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Cerium(III)fluoride

HCID 522669
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Basic informationOverviewNames & identifiersPropertiesSafety & regulationChemistry & industryRelated reactionsCompound notes
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Basic information

CAS
7758-88-5
Standard SMILES
[F][Ce]([F])[F]
InChIKey
QCCDYNYSHILRDG-UHFFFAOYSA-K
Molecular formula
CeF3
Average molar mass
197.111 g/mol
Monoisotopic mass
196.90066

Overview

See also: Cerium trifluoride (preferred).

Names & identifiers

Preferred name
Cerium(III)fluoride
IUPAC
trifluorocerium
English name
Cerium(III) Fluoride
Molecular formula
CeF3
Molecular weight
197.1112096

Names & synonyms

Cerium(III)fluorideCerium fluorure [French]UNII-1GCT2G09ANCerium(III) fluoride anhydrousSCHEMBL2215184EINECS 231-841-3CEROUS FLUORIDE, ANH.,99.9%EC 231-841-3Q1054573Cerium(III) fluoride, anhydrous, 99.99% (REO), powderCerium(III) fluoride, anhydrous powder, 99.9% trace metals basisCerium(III) fluoride, anhydrous, powder, 99.99% trace metals basis
Show more names
CERIUM FLUORIDEceriumfluorureCerium(III) fLCerium fluorureCerium FlourideCEROUS FLUORIDECeriuM(III)fluoriCERIUM(+3)FLUORIDECERIUM TRIFLUORIDECerium(Ⅲ) fluoride

Database identifiers

CAS
7758-88-5
PubChem CID
522669

Properties

Computed structural properties

Topological polar surface area
0 Ų
Hydrogen bond donors
0
Hydrogen bond acceptors
3
Rotatable bonds
0
Heavy atoms
4
Formal charge
0
Complexity
8

Physicochemical properties

Melting point
1640 °C · 1640 °C
Boiling point
2300 °C · 2300 °C
Density
6.16 g/mL · 6.16 g/mL at 25 °C(lit.)
Flash point
2300 °C · 2300°C
storage temp.
Store at room temperature
solubility
Soluble in strong mineral acids.
form
Powder
color
white to off-white
Specific Gravity
6.16 · 6.16
Water Solubility
Practically insoluble in, but slowly hydrolyzed by water
Sensitive
Hygroscopic
Crystal Structure
3 type · LaF3 type
crystal system
Three sides
Merck
14 · 14,1998
Solubility Product Constant (Ksp)
15.1 · pKsp: 15.1
Space group
3 c1 · P3c1
Lattice constant

Safety & regulation

Safety information is for reference only and does not replace the supplier’s Safety Data Sheet (SDS), applicable regulations, or professional assessment.

Safety data

PPE
dust mask type N95 (US), Eyeshields, Gloves
wgk
2
tsca
TSCA listed
rtecs
FK6125000
hs_code
28461000
risk_code
36/37/38-20/21/22
Signal word
Warning
Symbol(GHS)
GHS07
hazard_code
Xi,Xn
hazard_note
Irritant
safety_code
22-24/25-37/39-26-36/37
Storage Class
11 - Combustible Solids
Hazard statements
H312+H332-H315-H319-H335
REACH Registrations
Active
Precautionary statements
P280a-P304+P340-P405-P501a-P261-P280-P305+P351+P338

Chemistry & industry

Applications · 4 items

UsesCerium Fluoride, is the important raw material for polishing powder, special glass, metallurgical applications. In glass industry, it is considered to be the most efficient glass polishing agent for precision optical polishing. It is also used to decolorize glass by keeping iron in its ferrous state. In steel manufacturing, it is used to remove free Oxygen and Sulfur by forming stable oxysulfides and by tying up undesirable trace elements, such as lead and antimony.

DescriptionCerium(III) Fluoride (CeF3), in particular, is successfully used in experiments in high-energy physics. As a potential scintillator and a tunable laser material, CeF3 is a luminescent material with 100% activator (Ce3+) concentration. CeF3 has been previously prepared by several methods, including the reaction of CeO2 with fluorine gas at elevated temperature, using high-intensity ultrasound, rapid microwave method, thermal decomposition of precursors, hydrothermal synthesis, synthesis by precipitation from aqueous solutions, sol-gel method, synthesis of nanoparticles in colloidal nanoreactors, solvothermal method and conventional melting technique[1].

UsesIn arc carbons to increase their brilliance; prepa- ration of cerium metal.

UsesCerium(III) fluoride is used to make Lewis acid. It is considered to be the most effective glass polishing agent for high precision optical polishing. Cerium fluoride used as a core additive to improve the properties of the eventual weld. The fluoride provides stability to the arc and also modifies the behavior of the molten metal flowing into the weld.

Upstream & downstream products

Upstream raw materials

Hydrogen fluorideCerium dioxide

Downstream products

CERIUM(IV) FLUORIDE

Suppliers100 total

Related reactions

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Compound notes

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On this pageBasic informationOverviewNames & identifiersPropertiesSafety & regulationChemistry & industryRelated reactionsCompound notes
a/nm
Symbol(GHS)
7 · GHS07
Signal word
Warning
Hazard statements
312 · H312+H332-H315-H319-H335
Precautionary statements
280 a-P304+P340-P405-P501a-P261-P280-P305+P351+P338 · P280a-P304+P340-P405-P501a-P261-P280-P305+P351+P338
PPE
95 · dust mask type N95 (US), Eyeshields, Gloves
Hazard Codes
Xi,Xn
Risk Statements
36 · 36/37/38-20/21/22
Safety Statements
22 · 22-24/25-37/39-26-36/37
WGK Germany
2 · 2
RTECS
6125000 · FK6125000
Hazard Note
Irritant
TSCA
TSCA listed
HS Code
28461000 · 28461000
Storage Class
11 · 11 - Combustible Solids
REACH Registrations
Active
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