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Cesium bromide

HCID 24592
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Basic information

CAS
7787-69-1
Standard SMILES
[Br-].[Cs+]
InChIKey
LYQFWZFBNBDLEO-UHFFFAOYSA-M
Molecular formula
BrCs
Average molar mass
212.81 g/mol
Monoisotopic mass
211.82379

Overview

Cesium bromide is an chemical compound of caesium and bromine. It is used in optics as a beamsplitter component in wide-band spectrophotometers. Bromine is a halogen element with the symbol Br and atomic number 35. Diatomic bromine does not occur naturally, but bromine salts can be found in crustal rock. (L625, L645)

Names & identifiers

Preferred name
Cesium bromide
IUPAC
cesium bromide
English name
Cesium bromide
Molecular formula
BrCs
Molecular weight
212.80945

Names & synonyms

CESIUM BROMIDE7787-69-1Caesium bromideCesium bromide (CsBr)Tricesium tribromideBromocaesium06M25EDM3FNSC-84269DTXSID8064854RefChem:124634DTXCID0048058232-130-0
Show more names
Cesiumbromidecesium;bromideCsBrBrCscesium monobromideEINECS 232-130-0cesium(I) bromideUNII-06M25EDM3F

Database identifiers

CAS
7787-69-1
PubChem CID
24592
DTXSID
DTXSID8064854
UNII
06M25EDM3F
EC Number
232-130-0
Nikkaji
J43.756E

Properties

Computed structural properties

Topological polar surface area
0 Ų
Hydrogen bond donors
0
Hydrogen bond acceptors
1
Rotatable bonds
0
Heavy atoms
2
Formal charge
0
Complexity
2

Experimental & physicochemical properties

Chemical ClassesMetals -> Metals, Inorganic Compounds
SpringerMaterials Propertiesdielectric constant
Physical DescriptionSolid; [Merck Index] Hygroscopic beads; [Sigma-Aldrich MSDS]

Physicochemical properties

Melting point
636 °C · 636 °C

Safety & regulation

Safety information is for reference only and does not replace the supplier’s Safety Data Sheet (SDS), applicable regulations, or professional assessment.

GHS classification

GHS Classification · 5 items

This chemical does not meet GHS hazard criteria for 34.2% (26 of 76) of reports.

Warning

H302 (11.8%): Harmful if swallowed [Warning Acute toxicity, oral]

P261, P264, P264+P265, P270, P271, P280, P301+P317, P302+P352, P304+P340, P305+P351+P338, P319, P321, P330, P332+P317, P337+P317, P362+P364, P403+P233, P405, and P501 (click each P-code to see the statement)

Aggregated GHS information provided per 76 reports by companies from 10 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.

Hazard information

Regulatory Information · 2 items

Chemical: Cesium bromide (CsBr)

Caesium bromide: Does not have an individual approval but may be used under an appropriate group standard

Other Safety InformationEvaluation - Cesium salts
Hazards SummaryA skin and strong eye irritant; [Sigma-Aldrich MSDS] See Cesium.
Hazard Classes and CategoriesAcute Tox. 4 (11.8%)

Toxicology

Treatment · 1 item

EYES: irrigate opened eyes for several minutes under running water. INGESTION: do not induce vomiting. Rinse mouth with water (never give anything by mouth to an unconscious person). Seek immediate medical advice. SKIN: should be treated immediately by rinsing the affected parts in cold running water for at least 15 minutes, followed by thorough washing with soap and water. If necessary, the person should shower and change contaminated clothing and shoes, and then must seek medical attention. INHALATION: supply fresh air. If required provide artificial respiration.

Chemistry & industry

Pharmacology

Metabolism/Metabolites · 1 item

Bromine is mainly absorbed via inhalation, but may also enter the body through dermal contact. Bromine salts can be ingested. Due to its reactivity, bromine quickly forms bromide and may be deposited in the tissues, displacing other halogens. (L626)

Uses & manufacturing

Uses · 2 items

In x-ray fluorescent screens, spectrometer prisms, and absorption-cell windows. [Merck Index]

Caesium bromide is used in optics as a beamsplitter component in wide-band spectrophotometers. (L645)

General Manufacturing InformationCesium bromide (CsBr): ACTIVE

Related reactions

1 records
New reaction record
HRID 1077611 reaction equation
HRID 1077611As reactantuspto-grants-1996_08

Compound notes

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Health Effects · 1 item

Bromine vapour causes irritation and direct damage to the mucous membranes. Elemental bromine also burns the skin. The bromide ion is a central nervous system depressant and chronic exposure produces neuronal effects. This is called bromism and can result in central reactions reaching from somnolence to coma, cachexia, exicosis, loss of reflexes or pathologic reflexes, clonic seizures, tremor, ataxia, loss of neural sensitivity, paresis, papillar edema of the eyes, abnormal speech, cerebral edema, delirium, aggressiveness, and psychoses. (L625, L626, L627)

Exposure RoutesOral (L626) ; inhalation (L626) ; dermal (L626)
Toxicity Summary · 1 item

Bromine is a powerful oxidizing agent and is able to release oxygen free radicals from the water in mucous membranes. These free radicals are also potent oxidizers and produce tissue damage. In additon, the formation of hydrobromic and bromic acids will result in secondary irritation. The bromide ion is also known to affect the central nervous system, causing bromism. This is believed to be a result of bromide ions substituting for chloride ions in the in actions of neurotransmitters and transport systems, thus affecting numerous synaptic processes. (L626, L627, A543)

Signs and Symptoms · 1 item

Bromine vapour causes irritation and direct damage to the mucous membranes. Symptoms include lacrimation, rhinorrhoea, eye irritation with mucous secretions from the oropharyngeal and upper airways, coughing, dyspnoea, choking, wheezing, epistaxis, and headache. The bromide ion is a central nervous system depressant producing ataxia, slurred speech, tremor, nausea, vomiting, lethargy, dizziness, visual disturbances, unsteadiness, headaches, impaired memory and concentration, disorientation and hallucinations. This is called bromism. (L626, L627)

Carcinogen ClassificationNo indication of carcinogenicity to humans (not listed by IARC).