Basic information
- CAS
122-56-5- Standard SMILES
CCCCB(CCCC)CCCC- InChIKey
CMHHITPYCHHOGT-UHFFFAOYSA-N- Molecular formula
- C12H27B
- Average molar mass
- 182.16 g/mol
- Monoisotopic mass
- 182.22058126
Names & identifiers
- Preferred name
- Tributylborane
- IUPAC
- tributylborane
- English name
- TRIBUTYLBORANE
- Molecular formula
- C12H27B
- Molecular weight
- 182.15
Names & synonyms
Tributylborane122-56-5Tri-n-butylboraneBORANE, TRIBUTYL-TributylborineDTXSID9059543RefChem:190787DTXCID2033730204-554-6TributylboronTri-n-butyl boraneTributylborane (1.0 M in THF)
Show more names
Boronbutoxidetributyl-boranBorane,tributyl-tri-n-butylborane,
Tri-n-butylboronCCRIS 4133EINECS 204-554-6BRN 1738107TBB; Tri-n-butylborane; Tri-n-butylboron; Tributylboron;tributyl-boraneTributyl boraneSCHEMBL1237
Database identifiers
- CAS
122-56-5- PubChem CID
- 31216
- DTXSID
DTXSID9059543- EC Number
- 204-554-6
- Nikkaji
- J55.477D
Properties
Computed structural properties
- Topological polar surface area
- 0 Ų
- Hydrogen bond donors
- 0
- Hydrogen bond acceptors
- 0
- Rotatable bonds
- 9
- Heavy atoms
- 13
- Formal charge
- 0
- Complexity
- 72.1
Experimental & physicochemical properties
Chemical ClassesMetals -> Metalloid Compounds (Boron)
Physical DescriptionLiquid; [Sigma-Aldrich MSDS]
Physicochemical properties
- Melting point
- -34 °C · -34 °C
- Boiling point
- 109 °C20 · 109 °C20 mm Hg(lit.)
- Density
- 0.834 g/mL · 0.834 g/mL at 25 °C
- refractive index
- 1.4285 · 1.4285
- Flash point
- 1 °F · 1 °F
- storage temp.
- Flammables area
- solubility
- Benzene, Tetrahydrofuran
- form
- Solution
- color
- Clear colorless to light yellow
- Water Solubility
- Not miscible or difficult to mix with water.
- Sensitive
- Air Sensitive
- InChI
- 1S/C12H27B/c1-4-7-10-13(11-8-5-2)12-9-6-3/h4-12H2,1-3H3
- InChIKey
- CMHHITPYCHHOGT-UHFFFAOYSA-N
- SMILES
- CCCCB(CCCC)CCCC
- CAS DataBase Reference
- 122 · 122-56-5
- EWG's Food Scores
- 1 · 1
- EPA Substance Registry System
- Borane, tributyl- (122-56-5)
- UNSPSC Code
- 12352001 · 12352001
- NACRES
- 22 · NA.22
- Symbol(GHS)
- 2 · GHS02,GHS05
- Signal word
- Danger
- Hazard statements
- 250 · H250-H314-H318
- Precautionary statements
- 210 · P210-P222-P231+P232-P233-P280-P260-P264-P302+P334-P370+P378-P301+P330+P331-P303+P361+P353-P363-P304+P340-P310-P305+P351+P338-P405-P501
- PPE
- Eyeshields, Faceshields, Gloves, multi-purpose combination respirator cartridge (US)
- Hazard Codes
- F,Xn,C
- Risk Statements
- 17 · 17-34-40-36/37/38-20/21/22-11-22-19-37
- Safety Statements
- 7 · 7-23-26-36/37/39-43-45-16
- RIDADR
- 2845 · UN 2845 4.2/PG 1
- WGK Germany
- 1 · 1
- RTECS
- 1850000 · ED1850000
- TSCA
- TSCA listed
- HazardClass
- 4.2 · 4.2
- PackingGroup
- I
- HS Code
- 29310099 · 29310099
- Storage Class
- 4.2 · 4.2 - Pyrophoric and self-heating hazardous materials
- Hazard Classifications
- 4 OralEye · Acute Tox. 4 OralEye Dam. 1Pyr. Liq. 1Skin Corr. 1B
Safety & regulation
GHS classification
GHS Classification
Danger
H250 (100%): Catches fire spontaneously if exposed to air [Danger Pyrophoric liquids]
P210, P222, P231, P233, P260, P264, P264+P265, P270, P280, P301+P317, P301+P330+P331, P302+P335+P334, P302+P361+P354, P304+P340, P305+P354+P338, P316, P317, P321, P330, P363, P370+P378, P405, and P501 (click each P-code to see the statement)
Aggregated GHS information provided per 204 reports by companies from 5 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.
Hazard information
Hazards Summary
Causes convulsions, dyspnea, and lung changes in oral lethal-dose studies of rats; [RTECS] Pyrophoric; Reacts violently with water; Causes burns; Inhalation may cause corrosive injuries to upper respiratory tract and lungs; Harmful by ingestion and skin absorption; [Sigma-Aldrich MSDS] See Triethylboron.
