CAS 13476-99-8 Vanadium(III) acetylacetonate (HCID 5377225)

Overview

See also: Tris(pentane-2,4-dionato-O,O')vanadium (annotation moved to) ... View More ...

Names & identifiers

Preferred name: Vanadium(III) acetylacetonate
IUPAC: tris((Z)-4-hydroxypent-3-en-2-one);vanadium
English name: VANADIUM(III) ACETYLACETONATE
Molecular formula: C15H21O6V
Molecular weight: 348.27

Names & synonyms

Vanadium(III) acetylacetonate13476-99-8V(acac)3MFCD00000033Vanadium acetylacetonateTris(acetylacetonato)vanadium(III)Vanadium, tris(2,4-pentanedionato-.kappa.O,.kappa.O')-, (OC-6-11)-tris(((Z)-4-oxopent-2-en-2-yl)oxy)vanadiumVANADIUM(III) 2,4-PENTANEDIONATE2,4-Pentanedione vanadium(III) derivativevanadium(IV) acetylacetonateJTPOGAMSYINTGF-LNTINUHCSA-K

Show more names

Vanadium trisacetylacetonateVanadium(III) acetyLAcetyl acetone vanadiumVanadyltriacetylacetonateBis(pentanedionato) vanadylVANADIUM(III)2,4-PENTANEDIONETris(acetylacetonato)vanadiumVANADIUM III 2,4-PENTANEDIONATO

Vanadium(III) acetylacetonate, 97%Vanadium(III) (2,4-pentanedionate)AKOS025311066Vanadium, tris(2,4-pentanedionato-O,O'-)Vanadium, tris(2,4-pentanedionato-.kappa.O2,.kappa.O4)-, (OC-6-11)-

Database identifiers

CAS: 13476-99-8
PubChem CID: 5377225

Properties

Computed structural properties

Topological polar surface area: 112 Å²
Hydrogen bond donors: 3
Hydrogen bond acceptors: 6
Rotatable bonds: 3
Heavy atoms: 22
Formal charge: 0
Complexity: 380

Experimental & physicochemical properties

Chemical ClassesMetals -> Organic Compounds, Metal Salts

Physical DescriptionBlue powder; [MSDSonline]

Physicochemical properties

Melting point: 181 · 181-184 °C(lit.)
Boiling point: 170 °C · 170°C 0,05mm
Density: 1.05 · 1.050
storage temp.: Inert atmosphere,Room Temperature
solubility: soluble in methanol, acetone, benzene chloroform
form: crystal
color: brown
Water Solubility: 2 g/L, · Soluble in water 2g/L, toluene, ethanol, acetone.
Sensitive: Air Sensitive
Hydrolytic Sensitivity: 7 · 7: reacts slowly with moisture/water
BRN: 4148970 · 4148970
Exposure limits: 0.05 mg/m3 · NIOSH: Ceiling 0.05 mg/m3
InChI: 1S/3C5H8O2.V/c3*1-4(6)3-5(2)7;/h3*3,6H,1-2H3;/q;;;+3/p-3/b3*4-3-;
InChIKey: JTPOGAMSYINTGF-LNTINUHCSA-K
SMILES: CC(=O)\C=C(\C)O[V](O\C(C)=C/C(C)=O)O\C(C)=C/C(C)=O
LogP: 0.05 · 0.05
CAS DataBase Reference: 13476 · 13476-99-8
FDA UNII: 2 B8X59QLY5 · 2B8X59QLY5
EPA Substance Registry System: Vanadium, tris(2,4-pentanedionato-.kappa.O,.kappa.O')-, (OC-6-11)- (13476-99-8)
UNSPSC Code: 12352103 · 12352103
NACRES: 23 · NA.23
Symbol(GHS): 6 · GHS06
Signal word: Danger
Hazard statements: 301 · H301-H315-H319-H335
Precautionary statements: 301 · P301+P310+P330-P302+P352-P305+P351+P338
target organs: Respiratory system
PPE: 95 · dust mask type N95 (US), Eyeshields, Gloves
Hazard Codes: Xi,T
Risk Statements: 36 · 36/37/38-25
Safety Statements: 26 · 26-36-45
RIDADR: 3285 · UN 3285 6.1/PG 3
WGK Germany: 3 · 3
F: 23 · 23-10
TSCA: TSCA listed
HazardClass: 6.1 · 6.1
PackingGroup: III
Storage Class: 6.1 C · 6.1C - Combustible acute toxic Cat.3toxic compounds or compounds which causing chronic effects
Hazard Classifications: 3 OralEye · Acute Tox. 3 OralEye Irrit. 2Skin Irrit. 2STOT SE 3
REACH Registrations: Active

Safety & regulation

Hazard information

Hazards SummaryAn irritant; [MSDSonline] See Vanadium pentoxide.

Safety data

F: 23-10
PPE: dust mask type N95 (US), Eyeshields, Gloves
wgk: 3
tsca: TSCA listed
ridadr: UN 3285 6.1/PG 3
risk_code: 36/37/38-25
Signal word: Danger
Symbol(GHS): GHS06
hazard_code: Xi,T
safety_code: 26-36-45
hazard_class: 6.1
Storage Class: 6.1C - Combustible acute toxic Cat.3toxic compounds or compounds which causing chronic effects
packing_group: III
target organs: Respiratory system
Hazard statements: H301-H315-H319-H335
REACH Registrations: Active
Hazard Classifications: Acute Tox. 3 OralEye Irrit. 2Skin Irrit. 2STOT SE 3
Precautionary statements: P301+P310+P330-P302+P352-P305+P351+P338

Chemistry & industry

Uses & manufacturing

General Manufacturing InformationVanadium, tris(2,4-pentanedionato-.kappa.O2,.kappa.O4)-, (OC-6-11)-: ACTIVE

Applications · 2 items

UsesVanadium(III) acetylacetonate can be used as a soluble catalyst, which acts as a redox mediator that allows effective oxidation of lithium peroxide for lithium-ion batteries. It can also be used as source material for the preparation of vanadium dioxide films by chemical vapor deposition (CVD) technique.

UsesCatalyst.