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Cadmium iodide

HCID 24635
NotesReactions
Basic informationOverviewNames & identifiersPropertiesSafety & regulationChemistry & industryRelated reactionsCompound notes
Substructure searchFind similar structures

Basic information

CAS
7790-80-9
Standard SMILES
[Cd+2].[I-].[I-]
InChIKey
OKIIEJOIXGHUKX-UHFFFAOYSA-L
Molecular formula
CdI2
Average molar mass
366.22 g/mol
Monoisotopic mass
367.71231

Overview

Cadmium iodide is an iodide of cadmium that can be made by heating cadmium with iodine. It is used in lithography, photography, electroplating and the manufacturing of phosphors. Cadmium is a transition metal and chemical element with the symbol Cd and atomic number 48. It is found naturally in the earth's crust, though rarely on it's own. (L6, L469)

Names & identifiers

Preferred name
Cadmium iodide
IUPAC
cadmium(2+) diiodide
English name
Cadmium iodide
Molecular formula
CdI2
Molecular weight
366.22

Names & synonyms

CADMIUM IODIDE7790-80-9Cadmium diiodideCadmium iodide (CdI2)2F2UPU4KCWDTXSID20894887diiodocadmiumRefChem:122578DTXCID501324446232-223-6cadmium(2+);diiodideCadmium(II) iodide
Show more names
CdI2CadmiumjodidIodo cadmiumCadium iodideCadmium lodidecadmiumdiiodideGermanium lodideCADMIUM IODIDE GRCadmiumiodide,99%
MFCD00010920CadmiumiodideCadmium diiodide, Cadmiumdiiodid, Cadmium iodide (CdI2), cadmium(2+) diiodide, CADMIUM(II) IODIDECadmium Iodide PowderCADMIUM IODATUMUltra Dry Cadmium IodideCADMIUM IODIDE [MI]SCHEMBL20297

Database identifiers

CAS
7790-80-9
PubChem CID
24635
DTXSID
DTXSID20894887
UNII
2F2UPU4KCW
EC Number
232-223-6
Nikkaji
J43.714J

Properties

Computed structural properties

Topological polar surface area
0 Ų
Hydrogen bond donors
0
Hydrogen bond acceptors
2
Rotatable bonds
0
Heavy atoms
3
Formal charge
0
Complexity
0

Experimental & physicochemical properties

Chemical ClassesMetals -> Cadmium Compounds, Inorganic
SpringerMaterials Propertiesphonon wavenumber
Physical DescriptionWhite odorless solid; Turns yellow on contact with air and light; [Hawley] Light green odorless powder; [MSDSonline]

Physicochemical properties

Melting point
388 °C · 388 °C (lit.)
Boiling point
787 °C · 787 °C (lit.)
Density
5.67 g/mL · 5.67 g/mL at 25 °C (lit.)
Flash point
787 °C · 787°C
storage temp.
2 · 2-8°C, protect from light, stored under nitrogen
solubility
It is soluble in ethanol, acetone, ether and ammonia.
form
beads
color
White to yellow
Specific Gravity
5.67 · 5.67
Water Solubility

Safety & regulation

Safety information is for reference only and does not replace the supplier’s Safety Data Sheet (SDS), applicable regulations, or professional assessment.

GHS classification

GHS Classification · 6 items

Danger

H301: Toxic if swallowed [Danger Acute toxicity, oral]

P203, P260, P261, P264, P270, P271, P273, P280, P301+P316, P304+P340, P316, P318, P319, P321, P330, P391, P403+P233, P405, and P501 (click each P-code to see the statement)

Danger

H301 (100%): Toxic if swallowed [Danger Acute toxicity, oral]

P203, P260, P261, P264, P270, P271, P273, P280, P301+P316, P304+P340, P316, P318, P319, P321, P330, P391, P403+P233, P405, and P501 (click each P-code to see the statement)

Hazard information

Regulatory Information · 3 items

Chemical: Cadmium iodide (CdI2)

Restricted substance: Cadmium iodide

Cadmium iodide: Does not have an individual approval but may be used under an appropriate group standard

Other Safety InformationIMAP assessments - Cadmium iodide (CdI2): Human health tier II assessment
Hazards SummaryAn irritant; Danger of cumulative effects after ingestion or inhalation; Oral LD50 (rat) = 222 mg/kg; [MSDSonline] See Cadmium and the linked diseases. See Iodine for the TLV of Iodides.
Hazard Classes and Categories · 4 items

