Methane

HCID 297CAS 74-82-8

Basic information

Standard SMILES
C
InChIKey
VNWKTOKETHGBQD-UHFFFAOYSA-N
Molecular formula
CH4
Average molar mass
16.043 g/mol
Monoisotopic mass
16.03130013

Overview

Methane is a colorless odorless gas. It is also known as marsh gas or methyl hydride. It is easily ignited. The vapors are lighter than air. Under prolonged exposure to fire or intense heat the containers may rupture violently and rocket. It is used in making other chemicals and as a constituent of the fuel, natural gas.

Names & identifiers

Preferred name
Methane
IUPAC
methane
English name
Methane
Molecular formula
CH4
Molecular weight
0

Names & synonyms

methaneMarsh gasMethyl hydrideFire DampBiogas74-82-8R 50 (refrigerant)metanotetrahydridocarbonHSDB 167Methane in gaseus stateUN1972
Show more names
BRN 1718732OP0UW79H66UN1971CH4DTXSID8025545UNII-OP0UW79H66CHEBI:16183R 50

Database identifiers

CAS
74-82-8、8006-14-2
PubChem CID
297
DTXSID
DTXSID8025545
ChEMBL
CHEMBL17564
ChEBI
CHEBI:16183
UNII
OP0UW79H66
EC Number
200-812-7、927-905-1
Nikkaji
J2.228.533E、J2.380I、J3.470.363I、J593B、J68.119I

Properties

Computed structural properties

XLogP
0.6
Topological polar surface area
0 Ų
Hydrogen bond donors
0
Hydrogen bond acceptors
0
Rotatable bonds
0
Heavy atoms
1

Experimental & physicochemical properties

Chemical Classes · 2 items

Toxic Gases & Vapors -> Simple Asphyxiants

Flammable agents - 4th degree

SpringerMaterials PropertiesDunham energy parameter
LogP · 3 items

log Kow = 1.09

1.09

1.09

Odor · 2 items

Odorless

Weak odor

TasteTasteless
Density · 4 items

0.415 to 0.45 at -259.6 °F (USCG, 1999)

0.422 at -256 °F (USCG, 1999) - Less dense than water; will float

0.554 at 0 °C/4 °C (air = 1 ) or 0.7168 g/liter

0.4228 @ -162°C

Physicochemical properties

Melting point
-182.6 °C · -182.6 °C
Boiling point
-161.4 °C · -161.4 °C
Density
0.7168 g/cm3 · 0.7168 g/cm3
Symbol(GHS)
2 · GHS02,GHS04
Signal word
Danger
Hazard statements
220 · H220-H280

Safety & regulation

GHS classification

GHS Classification · 6 items

Danger

H220: Extremely flammable gas [Danger Flammable gases]

P203, P210, P222, P280, P377, P381, and P403 (click each P-code to see the statement)

Danger

H220 (100%): Extremely flammable gas [Danger Flammable gases]

P203, P210, P222, P280, P282, P336+P317, P377, P381, P403, and P410+P403 (click each P-code to see the statement)

Hazard information

Regulatory Information · 5 items

Chemical: Methane

Methane is listed on the EPA's Chemical Data Reporting (CDR) system. Manufacturers and importers of Methane are required to report information about their production and use of this chemical to the EPA under the Toxic Substances Control Act (TSCA). (40 eCFR Part 711)

Status: Active Update: 23-03-2023 https://echa.europa.eu/registration-dossier/-/registered-dossier/14250

Methane or natural gas but excluding refrigerated liquid methane or natural gas: HSNO Approval: HSR001005 Approved with controls

The New Jersey Worker and Community Right to Know Act requires public and private employers to provide information about hazardous substances at their workplaces. (N.J.S.A. 34:5A-1 et. seq.)

Other Safety InformationIMAP assessments - Methane: Human health tier I assessment
DOT Label · 4 items

Flammable Gas

Flammable Gas

Flammable Gas

Flammable Gas

Fire Hazards · 6 items

Excerpt from ERG Guide 115 [Gases - Flammable (Including Refrigerated Liquids)]:

Special Hazards of Combustion Products: None (USCG, 1999)

Excerpt from ERG Guide 115 [Gases - Flammable (Including Refrigerated Liquids)]:

Excerpt from ERG Guide 115 [Gases - Flammable (Including Refrigerated Liquids)]:

· EXTREMELY FLAMMABLE.

· EXTREMELY FLAMMABLE.

Fire Potential · 2 items

Very dangerous fire and explosion hazard when exposed to heat or flame.

Flammable in the presence of an oxidizing gas (eg air), a source of ignition, and when the concentration of the gas is between the lower and upper explosive limits. Keep away from heat/sparks/open flame/hotsurface/oxidizing gas. No smoking.

Health Hazards · 6 items

If concentration of gas is high enough, may cause asphyxiation. No detectable systemic effects, even at 5% concentration in air. (USCG, 1999)

High concentrations may cause asphyxiation. No systemic effects, even at 5% concentration in air. (USCG, 1999)

Excerpt from ERG Guide 115 [Gases - Flammable (Including Refrigerated Liquids)]:

Excerpt from ERG Guide 115 [Gases - Flammable (Including Refrigerated Liquids)]:

· Vapors may cause dizziness or asphyxiation without warning, especially when in closed or confined areas.

