Basic information
- CAS
137-29-1- Standard SMILES
CN(C)C(=S)[S-].CN(C)C(=S)[S-].[Cu+2]- InChIKey
ZOUQIAGHKFLHIA-UHFFFAOYSA-L- Molecular formula
- C6H12CuN2S4
- Average molar mass
- 304 g/mol
- Monoisotopic mass
- 302.91793
Names & identifiers
- Preferred name
- Copper dimethyldithiocarbamate
- IUPAC
- copper bis(N,N-dimethylcarbamodithioate)
- English name
- Copper(II) Dimethyldithiocarbamate
- Molecular formula
- C6H12CuN2S4
- Molecular weight
- 303.98
Names & synonyms
137-29-1Copper dimethyldithiocarbamateCopper(II) dimethyldithiocarbamateCumateDTXSID2020345DimethyldithiocarbamatocopperDTXCID60345F3D0AX36Y9Cupric N,N-dimethyldithiocarbamateCopper bis(dimethyldithiocarbamate)Copper(2+) dimethyldithiocarbamateCopper, bis(dimethyldithiocarbamato)-
Show more names
CDMChermatcuMETHYL CUMATECompound-4018Perkacit CDMCAkrochem Cu.D.DBis(dimethylcarbamodMETHYL CUMATE RODFORM
BIS(DIMETHYLDITHIOCARBAMATO)COPPER(II)NSC-32947BIS(DIMETHYLDITHIOCARBAMATO)COPPERCopper, bis(dimethylcarbamodithioato-.kappa.S,.kappa.S')-, (SP-4-1)-Copper, bis(dimethylcarbamodithioato-S,S')-, (SP-4-1)-BIS(N,N-DIMETHYL(DITHIOCARBAMATO-S,S'))COPPERCARBAMODITHIOIC ACID, DIMETHYL-, COPPER(2+) SALTWolfen
Database identifiers
- CAS
137-29-1- PubChem CID
- 472181
- DTXSID
DTXSID2020345- UNII
- F3D0AX36Y9
- EC Number
- 205-287-8
- Nikkaji
- J67.583K
Properties
Computed structural properties
- Topological polar surface area
- 72.7 Ų
- Hydrogen bond donors
- 0
- Hydrogen bond acceptors
- 4
- Rotatable bonds
- 0
- Heavy atoms
- 13
- Formal charge
- 0
- Complexity
- 54.3
Experimental & physicochemical properties
PolymersPlastics & Rubber -> Dithiocarbamates (Rubber)
Food Contact SubstancesFCS -> FDA Inventory of Food Contact Substances Listed in 21 CFR
Physical DescriptionDark brown powder; Insoluble in cold water; [R.T. Vanderbilt MSDS]
Physicochemical properties
- Melting point
- 260 °C · 260°C
- Boiling point
- 415.51 °C · 415.51°C (estimate)
- Density
- 1 · 1,75 g/cm3
- vapor pressure
- 0 Pa · 0Pa at 25℃
- form
- powder to crystal
- color
- Orange to Amber to Dark red
- Specific Gravity
- 1.75 · 1.75
- Hydrolytic Sensitivity
- 4 · 4: no reaction with water under neutral conditions
- InChI
- InChI=1S/2C3H7NS2.Cu/c2*1-4(2)3(5)6;/h2*1-2H3,(H,5,6);/q;;+2/p-2
- InChIKey
- ZOUQIAGHKFLHIA-UHFFFAOYSA-L
- SMILES
- C(=S)(S[Cu]SC(=S)N(C)C)N(C)C
- LogP
- 4.55 · 4.55
- CAS DataBase Reference
- 137 · 137-29-1(CAS DataBase Reference)
- Indirect Additives used in Food Contact Substances
- COPPER DIMETHYLDITHIOCARBAMATE
- FDA 21 CFR
- 177.26 · 177.2600
- EWG's Food Scores
- 1 · 1
- FDA UNII
- 3 D0AX36Y9 · F3D0AX36Y9
- NIST Chemistry Reference
- Bis(dimethyldithiocarbamato) copper complex(137-29-1)
- EPA Substance Registry System
- Copper dimethyldithiocarbamate (137-29-1)
- Symbol(GHS)
- 9 · GHS09
- Signal word
- Warning
- Hazard statements
- 410 · H410
- Precautionary statements
- 273 · P273-P391-P501
- RIDADR
- 3077 · 3077
- RTECS
- 175000 · FA0175000
- TSCA
- TSCA listed
- HazardClass
- 9 · 9
- PackingGroup
- III
- HS Code
- 2930200090 · 2930200090
- REACH Registrations
- Inactive
Safety & regulation
Safety information is for reference only and does not replace the supplier’s Safety Data Sheet (SDS), applicable regulations, or professional assessment.