Hazard Classes and CategoriesPyr. Liq. 1 (100%)
Toxicology
Adverse EffectsNeurotoxin - Other CNS neurotoxin
Safety data
- PPE
- Eyeshields, Faceshields, Gloves, multi-purpose combination respirator cartridge (US)
- wgk
- 1
- tsca
- TSCA listed
- rtecs
- ED1850000
- ridadr
- UN 2845 4.2/PG 1
- hs_code
- 29310099
- risk_code
- 17-34-40-36/37/38-20/21/22-11-22-19-37
- Signal word
- Danger
- Symbol(GHS)
- GHS02,GHS05
- hazard_code
- F,Xn,C
- safety_code
- 7-23-26-36/37/39-43-45-16
- hazard_class
- 4.2
- Storage Class
- 4.2 - Pyrophoric and self-heating hazardous materials
- packing_group
- I
- Hazard statements
- H250-H314-H318
- Hazard Classifications
- Acute Tox. 4 OralEye Dam. 1Pyr. Liq. 1Skin Corr. 1B
- Precautionary statements
- P210-P222-P231+P232-P233-P280-P260-P264-P302+P334-P370+P378-P301+P330+P331-P303+P361+P353-P363-P304+P340-P310-P305+P351+P338-P405-P501
Chemistry & industry
Uses & manufacturing
General Manufacturing InformationBorane, tributyl-: ACTIVE
Applications
UsesPetrochemical industry, organic reactions, catalyst.
UsesTributylborane is a reducing agent used in the controlled radical polymerization of alkyl acrylates.
Upstream & downstream products
Downstream products
Suppliers41 total
武汉欣扬瑞和化学科技有限公司153-07155313 15307155313 · [email protected]
Syntechem Co.,Ltd[email protected]
上海迈瑞尔生化科技有限公司4006356688 18621169109 · [email protected]
阿法埃莎（中国）化学有限公司400-6106006 · [email protected]
安耐吉化学&3A（安徽泽升科技股份有限公司）400-0056266 · [email protected]
上海瀚鸿科技股份有限公司021-54306202 13764082696 · [email protected]
希仕化工科技(上海)有限公司021-60499358 13661956116
赛默飞世尔科技（中国）有限公司800-810-5118 · [email protected]
天津思博宁医药科技有限公司0086-22-60330256
北京京土恒盛化工科技有限公司00-13911456598 13911456598 · [email protected]
雷丁试剂0510-85629785 18013409632 · [email protected]
陕西缔都医药化工有限公司029-81024372 17792795018 · [email protected]
Sigma-Aldrich西格玛奥德里奇(上海)贸易有限公司021-61415566 800-8193336 · [email protected]
HANGZHOU LEAP CHEM CO., LTD.+86-571-87711850 +86-15355479329 · [email protected]
厦门志信化学有限公司+86-5922680277 +86-13806087780 · [email protected]
上海阿拉丁生化科技股份有限公司6206333 13167063860 · [email protected]
康幸生物科技（上海）有限公司021-61556450 15800904410
南京艾比克斯生化科技有限公司025-87193546 18652950785 · [email protected]
上海源叶生物科技有限公司13636370518 · [email protected]
山东西亚化学有限公司4009903999 13395398332 · [email protected]
安泰精细化工技术有限公司18503026267 · [email protected]
山东小野化学股份有限公司0539-6362799 20）
山东英朗化工有限公司15763463371 15265310975 · [email protected]
武汉弘德悦欣医药科技有限公司027-83850116 18164090116 · [email protected]
Shaanxi Didu New Materials Co. Ltd+86-86-17392712779 +86-13289823923 · [email protected]
连云港捷众医药科技有限公司13165449089 · [email protected]
黄石市博尔化工有限公司0714-6401888 18671400300 · [email protected]
河南天孚化工有限公司+86-0371-55170693 +86-19937530512 · [email protected]
厦门盈融达化工有限公司+86-0592-6210733 · [email protected]
career henan chemical co+86-0371-86658258 · [email protected]
艾览（上海）化工科技有限公司400-668-9898 · [email protected]
深圳聚合生化科技有限公司+86-400-002-6226 · [email protected]
上海允复纳米科技有限公司18964169089 · [email protected]
ANHUI WITOP BIOTECH CO., LTD+8618071025641 · [email protected]
XIAMEN AMITY INDUSTRY AND TRADE CO., LTD.+8618950047208 · [email protected]
雷丁科技0510-85629785 18013409632 · [email protected]
山东天铭生物科技发展有限责任公司400-9019001 400-901-9001
DAYANG CHEM (HANGZHOU) CO.,LTD+86-88938639 +86-17705817739 · [email protected]
上海珅桔化工有限公司13167128868 13248068001 · [email protected]
上海药领医药科技合伙企业（有限合伙）400-6181121 18616383988 · [email protected]
Hefei TNJ Chemical Industry Co.,Ltd.+86-0551-65418671 +86-189 4982 3763 · [email protected]
Related reactions
30 records
Compound notes
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