Acute Tox. 3 (100%)

Acute toxicity - category 3

Acute toxicity (Oral) - Category 3

Carc. 2

Safety & protection

Exposure Control and Personal Protection · 1 item

Biological Exposure Indices (BEI) [ACGIH] - Cd in urine = 5 ug/g creatinine; Cd in blood = 5 ug/L; sampling time not critical; Monitoring in blood should be preferred during the initial year of exposure and whenever changes in the degree of exposure are suspected. [ACGIH]

Chemistry & industry

Pharmacology

Metabolism/Metabolites · 1 item

Cadmium is absorbed from oral, inhalation, and dermal routes. Cadmium initially binds to metallothionein and albumin and is transported mainly to the kidney and liver. Toxic effects are observed once the concentration of cadmium exceeds that of available metallothionein, and it has also been shown that the cadmium-metallothionein complex may be damaging. Cadmium is not known to undergo any direct metabolic conversion and is excreted unchanged, mainly in the urine. (L6)

Uses & manufacturing

Uses · 4 items

Used in photography, process engraving, lithography, analytical chemistry, and electroplating; Also used as in lubricants, phosphors, and nematocides; [Hawley] Used for cadmium electrodeposition and in photoconductors; [Merck Index] Use is highly restricted in the EU; [eChemPortal: ESIS: EDEXIM]

Electroplating [Category: Plate]

Lithography printing [Category: Hobbies]

Cadmium iodide is used in lithography, photography, electroplating and the manufacturing of phosphors. (L469)

General Manufacturing InformationCadmium iodide (CdI2): ACTIVE
Applications · 5 items

DescriptionCadmium iodide (chemical formula: CdI2) is a chemical compound consisting of cadmium and iodine element. It appears as a green-yellow solid, being soluble in water, alcohol, ether, acetone, ammonia, and acid. It is a compound with the typical crystal structure of the form MX2, exhibiting strong polarization effects. It has many applications such as being used in lithography, photography, electroplating, process engraving, analytical chemistry, electrodeposition of cadium as well as the manufacturing of phosphor and lubricants. It is manufactured through the reaction between cadmium metal, or its oxide, hydroxide or carbonate and hydroiodic acid.

UsesCadmium iodide is used in lithography, photography, electroplating and the manufacturing of phosphors, in engraving process, and was used as an antiseptic and astringent.

Related reactions

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Compound notes

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On this pageBasic informationOverviewNames & identifiersPropertiesSafety & regulationChemistry & industryRelated reactionsCompound notes
Very soluble in water, slightly soluble in acetone, ethanol and diethyl ether.
Specific Heat Capacity
0.22 J/ · Cp(crystal): 0.22 J/(g·K), at 25℃
Sensitive
Hygroscopic
Merck
14 · 14,1621
Exposure limits
0.01 mg/m3; · ACGIH: TWA 0.01 mg/m3; TWA 0.002 mg/m3; TWA 0.01 ppmNIOSH: IDLH 9 mg/m3
InChI
1S/Cd.2HI/h;2*1H/q+2;;/p-2
InChIKey
OKIIEJOIXGHUKX-UHFFFAOYSA-L
SMILES
I[Cd]I
REACH Annex XVII Substances List
Cadmium iodide (7790-80-9)
CAS DataBase Reference
7790 · 7790-80-9(CAS DataBase Reference)
EWG's Food Scores
2 · 2
FDA UNII
2 F2UPU4KCW · 2F2UPU4KCW
EPA Substance Registry System
Cadmium iodide (7790-80-9)
UNSPSC Code
12352302 · 12352302
NACRES
23 · NA.23
Symbol(GHS)
6 · GHS06,GHS08,GHS09
Signal word
Danger
Hazard statements
301 · H301+H331-H351-H373-H410
Precautionary statements
201 · P201-P202-P260-P273-P301+P310-P304+P340+P311
PPE
2 · Eyeshields, Faceshields, Gloves, type P2 (EN 143) respirator cartridges
Hazard Codes
T,N
Risk Statements
23 · 23/25-33-50/53-68/20/22-68
Safety Statements
22 · 22-45-60-61
RIDADR
2570 · UN 2570 6.1/PG 3
WGK Germany
3 · 3
RTECS
1290000 · EV1290000
TSCA
TSCA listed
HazardClass
6.1 · 6.1
PackingGroup
III
HS Code
28276000 · 28276000
Storage Class
6.1 C · 6.1C - Combustible acute toxic Cat.3toxic compounds or compounds which causing chronic effects
Hazard Classifications
3 InhalationAcute · Acute Tox. 3 InhalationAcute Tox. 3 OralAquatic Acute 1Aquatic Chronic 1Carc. 2STOT RE 2
Limited Quantities
5 L · 5.0 L (1.3 gallons) (liquid) or 5.0 kg (11 lbs) (solid)
Excepted Quantities
Max Inner Pack (30g or 30ml) and Max Outer Pack (1Kg or 1L)
Minimum Risk LevelAcute Inhalation: 0.00003 mg/m3 (L134) Chronic Inhalation: 0.00001 mg/m3 (L134) Intermediate Oral: 0.0005 mg/kg/day (L134) Chronic Oral: 0.0001 mg/kg/day (L134)
Threshold Limit Values (TLV)0.01 [mg/m3], as Cd ( 0.002 mg/m3, as Cd, respirable fraction) [0.01 ppm, inhalable fraction and vapor (iodides)]
Permissible Exposure Limit (PEL)0.005 [mg/m3], as Cd, see 29 CFR 1910.1027
Immediately Dangerous to Life or Health (IDLH)9.0 [mg/m3], as Cd

