2-(Chloromethyl)allyl-trimethylsilane
Basic information
- CAS
18388-03-9- Standard SMILES
C=C(CCl)C[Si](C)(C)C- InChIKey
CQXWCEVXNRHUSQ-UHFFFAOYSA-N- Molecular formula
- C7H15ClSi
- Average molar mass
- 162.73 g/mol
- Monoisotopic mass
- 162.06315469
Names & identifiers
- Preferred name
- 2-(Chloromethyl)allyl-trimethylsilane
- IUPAC
- 2-(chloromethyl)prop-2-enyl-trimethylsilane
- English name
- 2-Chloromethyl-3-trimethylsilyl-1-propene
- Molecular formula
- C7H15ClSi
- Molecular weight
- 162.73
Names & synonyms
18388-03-92-(Chloromethyl)allyl-trimethylsilaneDTXSID80403333RefChem:253563DTXCID10354187626-838-22-Chloromethyl-3-trimethylsilyl-1-propene2-(chloromethyl)prop-2-enyl-trimethylsilane[2-(Chloromethyl)allyl]trimethylsilane(2-(chloromethyl)allyl)trimethylsilane[2-(chloromethyl)prop-2-en-1-yl]trimethylsilaneMFCD00013253
Show more names
2-(TRIMETHYLSILYLMETHYL)ALLYL CHLORIDE2-Methylene-3-chloropropyltrimethylsilane2-(Trimethylsilylmethyl)-3-chloro-1-propene2-(Trimethylsilylmethyl)-2-propenyl chloride[2-(Chloromethyl)-2-propenyl]trimethylsilaneSilane, [2-(chloromethyl)-2-propen-1-yl]trimethyl-2-(Chloromethyl)-3-trimethylsilyl-1-propene, 2-(Trimethylsilylmethyl)allyl chloride
SCHEMBL346590CQXWCEVXNRHUSQ-UHFFFAOYSA-N2-(chloromethyl)allyl-trimethyl-silaneAKOS006220776[2-(chloromethyl)allyl]trimethyl-silaneSY248950DB-0445102-(Chloromethyl)allyl-trimethylsilane, 97%
Database identifiers
- CAS
18388-03-9- PubChem CID
- 4440923
- DTXSID
DTXSID80403333- EC Number
- 626-838-2
- Nikkaji
- J267.180H
Properties
Computed structural properties
- Topological polar surface area
- 0 Ų
- Hydrogen bond donors
- 0
- Hydrogen bond acceptors
- 0
- Rotatable bonds
- 3
- Heavy atoms
- 9
- Formal charge
- 0
- Complexity
- 102
Physicochemical properties
- Boiling point
- 162 · 162-163 °C/768 mmHg (lit.)
- Density
- 0.899 g/mL · 0.899 g/mL at 25 °C (lit.)
- refractive index
- 20 · n20/D 1.453(lit.)
- Flash point
- 110 °F · 110 °F
- storage temp.
- 2 · 2-8°C
- solubility
- Chloroform, Methanol (Slightly)
- form
- Oil
- color
- Clear Colourless
- Specific Gravity
- 0.899 · 0.899
- Hydrolytic Sensitivity
- 4 · 4: no reaction with water under neutral conditions
- BRN
- 1747038 · 1747038
- Stability
- Moisture Sensitive
- InChI
- 1S/C7H15ClSi/c1-7(5-8)6-9(2,3)4/h1,5-6H2,2-4H3
- InChIKey
- CQXWCEVXNRHUSQ-UHFFFAOYSA-N
- SMILES
- C[Si](C)(C)CC(=C)CCl
- UNSPSC Code
- 12352100 · 12352100
- NACRES
- 22 · NA.22
Safety & regulation
Safety information is for reference only and does not replace the supplier’s Safety Data Sheet (SDS), applicable regulations, or professional assessment.
GHS classification
GHS Classification
Warning
H226 (100%): Flammable liquid and vapor [Warning Flammable liquids]
P210, P233, P240, P241, P242, P243, P261, P264, P264+P265, P271, P280, P302+P352, P303+P361+P353, P304+P340, P305+P351+P338, P319, P321, P332+P317, P337+P317, P362+P364, P370+P378, P403+P233, P403+P235, P405, and P501 (click each P-code to see the statement)
Aggregated GHS information provided per 39 reports by companies from 2 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.
Hazard information
Hazard Classes and CategoriesFlam. Liq. 3 (100%)
Safety data
- PPE
- Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
- wgk
- 3
- tsca
- No
- ridadr
- UN 1993 3/PG 3
- risk_code
- 10-36/37/38
- Signal word
- Warning
- Symbol(GHS)
- GHS02,GHS07
- hazard_code
- Xi
- safety_code
- 26-36
- hazard_class
- 3.2
- Storage Class
- 3 - Flammable liquids
- packing_group
- III
- target organs
- Respiratory system
- Hazard statements
- H226-H315-H319-H335
Chemistry & industry
Applications
Uses2-(Chloromethyl)allyl-trimethylsilane is one of the reagents to synthesize Leucasandrolide A Macrolide (I) via Mukaiyama aldol coupling.2-(Chloromethyl)allyl-trimethylsilane was used in catalytic Sakurai reaction of a,b-enones.
Related reactions
0 records
No reaction records under the current filter.
Compound notes
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