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Tetraethylene glycol diacrylate

HCID 28803
NotesReactions
Basic informationOverviewNames & identifiersPropertiesSafety & regulationChemistry & industryRelated reactionsCompound notes
Substructure searchFind similar structures

Basic information

CAS
17831-71-9
Standard SMILES
C=CC(=O)OCCOCCOCCOCCOC(=O)C=C
InChIKey
HCLJOFJIQIJXHS-UHFFFAOYSA-N
Molecular formula
C14H22O7
Average molar mass
302.32 g/mol
Monoisotopic mass
302.13655304

Overview

Tetraethylene glycol diacrylate is a pale yellow liquid. (NTP, 1992)

Names & identifiers

Preferred name
Tetraethylene glycol diacrylate
IUPAC
2-[2-[2-(2-prop-2-enoyloxyethoxy)ethoxy]ethoxy]ethyl prop-2-enoate
English name
Tetra(ethylene glycol) diacrylate
Molecular formula
C14H22O7
Molecular weight
302.32

Names & synonyms

17831-71-9TETRAETHYLENE GLYCOL DIACRYLATEViscoat 335HPAronix M 240SR 268DTXSID2026107Acrylic acid, diester with tetraethylene glycolAcrylic acid, oxybis(ethyleneoxyethylene) ester2-Propenoic acid, oxybis(2,1-ethanediyloxy-2,1-ethanediyl) esterDTXCID606107RefChem:188577Tetra(ethylene glycol) diacrylate
Show more names
POLYETHYLENE GLYCOL 400 DIACRYLATEPOLYETHYLENE GLYCOL 200 DIACRYLATEsr268aronixm240viscoat335hpPOLYETHYLENE GLYCOL 1000 DIACRYLATEPOLYETHYLENE GLYCOL (600) DIACRYLATEPOLY(ETHYLENE GLYCOL) (N) DIACRYLATE
Tetraethyleneglycol diacrylate2-[2-[2-(2-prop-2-enoyloxyethoxy)ethoxy]ethoxy]ethyl prop-2-enoateTTEGDA2-Propenoic acid, 1,1'-[oxybis(2,1-ethanediyloxy-2,1-ethanediyl)] esterMFCD00008630Tetraethylene Glycol Diacrylate (stabilized with MEHQ)((Oxybis(ethane-2,1-diyl))bis(oxy))bis(ethane-2,1-diyl) diacrylateEINECS 241-789-3

Database identifiers

Properties

Computed structural properties

XLogP
0.7
Topological polar surface area
80.3 Ų
Hydrogen bond donors
0
Hydrogen bond acceptors
7
Rotatable bonds
16
Heavy atoms
21
Formal charge
0
Complexity
284

Experimental & physicochemical properties

PolymersPlastics & Rubber -> (Meth)acrylates
LogP0.47
Density1.125 @25 °C
SolubilityInsoluble (<1 mg/ml) (NTP, 1992)
Flash Pointless than 65 °F (NTP, 1992)
Melting Point112 °C
Vapor Pressure0.00289 [mmHg]
Physical Description · 3 items

Tetraethylene glycol diacrylate is a pale yellow liquid. (NTP, 1992)

Liquid

Clear liquid with a musty odor; [MSDSonline]

Physicochemical properties

Melting point
12 · 12-17 °C
Boiling point
363.35 °C · 363.35°C (rough estimate)

Safety & regulation

Safety information is for reference only and does not replace the supplier’s Safety Data Sheet (SDS), applicable regulations, or professional assessment.

GHS classification

GHS Classification · 4 items

Danger

H302 (88.4%): Harmful if swallowed [Warning Acute toxicity, oral]

P260, P261, P264, P264+P265, P270, P272, P280, P301+P317, P301+P330+P331, P302+P352, P302+P361+P354, P304+P340, P305+P351+P338, P305+P354+P338, P316, P317, P321, P330, P332+P317, P333+P317, P337+P317, P362+P364, P363, P405, and P501 (click each P-code to see the statement)

Aggregated GHS information provided per 129 reports by companies from 10 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.