Toxicology

TreatmentCadmium poisoning is treated by removal from exposure and supportive care. If ingested, induced vomiting or gastric lavage may be performed. (L139)
Health EffectsChronic exposure to cadmium fumes can cause chemical pneumonitis, pulmonary edema, and lung diseases such as bronchitis and emphysema. Cadmium also accumulates in the kidneys, causing permanent damage. Loss of bone density also occurs. (L6)
Adverse EffectsNephrotoxin - The chemical is potentially toxic to the kidneys in the occupational setting.
Exposure RoutesOral (L6) ; inhalation (L6) ; dermal (L6)
Toxicity Summary · 1 item

Cadmium initially binds to metallothionein and is transported to the kidney. Toxic effects are observed once the concentration of cadmium exceeds that of available metallothionein, and it has also been shown that the cadmium-metallothionein complex may be damaging. Accumulation of cadmium in the kidney results in increased excretion of vital low and high weight molecular proteins. Cadmium is a high affinity zinc analog and can interfere in its biological processes. It also binds to and activates the estrogen receptor, likely stimulating the growth of certain types of cancer cells and causing other estrogenic effects, such as reproductive dysfunction. Cadmium causes cell apoptosis by activating mitogen-activated protein kinases. (L8, A18, A19, A28)

Signs and SymptomsAcute inhalation of cadmium fumes results in metal fume fever, which is characterized by chills, fever, headache, weakness, dryness of the nose and throat, chest pain, and coughing. Ingestion of cadmium causes vomiting and diarrhea. (L6)
Carcinogen Classification1, carcinogenic to humans. (L135)
Toxicity DataLD50: 4708 mg/kg (Oral, Rat) (L470)

Safety data

PPE
Eyeshields, Faceshields, Gloves, type P2 (EN 143) respirator cartridges
wgk
3
tsca
TSCA listed
rtecs
EV1290000
ridadr
UN 2570 6.1/PG 3
hs_code
28276000
risk_code
23/25-33-50/53-68/20/22-68
Signal word
Danger
Symbol(GHS)
GHS06,GHS08,GHS09
hazard_code
T,N
safety_code
22-45-60-61
hazard_class
6.1
Storage Class
6.1C - Combustible acute toxic Cat.3toxic compounds or compounds which causing chronic effects
packing_group
III
Hazard statements
H301+H331-H351-H373-H410
Limited Quantities
5.0 L (1.3 gallons) (liquid) or 5.0 kg (11 lbs) (solid)
Excepted Quantities
Max Inner Pack (30g or 30ml) and Max Outer Pack (1Kg or 1L)
Hazard Classifications
Acute Tox. 3 InhalationAcute Tox. 3 OralAquatic Acute 1Aquatic Chronic 1Carc. 2STOT RE 2
Precautionary statements
P201-P202-P260-P273-P301+P310-P304+P340+P311

UsesUsed in photography, analytical chemistry, manufacturing of phosphors, lubricants

UsesIn electrodeposition of Cd; as nematocide; in manufacture of phosphors; as lubricant; in photoconductors; in photography, process engraving; lithography; in analytical chemistry.

UsesMade by the action of hydriodic acid on cadmium oxide and crystallization. The colorless, flaky crystals are soluble in water, alcohol, and ether. This halide was a common iodizer for collodion formulas, particularly for negatives.