· Vapors may cause dizziness or asphyxiation without warning, especially when in closed or confined areas.

Safety & protection

Fire Fighting · 5 items

Excerpt from ERG Guide 115 [Gases - Flammable (Including Refrigerated Liquids)]:

Excerpt from ERG Guide 115 [Gases - Flammable (Including Refrigerated Liquids)]:

Excerpt from ERG Guide 115 [Gases - Flammable (Including Refrigerated Liquids)]:

Excerpt from ERG Guide 115 [Gases - Flammable (Including Refrigerated Liquids)]:

Shut off supply; if not possible and no risk to surroundings, let the fire burn itself out. In other cases extinguish with water spray, powder, carbon dioxide. In case of fire: keep cylinder cool by spraying with water. Combat fire from a sheltered position.

First Aid Measures · 3 items

Fresh air, rest. Artificial respiration may be needed. Refer for medical attention.

ON FROSTBITE: rinse with plenty of water, do NOT remove clothes. Refer for medical attention .

First rinse with plenty of water for several minutes (remove contact lenses if easily possible), then refer for medical attention.

Accidental Release Measures · 4 items

· CALL 911. Then call emergency response telephone number on shipping paper. If shipping paper not available or no answer, refer to appropriate telephone number listed on the inside back cover.

· ELIMINATE all ignition sources (no smoking, flares, sparks or flames) from immediate area.

· CALL 911. Then call emergency response telephone number on shipping paper. If shipping paper not available or no answer, refer to appropriate telephone number listed on the inside back cover.

· ELIMINATE all ignition sources (no smoking, flares, sparks or flames) from immediate area.

First Aid · 6 items

Remove victim to open air. If he is overcome by gas, apply artificial resuscitation. (USCG, 1999)

EYES: First check the victim for contact lenses and remove if present. Flush victim's eyes with water or normal saline solution for 20 to 30 minutes while simultaneously calling a hospital or poison control center. Do not put any ointments, oils, or medication in the victim's eyes without specific instructions from a physician. IMMEDIATELY transport the victim after flushing eyes to a hospital even if no symptoms (such as redness or irritation) develop.

Excerpt from ERG Guide 115 [Gases - Flammable (Including Refrigerated Liquids)]:

Excerpt from ERG Guide 115 [Gases - Flammable (Including Refrigerated Liquids)]:

General First Aid:

General First Aid:

Safe StorageFireproof. Cool. Ventilation along the floor and ceiling.
Exposure Control and Personal Protection · 2 items

· Wear positive pressure self-contained breathing apparatus (SCBA).

· Wear positive pressure self-contained breathing apparatus (SCBA).

Toxicology

TreatmentAsphyxiation should be treated by moving the affected person to an uncontaminated area, then giving artificial respiration and administering oxygen, if necessary. (L173)
Health EffectsMethane is an asphyxiant and displaces oxygen in enclosed spaces. At high enough concentrations, oxygen depletion may cause asphyxiation, resulting in generalized hypoxia and possibly death. (L171, L172)
Environmental Fate · 3 items

TERRESTRIAL FATE: Based on a classification scheme(1), an estimated Koc value of 9(SRC), determined from a log Kow of 1.09(2) and a regression-derived equation(3), indicates that methane is expected to have very high mobility in soil(SRC). Volatilization of methane from moist soil surfaces is expected to be an important fate process(SRC) given an estimated Henry's Law constant of 0.66 atm-cu m/mole(SRC), derived from its vapor pressure, 4.66X10+5 mm Hg(4), and water solubility, 22 mg/L(5). Methane is expected to volatilize from dry soil surfaces(SRC) based upon its vapor pressure(4). An average utilization of 55% for methane by anaerobic soil microorganisms(6) suggests that biodegradation may be an environmental fate process in soil(SRC).

AQUATIC FATE: Based on a classification scheme(1), an estimated Koc value of 9(SRC), determined from a log Kow of 1.09(2) and a regression-derived equation(3), indicates that methane is not expected to adsorb to suspended solids and sediment(SRC). Volatilization from water surfaces is expected(4) based upon an estimated Henry's Law constant of 0.66 atm-cu m/mole(SRC), derived from its vapor pressure, 4.66X10+5 mm Hg(5), and water solubility, 22 mg/L(6). Using this Henry's Law constant and an estimation method(4), volatilization half-lives for a model river and model lake are 2 hours(SRC). According to a classification scheme(7), an estimated BCF of 2(SRC), from its log Kow(2) and a regression-derived equation(3), suggests the potential for bioconcentration in aquatic organisms is low(SRC). The biodegradation half-life of methane was estimated to range from 70 days to infinity in model anaerobic estuarine ecosystems(8), indicating that biodegradation is not an important environmental fate process in water(SRC).

