Basic information
- CAS
25869-00-5- Standard SMILES
[C-]#N.[C-]#N.[C-]#N.[C-]#N.[C-]#N.[C-]#N.[Fe+2].[Fe+3].[NH4+]- InChIKey
ILZWGESBVHGTRX-UHFFFAOYSA-O- Molecular formula
- C6FeN6.Fe.H4N
- Average molar mass
- 285.83 g/mol
- Monoisotopic mass
- 285.922689
Overview
Ferric ammonium ferrocyanide is a solid.
Names & identifiers
- Preferred name
- Ferric Ammonium Ferrocyanide
- IUPAC
- azanium;iron(2+);iron(3+);hexacyanide
- English name
- AMMONIUM IRON (III) HEXACYANOFERRATE (II)
- Molecular formula
- C6H4Fe2N7
- Molecular weight
- 285.84
Names & synonyms
FERRIC AMMONIUM FERROCYANIDEAmmonium iron hexacyanoferrateAmmonium iron (III) hexacyanoferrateAmmonium iron(3+) hexakis(cyano-C)ferrate(4-)9R0NVI936IGiese saltFerrate(4-), hexakis(cyano-C)-, ammonium iron(3+) (1:1:1), (OC-6-11)-247-304-1AFCFAmmonium-ferric-cyano-ferrate(II)RefChem:140253Ferrate(4-), hexacyano-, ammonium iron(3+)
Show more names
giesesaltC. I. 77510Pigment Violet 27INSOLUBLEPRUSSIANBLUEPIGMENT BLUE 27 POWDERferricammoniumferrocyanideAMMONIUMFERRICCYANOFERRATEammonium-ferric-ferrocyanideammoniumironhexacyanoferrate
ammonium ferric hexacyanoferrateDTXCID209332Ferrate(4-), hexakis(cyano-kappaC)-, ammonium iron(3+) (1:1:1), (OC-6-11)-Ferrate(4-), Hexakis(Cyano-C)-, Ammonium Iron(3++) (1:1:1)25869-00-5DTXSID1029332Ferrate(4 -), hexacyano-, ammonium iron(3+)SCHEMBL342293
Database identifiers
- CAS
25869-00-5- PubChem CID
- 33190
- UNII
- 9R0NVI936I
- EC Number
- 247-304-1
Properties
Computed structural properties
- Topological polar surface area
- 144 Ų
- Hydrogen bond donors
- 1
- Hydrogen bond acceptors
- 12
- Rotatable bonds
- 0
- Heavy atoms
- 15
- Formal charge
- 0
- Complexity
- 10
Experimental & physicochemical properties
Polymers
Plastics -> Pigments agents
Plastics -> Polyolefin-I; PUR; Polyolefin-II; PVC (soft); ABS; PVC (rigid); PET; PMMA; PA; PC; (E)PS
CosmeticsCosmetic colorant
Food AdditivesDrugs -> FDA Regulatory Status of Color Additives
Physical Description
Ferric ammonium ferrocyanide is a solid.
Dry Powder
Physicochemical properties
- RTECS
- 8140000 · LJ8140000
- Water Solubility
- Soluble in water and mineral acids. Insoluble in alkali.
- Merck
- 14 · 14,7910
- Exposure limits
- 1 mg/m3NIOSH: · ACGIH: TWA 1 mg/m3NIOSH: IDLH 25 mg/m3; TWA 1 mg/m3
- Cosmetics Ingredients Functions
- COLORANT
- LogP
- -0.25 · -0.250 (est)
- FDA 21 CFR
- 73.1298 · 73.1298; 73.2298
- FDA UNII
- 9 R0NVI936I · 9R0NVI936I
- EPA Substance Registry System
- Ferric ammonium ferrocyanide (25869-00-5)
- Hazard statements
- 402 · H402-H412
- Risk Statements
- 20 · 20/21/22
- Safety Statements
- 22 · 22-36/37/39
- TSCA
- TSCA listed
- Toxicity
- 50 orally · LD50 orally in mice: >5 g/kg (Pearce)
- REACH Registrations
- Active
Safety & regulation
Safety information is for reference only and does not replace the supplier’s Safety Data Sheet (SDS), applicable regulations, or professional assessment.
GHS classification
GHS Classification
This chemical does not meet GHS hazard criteria for 65% (204 of 314) of all reports.
H413 (31.2%): May cause long lasting harmful effects to aquatic life [Hazardous to the aquatic environment, long-term hazard]
P273, and P501 (click each P-code to see the statement)
Aggregated GHS information provided per 314 reports by companies from 7 notifications to the ECHA C&L Inventory.
