Sodium tetrametaphosphate

HCID 25951

Basic information

CAS
13396-41-3
Standard SMILES
O=P1([O-])OP(=O)([O-])OP(=O)([O-])OP(=O)([O-])O1.[Na+].[Na+].[Na+].[Na+]
InChIKey
UDEJEOLNSNYQSX-UHFFFAOYSA-J
Molecular formula
Na4O12P4
Average molar mass
407.85 g/mol
Monoisotopic mass
407.79309908

Overview

RN given refers to metaphosphoric acid, tetra-Na salt

Names & identifiers

Preferred name
Sodium tetrametaphosphate
IUPAC
tetrasodium;2,4,6,8-tetraoxido-1,3,5,7,2λ5,4λ5,6λ5,8λ5-tetraoxatetraphosphocane 2,4,6,8-tetraoxide
English name
Sodium Tetrametaphosphate
Molecular formula
Na4O12P4
Molecular weight
407.846924

Names & synonyms

CyclofosSODIUM TETRAMETAPHOSPHATE13396-41-3Tetrasodium cyclotetraphosphateMetaphosphoric acid (H4P4O12), tetrasodium saltTetrasodium tetrametaphosphateSodium tetrametaphosphate (Na4P4O12)Tetrametaphosphoric acid, tetrasodium saltSodium cyclotetraphosphate (Na4(P4O12))Metaphosphoric acid, tetrasodium saltSodium cyclotetraphosphate (Na4P4O12)MLC36A7X39
Show more names
CyclophosTetrasodium tetramethaphosphateMetaphosphoric acid, tetrasodium salt.2,4,6,8-Tetrakis(sodiooxy)-1,3,5,7-tetraoxa-2,4,6,8-tetraphosphacyclooctane-2,4,6,8-tetronetetrasodium,2,4,6,8-tetraoxido-1,3,5,7,2λ5,4λ5,6λ5,8λ5-tetraoxatetraphosphocane 2,4,6,8-tetraoxide
Tetrametaphosphoric acid (H4P4O12), tetrasodium saltDTXSID5074507RefChem:184124DTXCID2034174236-482-6Sodium metaphosphate (Na4P4O12)HSDB 773EINECS 236-482-6

Database identifiers

CAS
13396-41-3
PubChem CID
25951
DTXSID
DTXSID5074507
UNII
MLC36A7X39
EC Number
236-482-6
Nikkaji
J317.855B

Properties

Computed structural properties

Topological polar surface area
197 Ų
Hydrogen bond donors
0
Hydrogen bond acceptors
12
Rotatable bonds
0
Heavy atoms
20

Experimental & physicochemical properties

Chemical ClassesMetals -> Phosphates, Metallic Salts

Physicochemical properties

FDA UNII
36 A7X39 · MLC36A7X39
EPA Substance Registry System
Metaphosphoric acid (H4P4O12), tetrasodium salt (13396-41-3)
Hazardous Substances Data
13396 · 13396-41-3(Hazardous Substances Data)

Safety & regulation

Hazard information

Hazards Summary · 1 item

Emergency treatment: Inorganic phosphates; Inorganic phosphates can cause diarrhea, hyperphosphatemia, and hypocalcemia after ingestion; An adult died after receiving four sodium phosphate enemas within 24 hours; he had electrolyte abnormalities and died from cardiac arrest; [HSDB]

Safety & protection

Disposal Methods · 1 item

SRP: At the time of review, criteria for land treatment or burial (sanitary landfill) disposal practices are subject to significant revision. Prior to implementing land disposal of waste residue (including waste sludge), consult with environmental regulatory agencies for guidance on acceptable disposal practices.

Safety data

Hazardous Substances Data
13396-41-3(Hazardous Substances Data)

Chemistry & industry

Uses & manufacturing

Uses · 4 items

Used in household detergents, water conditioning, toothpaste, processed cheese, and additives in meat, fish, and poultry; [HSDB]

PHOSPHATE BUILDER IN HOUSEHOLD DETERGENTS; AGENT IN WATER CONDITIONING; ADDITIVE IN MEAT, FISH, POULTRY, & PROCESSED CHEESE; ABRASIVE IN TOOTHPASTE

Sequestrants; emulsifiers; textile processing; laundering /Sodium metaphosphate polymers/

Used in substitute dairy products for one or more of the following purposes: to alter buffering capacity of the system; to improve the stability of the protein to calcium ions; to improve the heat stability of the protein; to minimize the age gelatin of ultra-high temperature-(UHT) processed substitute products; to serve as emulsifying salts in imitation cheese manufacturing; and to modify the after-bonding capacity of protein and improve stability.

U.S. Production(1972) 1.08X10+10 GRAMS (INCL HEXA & POLY)
Consumption Patterns(INCL ALL SODIUM METAPHOSPHATES) 69% FOR BUILDERS & WATER TREATMENT; 12% FOR DENTIFRICES; 8% FOR CLAY PROCESSING; 7% FOR FOODS; 4% FOR MISCELLANEOUS USES (1972)
Methods of ManufacturingPREPD BY DEHYDRATION OF SODIUM PHOSPHATES (EG NA2H2P2O7, NAH2PO4, NA2HPO4). SEVERAL DIFFERENT FORMS ARE KNOWN.
General Manufacturing Information · 4 items

(NaPO3)n, where n ranges from 3-10 (cyclic molecules) or may be a much larger number (polymers). Cyclic sodium metaphosphate, based on rings of alternating phosphorus & oxygen atoms, range from trimetaphosphate, (NaPO3)3, to at least decametaphosphate.

Vitreous sodium phosphates having Na2O/P2O5 mole ratio near unity are classified as sodium metaphosphates (Graham's Salts). Average number of phosphorus atoms per molecules in these glasses ranges from about 25 to infinity.

The term sodium metaphosphate has also been extended to short-chain vitreous compositions, molecules of which exhibit polyphosphate formula Na(n+2)P(n)O3(n+1) with n as low as 4-5. These materials are more correctly called sodium polyphosphates.

THERE ARE NUMBER OF PROPOSED FOOD APPLICATIONS FOR CMPD, BUT NO APPLICATION HAS THUS FAR BEEN THOUGHT IMPORTANT ENOUGH TO BE APPROVED FOR USE IN FOODS BY US FDA.

Applications

UsesSodium Tetrametaphosphate is a sequestrant and emulsifier that is infinitely soluble in water. It is used as a water binder in cured pork. It is also termed graham’s salt.

Suppliers2 total

陕西缔都新材料有限公司029-63373950 17392216152 · [email protected]
DAYANG CHEM (HANGZHOU) CO.,LTD+86-88938639 +86-17705817739 · [email protected]

Related reactions

2 records

Compound notes

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