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mu-Oxidobis(oxido)dilanthanum

HCID 3280778
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Basic information

CAS
1312-81-8
Standard SMILES
[O]=[La][O][La]=[O]
InChIKey
KTUFCUMIWABKDW-UHFFFAOYSA-N
Molecular formula
La2O3
Average molar mass
325.809 g/mol
Monoisotopic mass
325.79747

Names & identifiers

Preferred name
mu-Oxidobis(oxido)dilanthanum
IUPAC
oxo(oxolanthaniooxy)lanthanum
English name
Lanthanum oxide
Molecular formula
La2O3
Molecular weight
325.81

Names & synonyms

mu-Oxidobis(oxido)dilanthanumSCHEMBL29349621Lanthanum(III) oxide, REacton?Lanthanum(III) oxide, 99.9%LANTHANUM OXIDE, 99.99%Lanthanum(III) oxide, >=99.9%AKOS025311171FL34028L0235Lanthanum(III) oxide, for AAS, >=99.9%Lanthanum(III) oxide, 99.99% trace metals basisLanthanum oxide (La2O3 ), 99.99% (REO) Nano
Show more names
LANTHANUM(III) OXIDELanthanum(Ⅲ) oxideLANTHANUM OXIDE, 99.99%LANTHANUM OXIDE, 99.99%LANTHANUM OXIDE, 99.99%LANTHANUM OXIDE, 99.99%O3La2LanthanalathanialanthaniaLanthanoxidLanthan oxide99.999% (REO)
Lanthanum(III) oxide, 99.999% trace metals basisLanthanum(III) oxide, nanopowder, <100 nm particle size (TEM), 99% trace metals basis

Database identifiers

CAS
1312-81-8
PubChem CID
3280778
DTXSID
DTXSID7051478

Properties

Computed structural properties

Topological polar surface area
43.4 Ų
Hydrogen bond donors
0
Hydrogen bond acceptors
3
Rotatable bonds
0
Heavy atoms
5
Formal charge
0
Complexity
34.2

Physicochemical properties

Melting point
2315 °C · 2315 °C
Boiling point
4200 °C · 4200 °C
Density
6.51 g/mL · 6.51 g/mL at 25 °C(lit.)
bulk density
1300 kg/m3 · 1300kg/m3
Flash point
4200 °C · 4200°C
storage temp.
no restrictions.
solubility
2 O; · insoluble in H2O; soluble in dilute acid solutions
form
nanopowder
color
White to yellow
Specific Gravity
6.51 · 6.51
PH
9 · 9.0 (50g/l, H2O, 20℃)(slurry)
Resistivity
1 · 1 ∞ 10*14 (550°C) (ρ/μΩ.cm)
Water Solubility
INSOLUBLE
Specific Heat Capacity
0.33 J/ · Cp(crystal): 0.33 J/(g·K), at 25℃
Sensitive
Hygroscopic
Crystal Structure
Trigonal

Safety & regulation

Safety information is for reference only and does not replace the supplier’s Safety Data Sheet (SDS), applicable regulations, or professional assessment.

Safety data

PPE
dust mask type N95 (US), Eyeshields, Gloves
wgk
1
tsca
TSCA listed
rtecs
OE5330000
hs_code
28469000
Toxicity
LD50 orally in Rabbit: > 9968 mg/kg
risk_code
36/37/38-36
Signal word
Warning
Symbol(GHS)
GHS07
hazard_code
Xi
safety_code
26-36-39
Storage Class
13 - Non Combustible Solids
Hazard statements
H320-H315-H319-H335
REACH Registrations
Active
Precautionary statements
P261-P280a-P304+P340-P305+P351+P338-P405-P501a-P264-P305+P351+P338+P337+P313

Chemistry & industry

Applications · 3 items

UsesLanthanum oxide is used to make high-quality glass, ceramics, carbon-arc electrodes, and fluorescent lamps. Lanthanum (III) oxide was used as an analytical standard in inductively coupled plasma atomic emission spectrometry (ICP-AES) for chemical characterization of ancient pottery.

UsesLanthanum(III) oxide is used as a precursor to LAMOX fast ion conductors and superconductors. It is also used in the manufacture of optical glasses, piezoelectric and thermoelectric material. It is also useful for X-ray imaging intensifying screens, phosphors as well as dielectric and conductive ceramics. In addition, it is used as a catalyst to effect certain organic transformations. It is one of the active ingredients and finds application in thermoelectric and piezoelectric materials.

General DescriptionLanthanum (III) oxide is an alkaline earth oxide, and is a diamagnetic, isostructural analog of neodymium oxide. It is also an efficient recyclable catalyst, and can be used in coupling various aryl halides with aromatic/alkyl thiols.

Preparation methods · 1 item

PreparationLanthanum oxide can be produced by direct combustion of lanthanum in oxygen or air. The oxide also may be prepared by decomposition of an oxo salt of lanthanum, such as nitrate, sulfate, carbonate, hydroxide or oxalate. La(CO3)3•8H2O → La2O3 + 3CO2 + 8H2O 2La2(C2O4)3•9H2O + 3O2 → 2La2O3 + 12CO2 + 18H2O

Upstream & downstream products

Upstream raw materials

ExtractantPYROGALLOL REDRare earth micronutrientsLANTHANUMMethylphosphonic acidPhosphine

Related reactions

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Compound notes

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On this pageBasic informationNames & identifiersPropertiesSafety & regulationChemistry & industryRelated reactionsCompound notes
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crystal system
Three sides
Merck
14 · 14,5363
Space group
3 m1 · P3m1
Lattice constant
a/nm
Symbol(GHS)
7 · GHS07
Signal word
Warning
Hazard statements
320 · H320-H315-H319-H335
Precautionary statements
261 · P261-P280a-P304+P340-P305+P351+P338-P405-P501a-P264-P305+P351+P338+P337+P313
PPE
95 · dust mask type N95 (US), Eyeshields, Gloves
Hazard Codes
Xi
Risk Statements
36 · 36/37/38-36
Safety Statements
26 · 26-36-39
WGK Germany
1 · 1
RTECS
5330000 · OE5330000
TSCA
TSCA listed
HS Code
28469000 · 28469000
Storage Class
13 · 13 - Non Combustible Solids
Toxicity
50 orally · LD50 orally in Rabbit: > 9968 mg/kg
REACH Registrations
Active

Downstream products

Lanthanum Fluoride