GHS classification
GHS Classification
This chemical does not meet GHS hazard criteria for 0.2% (1 of 562) of reports.
Danger
H330 (99.5%): Fatal if inhaled [Danger Acute toxicity, inhalation]
P260, P271, P273, P284, P304+P340, P316, P320, P391, P403+P233, P405, and P501 (click each P-code to see the statement)
Aggregated GHS information provided per 562 reports by companies from 9 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.
Not Classified
Hazard information
Regulatory Information
Chemical: Copper, bis(dimethylcarbamodithioato-S,S')-, (SP-4-1)-
REACH registered substance: Copper bis(dimethyldithiocarbamate) (EC: 205-287-8)
Copper (II) dimethyldithiocarbamate: HSNO Approval: HSR007610 Approved with controls
Hazards Summary
Acute copper poisoning after ingestion can cause liver injury, methemoglobinemia, and hemolytic anemia. Acute renal failure may result, secondary to massive hemoglobinuria. [Goldfrank, p. 1259] May cause mild eye irritation; Harmful by inhalation (dust may cause irregular breathing and lung congestion); Not a skin sensitizer in guinea pigs; [R.T. Vanderbilt MSDS] Several of the dialkyldithiocarbamates are known skin sensitizers; See Carba mix. See Copper.
Hazard Classes and Categories
Acute Tox. 2 (99.5%)
Hazardous to the aquatic environment (Acute) - Category 1
Safety & protection
Exposure Control and Personal Protection0.01 [mg/m3], respirable fraction (Cu, inorganic cmpnds)[German Research Foundation (DFG)]
Threshold Limit Values (TLV)1.0 [mg/m3], as Cu
Permissible Exposure Limit (PEL)1.0 [mg/m3], as Cu
Immediately Dangerous to Life or Health (IDLH)100.0 [mg/m3], as Cu
Toxicology
Adverse EffectsOccupational hepatotoxin - Secondary hepatotoxins: the potential for toxic effect in the occupational setting is based on cases of poisoning by human ingestion or animal experimentation.
Toxicity DataLCLo (rat) = 210 mg/m3/4hr
Safety data
- tsca
- TSCA listed
- rtecs
- FA0175000
- ridadr
- 3077
- hs_code
- 2930200090
- Signal word
- Warning
- Symbol(GHS)
- GHS09
- hazard_class
- 9
- packing_group
- III
- Hazard statements
- H410
- REACH Registrations
- Inactive
- Precautionary statements
- P273-P391-P501
Chemistry & industry
Uses & manufacturing
UsesUsed as an elastomer accelerator in industrial production; [R.T. Vanderbilt MSDS]
General Manufacturing InformationCopper, bis(dimethylcarbamodithioato-.kappa.S,.kappa.S')-, (SP-4-1)-: ACTIVE
Applications
UsesCopper dimethyldithiocarbamate [137-29-1] is used as an ultraaccelerator or vulcanization agent for SBR (styrenebutadiene), IR (polyisoprene isoprene), and EPDM (ethylene-propylene terpolymer) rubbers. Copper dimethyldithiocarbamate is often used as a stabilizer/antioxidant for synthetic elastomers or polyethers.