Hazard information

Regulatory Information · 4 items

Chemical: 2-Propenoic acid, oxybis(2,1-ethanediyloxy-2,1-ethanediyl) ester

2-Propenoic acid, 1,1'-[oxybis(2,1-ethanediyloxy-2,1-ethanediyl)] ester is listed on the EPA's Chemical Data Reporting (CDR) system. Manufacturers and importers of 2-Propenoic acid, 1,1'-[oxybis(2,1-ethanediyloxy-2,1-ethanediyl)] ester are required to report information about their production and use of this chemical to the EPA under the Toxic Substances Control Act (TSCA). (40 eCFR Part 711)

Status: Active Update: 09-12-2021 https://echa.europa.eu/registration-dossier/-/registered-dossier/23295

Tetraethylene glycol diacrylate: Does not have an individual approval but may be used as a component in a product covered by a group standard. It is not approved for use as a chemical in its own right.

DOT LabelCorrosive
Fire HazardsThis chemical is flammable. (NTP, 1992)
Health HazardsExcerpt from ERG Guide 154 [Substances - Toxic and/or Corrosive (Non-Combustible)]:
Hazards Summary · 1 item

A skin and eye irritant; May cause skin sensitization; [eChemPortal: ERMA; ESIS] Corrosive to skin and eyes; Can be absrobed through skin; May cause skin sensitization; [MSDSonline] Extremely irritating to eyes; Causes serious eye injuries in animal experiments; Suspected skin sensitizer; [AIHA] See ACRYLIC RESINS (MONOMERS).

Chemistry & industry

Uses & manufacturing

Uses · 2 items

Used in inks, coatings, and adhesives cured by ultra-violet light; [AIHA]

Painting (Pigments, Binders, and Biocides) [Category: Paint]

U.S. Production2023: <50,000 lb
Consumer UsesMonomers
Industry UsesMonomers
General Manufacturing Information · 2 items

Adhesive Manufacturing

2-Propenoic acid, 1,1'-[oxybis(2,1-ethanediyloxy-2,1-ethanediyl)] ester: ACTIVE

Applications

UsesTetra(ethylene glycol) diacrylate is a long-chain hydrophilic, crosslinking monomer widely used in the preparation of gel polymer electrolytes for Li-ion polymer batteries, acrylic polymers, and coating materials.

General DescriptionPale yellow liquid.

Suppliers81 total

梯希爱(上海)化成工业发展有限公司021-67121386 · [email protected]
郑州阿尔法化工有限公司+86-18530059196 · [email protected]
上海阿拉丁生化科技股份有限公司400-6206333 13167063860 · [email protected]
Hebei Chuanghai Biotechnology Co., Ltd+86-17732866630 · [email protected]
广州纳珑化工有限公司13192879270; 13192879270 · [email protected]

