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Mercury(2+) dichloride

HCID 5284416
NotesReactions
Basic informationOverviewNames & identifiersPropertiesSafety & regulationChemistry & industryRelated reactionsCompound notes
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Basic information

CAS
7487-94-7
Standard SMILES
[Cl-].[Cl-].[Hg+2]
InChIKey
LWJROJCJINYWOX-UHFFFAOYSA-L
Molecular formula
Cl2Hg
Average molar mass
271.5 g/mol
Monoisotopic mass
271.908349

Overview

Mercury chloride (HgCl2) is a highly toxic compound that volatizes slightly at ordinary temperature and appreciably at 100 degrees C. It is corrosive to mucous membranes and used as a topical antiseptic and disinfectant. Mercuric chloride was used to disinfect wounds by Arab physicians in the Middle Ages but modern medicine has since deemed it unsafe for use.

Names & identifiers

Preferred name
Mercury(2+) dichloride
IUPAC
mercury(2+) dichloride
English name
Mercury chloride
Molecular formula
Cl2Hg
Molecular weight
271.5

Names & synonyms

mercury(2+) dichlorideNCGC00091572-01CAS-7487-94-7Cl2HgSCHEMBL19132MERCURIC CHLORIDE [MI]MERCURIC CHLORIDE [HSDB]MERCURIC CHLORIDE [VANDF]MERCURIC CHLORIDE [MART.]Mercury(II) chloride ACS reagentMERCURIC CHLORIDE [WHO-DD]MERCURIUS CORROSIVUS [HPUS]
Show more names
HgCl2MERCURIC CHLORIDEMercury dichlorideMERCURY(II) CHLORIDEMERCURIC BICHLORIDELHGGSulemtl898TL 898Sulema
STR04236Tox21_111151Tox21_202259Tox21_300491MERCURIC CHLORIDE [EP IMPURITY]MERCURIC CHLORIDE [EP MONOGRAPH]NCGC00254443-01NCGC00259808-01

Database identifiers

CAS
7487-94-7
PubChem CID
5284416
DTXSID
DTXSID5020811
UNII
53GH7MZT1R

Properties

Computed structural properties

Topological polar surface area
0 Ų
Hydrogen bond donors
0
Hydrogen bond acceptors
2
Rotatable bonds
0
Heavy atoms
3
Formal charge
0
Complexity
0

Physicochemical properties

Melting point
277 °C · 277 °C(lit.)
Boiling point
302 °C · 302 °C
Density
5.44 · 5.44
bulk density
2000 kg/m3 · 2000kg/m3
vapor pressure
1.3 mm · 1.3 mm Hg ( 236 °C)
refractive index
1.859 · 1.859
Flash point
302 °C · 302°C
storage temp.
Store at RT.
solubility
2 O: · H2O: soluble
form
powder
color
White
Specific Gravity
5.44 · 5.44
PH
3.2 · 3.2 (15g/L in H2O)
Odor
odorless
Water Solubility
7.4 g/100 · 7.4 g/100 mL (20 ºC)
Thermal Conductivity
1.297 W/ · 1.297 W/(m·K)
Merck
14 · 14,5876
Henry's Law Constant

Safety & regulation

Safety information is for reference only and does not replace the supplier’s Safety Data Sheet (SDS), applicable regulations, or professional assessment.

Safety data

wgk
3
tsca
TSCA listed
rtecs
OV9100000
ridadr
UN 1624
risk_code
28-34-48/24/25-50/53-51/53-48/21/22-25-68-62-27-24/25
Signal word
Danger
Symbol(GHS)
GHS05,GHS06,GHS08,GHS09
hazard_code
T+,N,T
safety_code
36/37/39-45-60-61-28-26-36/37
hazard_class
6.1
Storage Class
6.1B - Non-combustible, acute toxic Cat. 1 and 2very toxic hazardous materials
packing_group
II
Hazard statements
H300-H314-H341-H361f-H372-H410
Limited Quantities
0.5 Kg (solid)
Excepted Quantities
Max Inner Pack (1g or 1ml) and Max Outer Pack (500g or 500ml)
Hazard Classifications
Acute Tox. 2 OralAquatic Acute 1Aquatic Chronic 1Muta. 2Repr. 2Skin Corr. 1BSTOT RE 1
Precautionary statements
P260-P273-P280-P303+P361+P353-P304+P340+P310-P305+P351+P338
Hazardous Substances Data
7487-94-7(Hazardous Substances Data)

Chemistry & industry

Applications · 5 items

DescriptionMercury is found in trace amounts in the air, but the largest deposits on earth are as cinnabar (mercuric sulfide). It exists in several forms such as a liquid metal (quicksilver), as a vapor, and in compounds (organic and inorganic). Mercury has been used as a medicine, to make amalgams, and in many industrial applications. Exposure to mercury can be toxic in any of its forms, in any route (ingestion, skin contact, and inhalation) depending on the dose and duration of exposure. Thermometers, ‘button’ batteries, the new energy-saving fluorescent light bulbs, and many seafood (shellfish, tuna, marlin, and many others) contain mercury, and are, therefore, potential sources of mercury poisoning. The primary intracellular target of mercury is the sulfhydryl groups in many tissue enzymes and proteins. Binding of –SH– groups paralyzes vital functions, eventually causing failure of organ systems such as the lungs, kidneys, or the nervous system. Industrial disasters cause release of mercury or methylmercury into the environment. The classic example of such a disaster is the contamination of Minamata Bay in Japan, where the term Minamata disease originated. Studies from about 1956 to 1960 suggested the unusual symptoms (neurological) found in people in this area was traced back to industrial wastewater containing methylmercury. Nearly 2200 people were diagnosed and over 1700 deaths were eventually attributed to methylmercury poisoning. Mercury has been used in skin creams; the most recent problem cream was identified in 1996 from Mexico named ‘Crèma de Belleza-Manning.’ Mercury poisoning can be caused by all forms of mercury (elemental, vapor, inorganic, and organic).