Preparation methods · 1 item

PreparationCadmium iodide is prepared by the addition of cadmium metal, or its oxide, hydroxide, nitrate or carbonate to hydriodic acid: CdO + 2HI → CdI2 + H2O Also, the compound can be made by heating cadmium with iodine: Cd +I2 → CdI2 A brownish crystalline β-form of the salt may be obtained by slow crystallization from solutions or fused salt mixtures.

Suppliers100 total

国药集团化学试剂有限公司86-21-63210123 · [email protected]
上海阿拉丁生化科技股份有限公司400-6206333 13167063860 · [email protected]
南通润丰石油化工有限公司66017690 19952660367 · [email protected]
Career Henan Chemica Co+86-0371-86658258 +86-13203830695 · [email protected]
天津市光复科技发展有限公司022-85689490 13132141716 · [email protected]
武汉欣扬瑞和化学科技有限公司153-07155313 15307155313 · [email protected]
INTATRADE GmbH+49 3493/605464 · [email protected]
江苏星科元信息科技有限公司400-605-7200 15335295587 · [email protected]
Dayang Chem (Hangzhou) Co.,Ltd.+86-0571-88938639 17705817739 · [email protected]
衢州明锋化工有限公司0570-3062502 13819002126;13819008176 · [email protected]
毕佳索(上海毕得医药科技股份有限公司)400-6005915 · [email protected]
上海迈瑞尔生化科技有限公司4006356688 18621169109 · [email protected]
江苏普乐司生物科技有限公司0513-66017706 18551496367 · [email protected]
武汉易泰科技有限公司上海分公司18930552037 · [email protected]
江西瑞威尔生物科技有限公司18502762009 · [email protected]
阿法埃莎(中国)化学有限公司400-6106006 · [email protected]
安耐吉化学&3A(安徽泽升科技股份有限公司)400-0056266 · [email protected]
广东云星生物技术有限公司0751-18902340975/189023400307 18902340307 · [email protected]
上海瀚鸿科技股份有限公司021-54306202 13764082696 · [email protected]
上海景颜化工科技有限公司13817811078 · [email protected]
山东西亚化学有限公司13355009207 13355009207 · [email protected]
四川库利南科技有限公司400-1166-196 18981987031 · [email protected]
南京化学试剂股份有限公司025-58369808 17895012682 · [email protected]
斯百全化学(上海)有限公司021-021-021-67601398-809-809-809 15221380277 · [email protected]
艾科试剂4008-755-333 18080918076 · [email protected]
赛默飞世尔科技(中国)有限公司800-810-5118 · [email protected]
深圳康特腾科技有限公司86-0755-86635001 · [email protected]
武汉普洛夫生物科技有限公司17612776928 · [email protected]
上海将来实业股份有限公司400-0066400 13621662912 · [email protected]
上海将来实业股份有限公司021-61552785 · [email protected]
安徽科迪达化工有限公司0554-2106669 · [email protected]
日照力德士化工有限公司010-51268198 · [email protected]
美岚实业(上海)有限公司021-58958189 · [email protected]
上海爱蝶实业有限公司021-58957966 18930537195 · [email protected]
广拓化学(上海)有限公司021-60899189-8001 18918189673 · [email protected]
上海麦克林生化科技股份有限公司15221275939 15221275939 · [email protected]
成都润泽本土化工有限公司13096311329 028-88469284 616445927 · [email protected]
Sigma-Aldrich西格玛奥德里奇(上海)贸易有限公司021-61415566 800-8193336 · [email protected]
九鼎化学(上海)科技有限公司4009209199 · [email protected]
上海谱振生物科技有限公司4001650900 13817534909 · [email protected]
上海卜微应用材料技术有限公司021-64112762 18930491979 · [email protected]
武汉鑫儒化工有限公司15927387915 15337108568 · [email protected]
上海玻尔化学试剂有限公司19102157732 · [email protected]
sgtlifesciences pvt ltd+91-8790379245 · [email protected]
四川普西奥标物科技有限公司13540909846 13882008651 · [email protected]
成都润泽本土化工有限公司028-88469284 18000562381 · [email protected]
上海西陇生化科技有限公司021-52907766-8042
上海源叶生物科技有限公司18916372613 · [email protected]
武汉克米克生物医药技术有限公司027-13163388153 13163388153 · [email protected]
山东西亚化学有限公司4009903999 13395398332 · [email protected]