Related reactions

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New reaction record

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Compound notes

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On this pageBasic informationOverviewNames & identifiersPropertiesSafety & regulationChemistry & industryRelated reactionsCompound notes
CAS
17831-71-9
PubChem CID
28803
DTXSID
DTXSID2026107
ChEMBL
CHEMBL1492729
EC Number
241-789-3
Nikkaji
J287.163G
Density
1.11 g/mL · 1.11 g/mL at 25 °C(lit.)
vapor pressure
0 Pa · 0Pa at 20℃
refractive index
20 · n20/D 1.47
Flash point
347 °F · 347 °F
solubility
2 O: · H2O: soluble
form
clear liquid
color
Colorless to Light yellow
Viscosity
20 cp · 20 cp (25C)
Water Solubility
95.6 g/L · 95.6g/L at 20℃
α-end
acrylate
Ω-end
acrylate
Cosmetics Ingredients Functions
PLASTICISER
InChI
1S/C14H22O7/c1-3-13(15)20-11-9-18-7-5-17-6-8-19-10-12-21-14(16)4-2/h3-4H,1-2,5-12H2
InChIKey
HCLJOFJIQIJXHS-UHFFFAOYSA-N
SMILES
C=CC(=O)OCCOCCOCCOCCOC(=O)C=C
LogP
0.814 at · 0.814 at 40℃
CAS DataBase Reference
17831 · 17831-71-9
FDA UNII
40 OE44A24 · E40OE44A24
EPA Substance Registry System
Tetraethylene glycol diacrylate (17831-71-9)
UNSPSC Code
12162002 · 12162002
NACRES
23 · NA.23
Symbol(GHS)
7 · GHS07
Signal word
Warning
Hazard statements
302 · H302-H317
Precautionary statements
261 · P261-P264-P270-P280-P301+P312-P302+P352
PPE
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
Hazard Codes
C
Risk Statements
41 · 41-34-22
Safety Statements
26 · 26-36/37/39-45-28-27
RIDADR
1760 · UN 1760 8/PG 2
WGK Germany
2 · 2
RTECS
8100000 · AS8100000
TSCA
TSCA listed
HazardClass
8 · 8
PackingGroup
III
HS Code
29161290 · 29161290
Storage Class
10 · 10 - Combustible liquids
Hazard Classifications
4 OralSkin · Acute Tox. 4 OralSkin Sens. 1
REACH Registrations
Active
Reactive GroupEsters, Sulfate Esters, Phosphate Esters, Thiophosphate Esters, and Borate Esters
Reactivity Profile · 1 item

An ester. Esters react with acids to liberate heat along with alcohols and acids. Strong oxidizing acids may cause a vigorous reaction that is sufficiently exothermic to ignite the reaction products. Heat is also generated by the interaction of esters with caustic solutions. Flammable hydrogen is generated by mixing esters with alkali metals and hydrides.

Air and Water ReactionsInsoluble in water.
Hazard Classes and CategoriesAcute Tox. 4 (88.4%)

Safety & protection

Fire FightingFires involving this compound should be controlled with a dry chemical, carbon dioxide or halon extinguisher. (NTP, 1992)
First Aid · 1 item

EYES: First check the victim for contact lenses and remove if present. Flush victim's eyes with water or normal saline solution for 20 to 30 minutes while simultaneously calling a hospital or poison control center. Do not put any ointments, oils, or medication in the victim's eyes without specific instructions from a physician. IMMEDIATELY transport the victim after flushing eyes to a hospital even if no symptoms (such as redness or irritation) develop.

Nonfire Spill Response · 1 item

SMALL SPILLS AND LEAKAGE: If you should spill this chemical, use absorbent paper to pick up all liquid spill material. Seal the absorbent paper, as well as any of your clothing which may be contaminated, in a vapor-tight plastic bag for eventual disposal. Wash any surfaces you may have contaminated with a strong soap and water solution. Do not reenter the contaminated area until the Safety Officer (or other responsible person) has verified that the area has been properly cleaned.

Isolation and EvacuationExcerpt from ERG Guide 154 [Substances - Toxic and/or Corrosive (Non-Combustible)]:
Protective Action Criteria (PAC) · 3 items

3.0 [mg/m3]

27 [mg/m3]

160 [mg/m3]

Personal Protective Equipment (PPE) · 1 item

RECOMMENDED RESPIRATOR: Where the neat test chemical is weighed and diluted, wear a NIOSH-approved half face respirator equipped with an organic vapor/acid gas cartridge (specific for organic vapors, HCl, acid gas and SO2) with a dust/mist filter. (NTP, 1992)

Toxicology

Adverse EffectsSkin Sensitizer - An agent that can induce an allergic reaction in the skin.