Hazard information
Regulatory Information
Chemical: Ferrate(4-), hexakis(cyano-C)-, ammonium iron(3+) (1:1:1), (OC-6-11)-
Regulation (EC) No 1831/2003 (amended)
Ferrate(4-), hexakis(cyano-.kappa.C)-, ammonium iron(3+) (1:1:1), (OC-6-11)- is listed on the EPA's Chemical Data Reporting (CDR) system. Manufacturers and importers of Ferrate(4-), hexakis(cyano-.kappa.C)-, ammonium iron(3+) (1:1:1), (OC-6-11)- are required to report information about their production and use of this chemical to the EPA under the Toxic Substances Control Act (TSCA). (40 eCFR Part 711)
REACH registered substance: Ammonium iron(3+) hexakis(cyano-C)ferrate(4-) (EC: 247-304-1)
Ferrate(4-), hexakis(cyano-.kappa.C)-, ammonium iron(3+) (1:1:1), (OC-6-11)-: Does not have an individual approval but may be used under an appropriate group standard
Fire HazardsFlash point data for this chemical are not available. It is probably combustible. (NTP, 1992)
Reactive GroupCyanides, Inorganic
Reactivity Profile
FERRIC AMMONIUM FERROCYANIDE is an inorganic cyanide. Inorganic cyanides react slowly with water to evolve gaseous hydrogen cyanide (HCN). Acids cause the rapid evolution of HCN; carbon dioxide from the air is sufficiently acidic to liberate HCN from solutions of cyanides. Inorganic cyanides are incompatible with isocyanates, nitrides, and peroxides. Cyanides have been known to initiate polymerization reactions of epoxides. Cyanides form compounds with metal salts; heat and hydrogen production may accompany these reactions. Some cyanides can detonate when exposed to shock, heat, or friction. In the presence of strong acids or acid fumes may release highly toxic fumes of cyanides.
Air and Water ReactionsIrradiation of aqueous solutions of the compound will liberate hydrocyanic acid.
Hazard Classes and CategoriesAquatic Chronic 4 (31.2%)
Safety & protection
Fire FightingFires involving this material can be controlled with a dry chemical, carbon dioxide or Halon extinguisher. (NTP, 1992)
First Aid
EYES: First check the victim for contact lenses and remove if present. Flush victim's eyes with water or normal saline solution for 20 to 30 minutes while simultaneously calling a hospital or poison control center. Do not put any ointments, oils, or medication in the victim's eyes without specific instructions from a physician. IMMEDIATELY transport the victim after flushing eyes to a hospital even if no symptoms (such as redness or irritation) develop.
Nonfire Spill ResponseSTORAGE PRECAUTIONS: You should store this material in a refrigerator. (NTP, 1992)
Personal Protective Equipment (PPE)
RECOMMENDED RESPIRATOR: Where the neat test chemical is weighed and diluted, wear a NIOSH-approved half face respirator equipped with an organic vapor/acid gas cartridge (specific for organic vapors, HCl, acid gas and SO2) with a dust/mist filter. (NTP, 1992)
Safety data
- tsca
- TSCA listed
- Toxicity
- LD50 orally in mice: >5 g/kg (Pearce)
- risk_code
- 20/21/22
- safety_code
- 22-36/37/39
- Hazard statements
- H402-H412
- REACH Registrations
- Active
Chemistry & industry
Uses & manufacturing
UsesPlastics -> Typical concentration range in plastic materials -> 0.5%
U.S. Production2023: 75,000 - <500,000 lb
Consumer UsesPigment
Industry UsesPigment
Household ProductsInformation on 44 consumer products that contain Ferric ammonium ferrocyanide in the following categories is provided:
Use Classification
Cosmetics -> Cosmetic colorant
Plastics -> Polymer Type -> Polyolefin-I; PUR; Polyolefin-II; PVC (soft); ABS; PVC (rigid); PET; PMMA; PA; PC; (E)PS
Plastics -> Pigments agents
General Manufacturing Information
Construction
Ferrate(4-), hexakis(cyano-.kappa.C)-, ammonium iron(3+) (1:1:1), (OC-6-11)-: ACTIVE
Applications
UsesIt is employed as a intermediate for pharmaceuticals. Also used in decorative cosmetics.
General DescriptionSolid.
Suppliers13 total
陕西缔都医药有限责任公司029-81124775 17791530730 · [email protected]
上海迈瑞尔生化科技有限公司4006356688 18621169109 · [email protected]
阿法埃莎（中国）化学有限公司400-6106006 · [email protected]
安耐吉化学&3A（安徽泽升科技股份有限公司）400-0056266 · [email protected]
上海御略医药科技有限公司021-60345187 13671753212 · [email protected]
杭州洁汉化工有限公司+86-571-86217390; +8618058761490 · [email protected]
career henan chemical co+86-0371-86658258 · [email protected]
XIAMEN AMITY INDUSTRY AND TRADE CO., LTD.+8618950047208 · [email protected]
BOC Sciences+1-631-485-4226 · [email protected]
重庆卡兰医药有限公司[email protected]
DAYANG CHEM (HANGZHOU) CO.,LTD+86-88938639 +86-17705817739 · [email protected]
广州市海珠区正鸿商行020-82550624 13016020539 · [email protected]
AFINE CHEMICALS LIMITED+86-571-85134551 +86-18958018566 · [email protected]
Related reactions
0 records
No reaction records under the current filter.
Compound notes
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