ATMOSPHERIC FATE: According to a model of gas/particle partitioning of semivolatile organic compounds in the atmosphere(1), methane, which has a vapor pressure of 4.66X10+5 mm Hg at 25 °C(2), is expected to exist solely as a gas in the ambient atmosphere. Gas-phase methane is degraded in the atmosphere by reaction with photochemically-produced hydroxyl radicals(SRC); the half-life for this reaction in air is estimated to be 4 yrs(3), calculated from its rate constant of 6.85X10-15 cu cm/molecule-sec at 25 °C(4). Methane does not contain chromophores that absorb at wavelengths >290 nm(5) and, therefore, is not expected to be susceptible to direct photolysis by sunlight(SRC).

Adverse EffectsOther Poison - Simple Asphyxiant
Exposure Routes · 2 items

The substance can be absorbed into the body by inhalation.

Inhalation (L172)

Toxicity Summary · 1 item

Methane is an asphyxiant and displaces oxygen in enclosed spaces. At high enough concentrations, oxygen depletion may cause asphyxiation. Low concentrations of surrounding oxygen results in deficient oxygen to the organs, compounded by increased oxygen exhalation during respiration. This results in generalized hypoxia and possibly death. (L171, A120)

Regulatory information

DHS Chemicals of Interest (COI) · 4 items

Methane

1

10000

Flammable chemical that can be released at a facility.

Safety data

Signal word
Danger
Symbol(GHS)
GHS02,GHS04
Hazard statements
H220-H280
Precautionary statements
P210-P377-P381-P410+P403

Chemistry & industry

Pharmacology

Metabolism/Metabolites · 3 items

Methane is absorbed through the lungs in mammals. when inhaled, the majority of the absorbed dose is exhaled unchanged. A small amount of methane is converted to methanol and ultimately to carbon dioxide. Uptake in humans is less rapid than in the rat.

Small amt of methane undergoes metabolism to methanol and ultimately to carbon dioxide.

Methane is biologically inactive. (L172)

Absorption, Distribution and Excretion · 2 items

The pharmacokinetics of methane ... would probably be similar to that reported for ethane.

Methane has been demonstrated to be absorbed through the lungs in mammals.

Tissue LocationsAdipose Tissue
Cellular LocationsCytoplasm

Uses & manufacturing

Uses · 6 items

In the USA 85% of natural gas is methane. [Merck Index] Produced by decaying matter in swamps and marshes; [Hawley]

Mining [Category: Industry]

Smoking cigarettes [Category: Food & Drugs]

In the production of methanol

Constituent of illuminating and cooking gas; in manufacture of hydrogen, hydrogen cyanide, ammonia, acetylene, formaldehyde, in organic syntheses.

Chemical intermediate (excluding fuel use); constituent of natural gas (about 85% methane); ... halogenated methanes, carbon disulfide, sodium hydrosulfide, carbon black

ImpuritiesMethanol and carbon monoxide
U.S. Exports · 3 items

(1972) 7.8X10+10 CU FT (NATURAL GAS)

(1975) 7.0X10+10 CU FT (NATURAL GAS)

(1984) 1.70X10+11 g /NATURAL GAS, METHANE AND MIXTURES THERE OF INCLUDING SYNTHETIC NATURAL GAS/

U.S. Imports · 4 items

(1972) 1.02X10+12 CU FT (NATURAL GAS)

(1975) 9.7X10+11 CU FT (NATURAL GAS)

(1984) 3.80X10+11 g /NATURAL GAS, METHANE AND MIXTURES THEREOF INCLUDING SYNTHETIC NATURAL GAS/

(1986) 7.26X10+8 mcf /Natural gas, methane and mixtures thereof including synthetic natural gas/

U.S. Production · 6 items

2023: 4,000,000,000 - <5,500,000,000 lb

(1972) 2.25X10+13 CU FT (NATURAL GAS)

(1975) 2.01X10+13 CU FT (NATURAL GAS)

(1982) 509.1 MILLION BARRELS

Methane is listed as a High Production Volume (HPV) chemical (65FR81686). Chemicals listed as HPV were produced in or imported into the U.S. in >1 million pounds in 1990 and/or 1994. The HPV list is based on the 1990 Inventory Update Rule. (IUR) (40 CFR part 710 subpart B; 51FR21438).

For more U.S. Production (Complete) data for METHANE (7 total), please visit the HSDB record page.

Consumer UsesFuel

Suppliers33 total

安徽旺山旺水特种气体有限公司15906197626 · [email protected]
江西核研院新材料有限公司18901398682 18901398682 · [email protected]
湖南省华中特种气体有限公司0734-8755555 15674722888 · [email protected]
Shanghai Enviko Biotechnologyg Co.,Ltd+86-13918629532 +86-13918629532 · [email protected]
济南源茂化工有限公司15665725027 18854103888 · [email protected]
Additional notes · 1 item

DefinitionChEBI: Methane is a one-carbon compound in which the carbon is attached by single bonds to four hydrogen atoms. It is a colourless, odourless, non-toxic but flammable gas (b.p. -161℃). It has a role as a fossil fuel, a member of greenhouse gas and a bacterial metabolite. It is a mononuclear parent hydride, a one-carbon compound, a gas molecular entity and an alkane. It is a conjugate acid of a methanide.

Related reactions

4,433 records

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