Safety data

PPE
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
wgk
2
tsca
TSCA listed
rtecs
AS8100000
ridadr
UN 1760 8/PG 2
hs_code
29161290
risk_code
41-34-22
Signal word
Warning
Symbol(GHS)
GHS07
hazard_code
C
safety_code
26-36/37/39-45-28-27
hazard_class
8
Storage Class
10 - Combustible liquids
packing_group
III
Hazard statements
H302-H317
REACH Registrations
Active
Hazard Classifications
Acute Tox. 4 OralSkin Sens. 1
Precautionary statements
P261-P264-P270-P280-P301+P312-P302+P352
武汉欣扬瑞和化学科技有限公司
153-07155313 15307155313 · [email protected]
杭州品高化工有限公司0571-87658025 · [email protected]
河北创海生物科技有限公司+86-86-13131129325 · [email protected]
江苏星科元信息科技有限公司400-605-7200 15335295587 · [email protected]
爱斯特(成都)生物制药股份有限公司+86-28-85122536 85324413 · [email protected]
上海仲因实业有限公司2537653158 16621191650 · [email protected]
Dayang Chem (Hangzhou) Co.,Ltd.+86-0571-88938639 17705817739 · [email protected]
Hebei Yanxi Chemical Co., Ltd.+86-17531190177 · [email protected]
上海赛可锐生物科技有限公司021-58000709 13120558703 · [email protected]
上海迈瑞尔生化科技有限公司4006356688 18621169109 · [email protected]
上海颖心实验室设备有限公司021-59178156 17002132182 · [email protected]
安耐吉化学&3A(安徽泽升科技股份有限公司)400-0056266 · [email protected]
广东云星生物技术有限公司0751-18902340975/189023400307 18902340307 · [email protected]
广东方信生物科技有限公司0751-2838688 13376594225 · [email protected]
上海维亦特生物科技有限公司15317051735 · [email protected]
湖北微斯汀科技有限公司027-61182895 13367240285 · [email protected]
玛雅试剂+86 (573) 82222445 (0)18006601000 452520369 · [email protected]
四川库利南科技有限公司400-1166-196 18981987031 · [email protected]
天津希恩思生化科技有限公司400 638 7771 · [email protected]
杭州云易国科生物科技有限公司18457506494 · [email protected]
湖南汇百侍生物科技有限公司0731-85526065 13308475853 · [email protected]
TOKYO CHEMICAL INDUSTRY CO., LTD.03-36680489 · [email protected]
深圳振强药物研发有限公司0755-66853366 13670046396 · [email protected]
苏州亚科科技股份有限公司0512-87182055 13451648594 · [email protected]
深圳菲斯生物科技有限公司0755-83725350 13380397412 · [email protected]
天津普西唐生物医药科技有限公司010-60605840 · [email protected]
上海麦克林生化科技股份有限公司15221275939 15221275939 · [email protected]
盖米科技(青岛)有限公司19524370118 · [email protected]
普善实业(陕西)有限公司029-81310890 18165209495 · [email protected]
Sigma-Aldrich西格玛奥德里奇(上海)贸易有限公司021-61415566 800-8193336 · [email protected]
九鼎化学(上海)科技有限公司4009209199 · [email protected]
上海谱振生物科技有限公司4001650900 13817534909 · [email protected]
广东翁江化学试剂有限公司0751-2815987 13927875076 · [email protected]
Alfa Chemistry+1-5166625404 · [email protected]
上海珈得尔化学技术有限公司13564435016 13564435016 · [email protected]
陕西缔都医药化工有限公司029-029-81120477 17792793610 · [email protected]
启源(广东)医药化工有限公司18026564465 · [email protected]
安那莱(齐河)新材料科技有限公司18600642180(微信同) 13391601435 · [email protected]
成都远大化工有限公司028-85356300 18980937689 · [email protected]
南通市苏北化工原料有限公司0513-85290972 18762756250 · [email protected]
上海源叶生物科技有限公司18916372613 · [email protected]
湖北鑫杰成化工科技有限公司18008658050 18008658050 · [email protected]
山东西亚化学有限公司4009903999 13395398332 · [email protected]
武汉卡诺斯科技有限公司18064039730 · [email protected]
广州市金华大化学试剂有限公司020-84383047 · [email protected]