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Fluorosilicate

HCID 28117
NotesReactions
Basic informationOverviewNames & identifiersPropertiesSafety & regulationChemistry & industryRelated reactionsCompound notes
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Basic information

CAS
17084-08-1
Standard SMILES
F[Si-2](F)(F)(F)(F)F
InChIKey
OHORFAFFMDIQRR-UHFFFAOYSA-N
Molecular formula
F6Si-2
Average molar mass
142.075 g/mol
Monoisotopic mass
141.96734551

Overview

Fluorosilicates, n.o.s. appears as a crystalline solid or the solid dissolved in a liquid. Denser than water. Contact may irritate skin, eyes and mucous membranes. May be toxic by ingestion. Used to make other chemicals.

Names & identifiers

Preferred name
Fluorosilicate
IUPAC
hexafluorosilicon(2-)
English name
Fluorosilicate
Molecular formula
Cs2F6Si
Molecular weight
407.89

Names & synonyms

Fluorosilicate17084-08-1RefChem:1085448Hexafluorosilicate(2-)hexafluorosilicon(2-)Silicon hexafluoride ionHexafluorosilicate(2-) ionhexafluoridosilicate(2-)SILICATE(2-), HEXAFLUORO-CESIUM HEXAFLUORO SILICATEUN2856hexafluoridosilicate(IV)
Show more names
fluosilicatesilicofluoridehexafluorosilicatesiliconhexafluorideionhexafluoro-silicate(2-hexafluorosilicate(2-)ionFluorosilicate ISO 9001:2015 REACH
Fluorosilicates, n.o.s.SCHEMBL41972412SiF6(2-)CHEBI:37189[SiF6](2-)NS00086685Fluorosilicates, n.o.s. [UN2856] [Poison]Q27117065

Database identifiers

CAS
17084-08-1
PubChem CID
28117
DTXSID
DTXSID8047214
ChEBI
CHEBI:37189
Nikkaji
J283.200C

Properties

Computed structural properties

Topological polar surface area
0 Ų
Hydrogen bond donors
0
Hydrogen bond acceptors
7
Rotatable bonds
0
Heavy atoms
7
Formal charge
-2
Complexity
62.7

Experimental & physicochemical properties

PFASPFAS -> Other/unspecified
Physical DescriptionFluorosilicates, n.o.s. appears as a crystalline solid or the solid dissolved in a liquid. Denser than water. Contact may irritate skin, eyes and mucous membranes. May be toxic by ingestion. Used to make other chemicals.

Physicochemical properties

Density
4.75 g/cm3 · 4.75 g/cm3
Solubility Product Constant (Ksp)
4.9 · pKsp: 4.9
EPA Substance Registry System
Silicate(2-), hexafluoro- (17084-08-1)

Safety & regulation

Safety information is for reference only and does not replace the supplier’s Safety Data Sheet (SDS), applicable regulations, or professional assessment.

Hazard information

DOT LabelPoison
Fire HazardsExcerpt from ERG Guide 151 [Substances - Toxic (Non-Combustible)]:
Health HazardsExcerpt from ERG Guide 151 [Substances - Toxic (Non-Combustible)]:
Reactive GroupFluoride Salts, Soluble
Reactivity AlertsWater-Reactive
Reactivity Profile · 1 item

Fluorosilicates react with water to generate hydrofluoric acid and silicic acid, and are thus sources of soluble fluoride ions. Unlike other halide ions, fluoride is quite reactive, acting as a weak base and participating in some unique reactions. In particular, fluorides react strongly with compounds containing calcium, magnesium, or silicon ions, which means that solutions containing soluble fluorides are corrosive to both living tissue and glass. Hydrofluoric acid can cause severe chemical burns and is one of the few materials that can etch glass. It is also a toxic gas in its anhydrous form.

Air and Water ReactionsSlightly soluble in water. Forms heavy clouds with moist air, decomposed by water into silicic acid and hydrofluoric acid [Merck 11th ed. 1989].

Safety & protection

Fire FightingExcerpt from ERG Guide 151 [Substances - Toxic (Non-Combustible)]:
First AidExcerpt from ERG Guide 151 [Substances - Toxic (Non-Combustible)]:
Nonfire Spill Response

Chemistry & industry

Applications

General DescriptionA crystalline solid or the solid dissolved in a liquid. Denser than water. Contact may irritate skin, eyes and mucous membranes. May be toxic by ingestion. Used to make other chemicals.

Suppliers13 total

普善实业(陕西)有限公司029-81310890 18165209495 · [email protected]
苏州市森菲达化工有限公司18796480002 18796480002 · [email protected]
湖北成海化工有限公司027-59220433 18327245847 · [email protected]
陕西缔都医药化工有限公司029-029-81120477 17792793610 · [email protected]
陕西缔都医药化工有限公司+86-29-81139210 +86-17392587031 · [email protected]
金锦乐(湖南)化学有限公司18001959627(微信同号) 18001959627 · [email protected]
湖北摆渡化学有限公司027-59106051 13627137652 · [email protected]
爆牛贸易重庆有限公司+86-023-6139-8061 +86-86-13650506873 · [email protected]
XIAMEN AMITY INDUSTRY AND TRADE CO., LTD.+8618950047208 · [email protected]
DAYANG CHEM (HANGZHOU) CO.,LTD+86-88938639 +86-17705817739 · [email protected]
榆林润天畅化工有限责任公司15890142075 15890142075 · [email protected]
Hefei TNJ Chemical Industry Co.,Ltd.

Related reactions

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Compound notes

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On this pageBasic informationOverviewNames & identifiersPropertiesSafety & regulationChemistry & industryRelated reactionsCompound notes
Excerpt from ERG Guide 151 [Substances - Toxic (Non-Combustible)]:
Isolation and EvacuationExcerpt from ERG Guide 151 [Substances - Toxic (Non-Combustible)]:
Personal Protective Equipment (PPE)Excerpt from ERG Guide 151 [Substances - Toxic (Non-Combustible)]:
+86-0551-65418671 +86-189 4982 3763 · [email protected]
陕西奥博利辉新材料科技有限公司0917-18691729 18691729963 · [email protected]

Additional notes

DefinitionAny salt of fluorosilic acid.