Rhodium;2,2,2-trifluoroacetic acid
Basic information
- CAS
31126-95-1- Standard SMILES
O=C(O)C(F)(F)F.O=C(O)C(F)(F)F.O=C(O)C(F)(F)F.O=C(O)C(F)(F)F.[Rh].[Rh]- InChIKey
SZQVMUPTZFMHQT-UHFFFAOYSA-N- Molecular formula
- C8H4F12O8Rh2
- Average molar mass
- 661.9 g/mol
- Monoisotopic mass
- 661.78244
Overview
See also: Rhodium (II) Trifluoroacetate dimer (preferred).
Names & identifiers
- Preferred name
- Rhodium;2,2,2-trifluoroacetic acid
- IUPAC
- bis(rhodium);tetrakis(2,2,2-trifluoroacetic acid)
- English name
- Rhodium(II) trifluoroacetate dimer
- Molecular formula
- C8F12O8Rh2
- Molecular weight
- 657.87
Names & synonyms
31126-95-1rhodium;2,2,2-trifluoroacetic acidrhodium(II) trifluoroacetateRhodium(II) trifluoroacetate dimerNSC281175CID 430696DTXSID401376068NSC-281175Rhodium(II) trifluorRhodiumtrifluoroacetateRhodium(Ⅱ) trifluoroacetate dimerRhodium(I) trifluoroacetate dimer
Show more names
rhodium,2,2,2-trifluoroacetic acidRhodium(2+) trifluoroacetate (1:2)Rhodium(II) trifluoroacetate dimmerRhodium(III) trifluoroacetate dimer
Database identifiers
- CAS
31126-95-1- PubChem CID
- 430696
- DTXSID
DTXSID401376068
Properties
Computed structural properties
- Topological polar surface area
- 149 Ų
- Hydrogen bond donors
- 4
- Hydrogen bond acceptors
- 20
- Rotatable bonds
- 0
- Heavy atoms
- 30
- Formal charge
- 0
- Complexity
- 440
Physicochemical properties
- solubility
- sol MeCN, DMSO, pyridine; slightly sol dichloromethane, benzene.
- form
- Crystalline Powder
- color
- Green
- Stability
- hygroscopic
- InChI
- InChI=1S/4C2HF3O2.2Rh/c4*3-2(4,5)1(6)7;;/h4*(H,6,7);;/q;;;;2*+2/p-4
- InChIKey
- PQEXTYUESSEHKW-UHFFFAOYSA-J
- SMILES
- C(C1=O[Rh+2]234O=C(C(F)(F)F)[O-][Rh+2]2(O=C(C(F)(F)F)[O-]3)(O=C(C(F)(F)F)[O-]4)[O-]1)(F)(F)F
- UNSPSC Code
- 12352103 · 12352103
- NACRES
- 23 · NA.23
- Symbol(GHS)
- 7 · GHS07
- Signal word
- Warning
- Hazard statements
- 315 · H315-H319-H335
- Precautionary statements
- 261 · P261-P264-P271-P280-P302+P352-P305+P351+P338
- target organs
- Respiratory system
- PPE
- 95 · dust mask type N95 (US), Eyeshields, Gloves
- Hazard Codes
- Xi
Safety & regulation
Safety information is for reference only and does not replace the supplier’s Safety Data Sheet (SDS), applicable regulations, or professional assessment.
Safety data
- PPE
- dust mask type N95 (US), Eyeshields, Gloves
- wgk
- 3
- hs_code
- 28439000
- risk_code
- 36/37/38
- Signal word
- Warning
- Symbol(GHS)
- GHS07
- hazard_code
- Xi
- safety_code
- 26-36-37/39
- Storage Class
- 11 - Combustible Solids
- target organs
- Respiratory system
- Hazard statements
- H315-H319-H335
- Hazard Classifications
- Eye Irrit. 2Skin Irrit. 2STOT SE 3
- Precautionary statements
- P261-P264-P271-P280-P302+P352-P305+P351+P338
Chemistry & industry
Applications
UsesUsed in the preparation of isomerically pure α,β-unsaturated carbonyl compounds and the preparation of building blocks for one-, two-, and three-dimensional molecular solids.
Related reactions
0 records
No reaction records under the current filter.
Compound notes
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