UsesMercuric chloride is used in tanning leather; intensifier in photography; topical antiseptic and disinfectant.

UsesMercuric chloride is used in preservatives for wood and anatomical specimens, embalming solutions, disinfectants, photographic intensifiers, leather tanning, seed treatments, analytical reagents for organic syntheses, and the manufacture of other mercury-containing compounds. Pharmaceuticals containing mercuric chloride have also been used therapeutically as topical antiseptics and disinfectants.

UsesPreserving (kyanizing) wood and anatomical specimens; also embalming; disinfecting; browning and etching steel and iron; intensifier in photography; white reserve in fabric printing; tanning leather; electroplating aluminum; depolarizer for dry batteries; freeing gold from lead; magic photograms; mordant for rabbit and beaver furs; staining wood and vegetable ivory pink; manufacture of ink for mercurography; treating seed potatoes; manufacture of other mercury Compounds. As an important reagent In animal chemistry.

Related reactions

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Compound notes

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On this pageBasic informationOverviewNames & identifiersPropertiesSafety & regulationChemistry & industryRelated reactionsCompound notes
Nikkaji
J3.741I
1 · 1.0×103 mol/(m3Pa) at 25℃, Severit (1997)
Exposure limits
0.025 mg/m3 · PC-TWA: 0.025 mg/m3
Dielectric constant
3.2 · 3.2(Ambient)
Stability
Stable, but moisture sensitive and light sensitive - decomposes in sunlight. Incompatible with strong acids, ammonia, carbonates, metallic salts, alkalies, phosphites, phosphates, sulfites, sulfates, arsenic, antimony, bromides.
InChI
1S/2ClH.Hg/h2*1H;/q;;+2/p-2
InChIKey
LWJROJCJINYWOX-UHFFFAOYSA-L
SMILES
[Hg+2].[Cl-].[Cl-]
Toxicology and Carcinogenesis
Toxicology and Carcinogenesis Studies of Mercuric Chloride (CASRN 7487-94-7) in F344 Rats and B6C3F1 Mice (Gavage Studies)
FDA 21 CFR
310.545 · 310.545
CAS DataBase Reference
7487 · 7487-94-7(CAS DataBase Reference)
EWG's Food Scores
4 · 4
FDA UNII
53 GH7MZT1R · 53GH7MZT1R
ATC code
8 AK03 · D08AK03
NIST Chemistry Reference
Mercury dichloride(7487-94-7)
EPA Substance Registry System
Mercuric chloride (7487-94-7)
UNSPSC Code
12352302 · 12352302
NACRES
21 · NA.21
Symbol(GHS)
5 · GHS05,GHS06,GHS08,GHS09
Signal word
Danger
Hazard statements
300 · H300-H314-H341-H361f-H372-H410
Precautionary statements
260 · P260-P273-P280-P303+P361+P353-P304+P340+P310-P305+P351+P338
Hazard Codes
T+,N,T
Risk Statements
28 · 28-34-48/24/25-50/53-51/53-48/21/22-25-68-62-27-24/25
Safety Statements
36 · 36/37/39-45-60-61-28-26-36/37
RIDADR
1624 · UN 1624
WGK Germany
3 · 3
RTECS
9100000 · OV9100000
TSCA
TSCA listed
HazardClass
6.1 · 6.1
PackingGroup
II
Storage Class
6.1 B · 6.1B - Non-combustible, acute toxic Cat. 1 and 2very toxic hazardous materials
Hazard Classifications
2 OralAquatic · Acute Tox. 2 OralAquatic Acute 1Aquatic Chronic 1Muta. 2Repr. 2Skin Corr. 1BSTOT RE 1
Hazardous Substances Data
7487 · 7487-94-7(Hazardous Substances Data)
Limited Quantities
0.5 Kg · 0.5 Kg (solid)
Excepted Quantities
Max Inner Pack (1g or 1ml) and Max Outer Pack (500g or 500ml)

General DescriptionAn odorless white crystalline solid. Density 5.4 g / cm3. Melting point 277°C. Slightly volatile at ordinary temperatures. Can be sublimed unchanged. Corrosive to the mucous membranes. Toxic by inhalation (dusts, etc.), ingestion, and skin absorption. Used in photography, disinfectants, wood preservatives, fungicides.

Upstream & downstream products

Upstream raw materials

Sodium hypochloriteCyclone separatorChlorineCooling towerMercury

Downstream products

PinacolMERCURY(II) IODIDEVINYL CHLORIDE4,6-Dimethyl-pyridine-2-carboxylic acidAminomercuric chlorideN-MethylcyclohexylamineMercuric Oxide1-Ethylpiperazin-2-one(2S,5R,6S)-6-[(3-Hydroxy-3-oxo-2-thiophen-3-ylpropanoyl)amino]-6-methoxy-3,3-dimethyl-7-oxo-4-thia-1-azabicyclo[3.2.0]heptane-2-carboxylic aciddiammonium tetrachloromercurate
Additional notes · 1 item

DefinitionChEBI: A mercury coordination entity made up of linear triatomic molecules in which a mercury atom is bonded to two chlorines. Water-soluble, it is highly toxic. Once used in a wide variety of applications, including preserving wood and anatomical specimens, emba ming and disinfecting, as an intensifier in photography, as a mordant for rabbit and beaver furs, and freeing gold from lead, its use has markedly declined as less toxic alternatives have been developed.