Suppliers100 total
梯希爱(上海)化成工业发展有限公司021-67121386 · [email protected]
郑州阿尔法化工有限公司+86-18530059196 · [email protected]
湖北永阔科技有限公司027-59223108 15972152991 · [email protected]
上海阿拉丁生化科技股份有限公司400-6206333 13167063860 · [email protected]
南通润丰石油化工有限公司66017690 19952660367 · [email protected]
广州纳珑化工有限公司13192879270; 13192879270 · [email protected]
武汉欣扬瑞和化学科技有限公司153-07155313 15307155313 · [email protected]
普善实业（陕西）有限公司029-81310890 18165209495 · [email protected]
Dayang Chem (Hangzhou) Co.,Ltd.+86-0571-88938639 17705817739 · [email protected]
武汉绿景丰华生物科技有限公司19972070065 · [email protected]
毕佳索（上海毕得医药科技股份有限公司）400-6005915 · [email protected]
上海迈瑞尔生化科技有限公司4006356688 18621169109 · [email protected]
江苏普乐司生物科技有限公司0513-66017706 18551496367 · [email protected]
武汉易泰科技有限公司上海分公司18930552037 · [email protected]
武汉市聚舜化工有限公司027-02783261126 18971318572 · [email protected]
安耐吉化学&3A（安徽泽升科技股份有限公司）400-0056266 · [email protected]
上海泰坦科技股份有限公司4006009262 13023226327 · [email protected]
湖北广奥生物科技有限公司027-02702759223056 18162699093 · [email protected]
孝感深远化工有限公司15527621225; 15527621225 · [email protected]
山东西亚化学有限公司13355009207 13355009207 · [email protected]
玛雅试剂+86 (573) 82222445 (0)18006601000 452520369 · [email protected]
天津希恩思生化科技有限公司400 638 7771 · [email protected]
上海遐瑞医药科技有限公司+86 21 61551611
江苏艾康生物医药研发有限公司025-66113011 13913916777 · [email protected]
TCI AMERICA800-4238616 · [email protected]
TOKYO CHEMICAL INDUSTRY CO., LTD.03-36680489 · [email protected]
TCI Europe320-37350700 · [email protected]
武汉卡诺斯科技有限公司153-37111468 15337111468 · [email protected]
武汉普洛夫生物科技有限公司17612776928 · [email protected]
湖北隆信化工实业有限公司15271551270 · [email protected]
北京环宇世纪化学科技有限公司hysj_bj.com
上海湄水化工科技有限公司021-60549325 18616193163
上海笛柏生物科技有限公司400-008-9730,021-54359730 400-008-9730 · [email protected]
成都零六生物科技有限公司400-1166-196 13458535857 · [email protected]
池州凯隆进出口贸易有限公司[email protected]
长沙晶康新材料科技有限公司0731-85118349 18874718518 · [email protected]
康迪斯化工(湖北)有限公司13343438265 · [email protected]
九鼎化学（上海）科技有限公司4009209199 · [email protected]
武汉峰耀同辉化学制品有限公司027-87466205 15377579727 · [email protected]
武汉鑫儒化工有限公司15927387915 15337108568 · [email protected]
厦门志信化学有限公司+86-5922680277 +86-13806087780 · [email protected]
武汉匠信生物科技有限公司19272768272 18007157445 · [email protected]
陕西缔都医药化工有限公司029-029-81120477 17792793610 · [email protected]
湖北源梦生物科技有限公司027-68897569 18120462897 · [email protected]
郑州阿尔法化工有限公司0371-53765687 18937137882 · [email protected]
南京择优新材料科技有限公司173-40521416 17340521416 · [email protected]
上海源叶生物科技有限公司18916372613 · [email protected]
上海西格生物科技有限公司021-57810052 18930344717 · [email protected]
武汉市承天精细化工有限公司18164098996 · [email protected]
武汉克米克生物医药技术有限公司027-13163388153 13163388153 · [email protected]
Related reactions
0 records
No reaction records under the current filter.
Compound notes
Loading…