Ruthenium,4-pentanedionato)-
Basic information
- CAS
14284-93-6- Standard SMILES
CC(=O)CC(C)=O.CC(=O)CC(C)=O.CC(=O)CC(C)=O.[Ru]- InChIKey
GNHBILLJFGEMKL-UHFFFAOYSA-N- Molecular formula
- C15H24O6Ru
- Average molar mass
- 401.4 g/mol
- Monoisotopic mass
- 402.061629
Names & identifiers
- Preferred name
- Ruthenium,4-pentanedionato)-
- IUPAC
- tris(pentane-2,4-dione);ruthenium
- English name
- Ruthenium acetylacetonate
- Molecular formula
- C15H21O6Ru
- Molecular weight
- 398.39
Names & synonyms
Ruthenium,4-pentanedionato)-Ruthenium(III)-2,4-pentanedionateNSC139624NSC-139624Ruthenium,4-pentanedionato-O,O')-, (OC-6-11)-Ru(acac)3RUTHENIUM(III) 2,4-PENTANEDIONATERuthenium 2,4-pentanedionateTRIS(ACETYLACETONATO)RUTHENIUM(III)Ruthenium(III) 2,4-pentanedionate~Tris(acetylacetonato)ruthenium(III)~Tris(2,4-pentanedionato)ruthenium(III)4-pentanedionatRutheniumpentanedionate
Show more names
Ruthenium acetylacetoneTris(2,4-pentanedionato)Ruthenium acetylacetonate
Database identifiers
- CAS
14284-93-6- PubChem CID
- 421900
Properties
Computed structural properties
- Topological polar surface area
- 102 Ų
- Hydrogen bond donors
- 0
- Hydrogen bond acceptors
- 6
- Rotatable bonds
- 0
- Heavy atoms
- 22
- Formal charge
- 0
- Complexity
- 314
Physicochemical properties
- Melting point
- 260 °C · 260 °C (dec.)(lit.)
- storage temp.
- 30 °C · Store below +30°C.
- form
- Crystalline
- color
- White
- Water Solubility
- Soluble in most organic solvents such as acetone, chlorinated hydrocarbons, alcohols, cyclohexane and benzene. Insoluble in water.
- InChI
- InChI=1S/3C5H8O2.Ru/c3*1-4(6)3-5(2)7;/h3*3,6H,1-2H3;/q;;;+3/p-3/b3*4-3-;
- InChIKey
- RTZYCRSRNSTRGC-LNTINUHCSA-K
- SMILES
- [Ru](O/C(/C)=C\C(=O)C)(O/C(/C)=C\C(=O)C)O/C(/C)=C\C(=O)C
- EPA Substance Registry System
- Ruthenium, tris(2,4-pentanedionato-.kappa.O,.kappa.O')-, (OC-6-11)- (14284-93-6)
- UNSPSC Code
- 12352103 · 12352103
- NACRES
- 23 · NA.23
- Symbol(GHS)
- 7 · GHS07
- Signal word
- Warning
- Hazard statements
- 315 · H315-H319-H335
- Precautionary statements
- 261 · P261-P280a-P304+P340-P305+P351+P338-P405-P501a
Safety & regulation
Safety information is for reference only and does not replace the supplier’s Safety Data Sheet (SDS), applicable regulations, or professional assessment.
Safety data
- F
- 10
- PPE
- dust mask type N95 (US), Eyeshields, Gloves
- wgk
- 3
- tsca
- TSCA listed
- hs_code
- 28439000
- risk_code
- 36/37/38
- Signal word
- Warning
- Symbol(GHS)
- GHS07
- hazard_code
- Xi,T
- safety_code
- 26-36-24/25
- Storage Class
- 11 - Combustible Solids
- Hazard statements
- H315-H319-H335
- Precautionary statements
- P261-P280a-P304+P340-P305+P351+P338-P405-P501a
Chemistry & industry
Applications
UsesPrecursor for the preparation of other compounds of ruthenium. Ruthenium(III) 2,4-pentanedionate is employed as a recyclable catalyst for certain organic transformations like the acetylation of phenols, alcohols, and amines under neat conditions. It is also used as a homogeneous catalyst, for example, in the hydrolysis of sodium borohydride and regiospecific tritiation of aromatic carboxylic acids. It is also used as a catalyst for enantioselective hydrogenation of acids such as aryl acrylic acid and aryl propenic acid.
Related reactions
1 records
Compound notes
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