (30g or 30ml) and Max Outer Pack (500g or 500ml)

Safety & regulation

GHS classification

GHS Classification · 4 items

Danger

H226 (96.5%): Flammable liquid and vapor [Warning Flammable liquids]

P210, P233, P240, P241, P242, P243, P260, P261, P262, P264, P264+P265, P270, P271, P280, P301+P317, P301+P330+P331, P302+P352, P302+P361+P354, P303+P361+P353, P304+P340, P305+P354+P338, P316, P317, P321, P330, P361+P364, P363, P370+P378, P403+P233, P403+P235, P405, and P501 (click each P-code to see the statement)

Aggregated GHS information provided per 172 reports by companies from 6 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.

Hazard information

Hazard Classes and CategoriesFlam. Liq. 3 (96.5%)

Safety data

PPE: Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
wgk: 3
tsca: TSCA listed
ridadr: UN 2733 3/PG 2
hs_code: 29213000
risk_code: 10-34-37-35-20/21/22-11-22
Signal word: Danger
Symbol(GHS): GHS02,GHS05,GHS07
hazard_code: C,F
safety_code: 16-26-36/37/39-45-28A
hazard_class: 8
Storage Class: 3 - Flammable liquids
packing_group: II
Hazard statements: H226-H302-H314
Limited Quantities: 1.0 L (0.3 gallons) (liquid) or 1 Kg (2.2 lbs) (solid)
Excepted Quantities: Max Inner Pack (30g or 30ml) and Max Outer Pack (500g or 500ml)
Hazard Classifications: Acute Tox. 4 OralFlam. Liq. 3Skin Corr. 1B
Precautionary statements: P210-P233-P280-P301+P312-P303+P361+P353-P305+P351+P338

Chemistry & industry

Uses & manufacturing

General Manufacturing InformationCyclohexanamine, 2-methyl-: ACTIVE

Applications

Uses2-Methylcyclohexylamine is an important raw material and intermediate used in organic synthesis, pharmaceuticals, agrochemicals and dyestuff fields.

General DescriptionMechanism of hydrodenitrogenation of 2-methylcyclohexylamine has been studied over sulfided NiMo/Al2O3. 2-Methylcyclohexylamine is the intermediate formed during hydrodenitrogenation of toluidine.