Basic information
- CAS
13939-06-5- Standard SMILES
[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[Mo]- InChIKey
KMKBZNSIJQWHJA-UHFFFAOYSA-N- Molecular formula
- C6MoO6
- Average molar mass
- 264.01 g/mol
- Monoisotopic mass
- 265.874891
Overview
C6-O6-Mo
Names & identifiers
- Preferred name
- Molybdenum hexacarbonyl
- IUPAC
- carbon monoxide;molybdenum
- English name
- Molybdenum hexacarbonyl
- Molecular formula
- C6MoO6
- Molecular weight
- 264
Names & synonyms
13939-06-5HexacarbonylmolybdenumMo(CO)6RefChem:145901237-713-3CHEBI:30508Molybdenum carbonyl (Mo(CO)6), (OC-6-11)-Molybdenum hexacarbonylMolybdenumhexacarbonylMolybdenum carbonylcarbon monoxide;molybdenumC6MoO6
Show more names
Hexacarbonylmolybdenum(0)MOLYBDENUM (VI) HEXACARBONYLMolybdenum carbonyl (Mo(CO)6)ybdenum hexacarbonyLMolybdenumcarbonyl,98%Molybdenum carbonyl 98%
hexakis(methanidylidyneoxidanium) molybdenumSCHEMBL2225813STR06546AKOS037655893FM159155F050113
Database identifiers
- CAS
13939-06-5- PubChem CID
- 2724068
- EC Number
- 237-713-3
Properties
Computed structural properties
- Topological polar surface area
- 6 Ų
- Hydrogen bond donors
- 0
- Hydrogen bond acceptors
- 6
- Rotatable bonds
- 0
- Heavy atoms
- 13
- Formal charge
- 0
- Complexity
- 10
Experimental & physicochemical properties
Chemical ClassesMetals -> Metals, Organic Compounds
Vapor Pressure9.75 [mmHg]
Physical DescriptionWhite solid; [Hawley]
Physicochemical properties
- Melting point
- 150 °C · 150 °C (dec.) (lit.)
- Boiling point
- 156 °C · 156 °C (lit.)
- Density
- 1.96 g/mL · 1.96 g/mL at 25 °C (lit.)
- vapor density
- 9.1 · 9.1 (vs air)
- vapor pressure
- 0.13 hPa · 0.13 hPa (20 °C)
- storage temp.
- 20 °C · Store at <= 20°C.
- solubility
- Slightly soluble in tetrahydrofuran, diglyme and acetonitrile.
- form
- crystal
- color
- white
- Specific Gravity
- 1.96 · 1.960
- Water Solubility
Safety & regulation
Safety information is for reference only and does not replace the supplier’s Safety Data Sheet (SDS), applicable regulations, or professional assessment.
GHS classification
GHS Classification
Danger
H300 (98.6%): Fatal if swallowed [Danger Acute toxicity, oral]
P260, P262, P264, P270, P271, P280, P284, P301+P316, P302+P352, P304+P340, P316, P320, P321, P330, P361+P364, P403+P233, P405, and P501 (click each P-code to see the statement)
Aggregated GHS information provided per 71 reports by companies from 4 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.
Hazard information
Regulatory Information
Chemical: Molybdenum carbonyl (Mo(CO)6), (OC-6-11)-
Molybdenum carbonyl (Mo(CO)6), (OC-6-11)-: Does not have an individual approval but may be used under an appropriate group standard
Hazards SummaryToxic by ingestion; May be harmful if absorbed through skin or inhaled; A skin, eye, and respiratory tract irritant; [MSDSonline] See Chromium hexacarbonyl. See Molybdenum.
Hazard Classes and CategoriesAcute Tox. 2 (98.6%)
Safety & protection
Protective Action Criteria (PAC)
1.2 [mg/m3]
13 [mg/m3]
79 [mg/m3]
Safety data
- PPE
- Eyeshields, Faceshields, Gloves, type P2 (EN 143) respirator cartridges
- wgk
- 3
- tsca
- TSCA listed
Chemistry & industry
Uses & manufacturing
Uses
Used in molybdenum plating; [Hawley]
Electroplating [Category: Plate]
General Manufacturing InformationMolybdenum carbonyl (Mo(CO)6), (OC-6-11)-: ACTIVE
Applications
UsesPlating molybdenum, i.e., molybdenum mir-rors; intermediate.
UsesIt is used as a catalyst in many organicsynthetic reactions.
UsesAlumina supported molybdenum hexacarbonyl acts as an active catalyst. It is used to synthesize MoO and MoC nanowires by electron beam induced deposition.
General DescriptionMolybdenum hexacarbonyl is a colorless compound that sublimates and decomposes without melting at 150oC. It has an octahedral structure. Inherent sublimation of molybdenum hexacarbonyl permits it to perform as an active liquefaction catalyst. To form a catalyst it is adsorbed on dehydroxylated alumina forming subcarboyls.
Suppliers100 total
国药集团化学试剂有限公司86-21-63210123 · [email protected]
阿诺西（上海）生物技术有限公司400-1107768 15058188853 · [email protected]
上海源象化学有限公司17312431727 · [email protected]
湖北永阔科技有限公司027-59223108 15972152991 · [email protected]
韶远科技(上海)有限公司4000665055 · [email protected]
Related reactions
0 records
No reaction records under the current filter.
Compound notes
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