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Potassium nitric acid

HCID 54599360
NotesReactions
Basic informationNames & identifiersPropertiesSafety & regulationChemistry & industryRelated reactionsCompound notes
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Basic information

CAS
7757-79-1
Standard SMILES
O=[N+]([O-])O.[K+]
InChIKey
NSKIEZNYPFRKOK-UHFFFAOYSA-N
Molecular formula
HKNO3+
Average molar mass
102.111 g/mol
Monoisotopic mass
101.95934938

Names & identifiers

Preferred name
Potassium nitric acid
IUPAC
potassium nitric acid
English name
Potassium nitrate
Molecular formula
KNO3
Molecular weight
101.1032

Names & synonyms

SCHEMBL4219455NSC57632KNO3SALTPETERXSJNITRATE NITROGENPOTASSIUM NITRATE PLANT CELL CULTURE*TES TEDnitrevicknitecollo-bosaltpetrekaliinitras

Database identifiers

CAS
7757-79-1
PubChem CID
54599360

Properties

Computed structural properties

Topological polar surface area
66.1 Ų
Hydrogen bond donors
1
Hydrogen bond acceptors
3
Rotatable bonds
0
Heavy atoms
5
Formal charge
1
Complexity
33.9

Physicochemical properties

Melting point
334 °C · 334 °C (lit.)
Boiling point
100 °C750 · 100 °C750 mm Hg
Density
1 g/mL · 1.00 g/mL at 20 °C
bulk density
800 kg/m3 · 800kg/m3
Flash point
400 °C · 400°C
storage temp.
Store at RT.
solubility
2 O: · H2O: 1 M at 20 °C, clear, colorless
form
Solid
Specific Gravity
2.109 · 2.109
color
white
PH
5 · 5.0-7.5 (50g/l, H2O, 20℃)
Flame Color
Light Purple
Odor
odorless, cooling pungent salty taste
Water Solubility
320 g/L · 320 g/L (20 ºC)
Thermal Conductivity
2.092 W/ · 2.092 W/(m·K)
Specific Heat Capacity
0.95 J/ · Cp(crystal): 0.95 J/(g·K), at 25℃

Safety & regulation

Safety information is for reference only and does not replace the supplier’s Safety Data Sheet (SDS), applicable regulations, or professional assessment.

Safety data

wgk
1
tsca
TSCA listed
rtecs
TT3700000
ridadr
UN 1486
hs_code
2834 21 00
Toxicity
LD50 orally in rabbits: 1.166 g anion/kg, Dollahite, Rowe, Southwest. Vet. 27, 246 (1974)
risk_code
8-36/38-36/37/38-22
Signal word
Warning
Symbol(GHS)
GHS03
hazard_code
O,Xi,Xn
safety_code
26-17-36-7-24/25
hazard_class
5.1
Storage Class
5.1B - Oxidizing hazardous materials
packing_group
III
Hazard statements
H272
Limited Quantities
5.0 kg (11 lbs) (solid)
Excepted Quantities
Max Inner Pack (30g or 30ml) and Max Outer Pack (1Kg or 1L)
REACH Registrations
Active
Hazard Classifications
Ox. Sol. 3
Precautionary statements
P210-P220-P280-P370+P378-P501
Hazardous Substances Data
7757-79-1(Hazardous Substances Data)

Chemistry & industry

Applications · 9 items

DescriptionPotassium nitrate (chemical formula: KNO3) is the nitrate of potassium. It is a crystalline salt and a strong oxidizer which can be specially used in making gunpowder, as a fertilizer, and in medicine. It can be manufactured through the reaction between ammonium nitrate and potassium hydroxide, and alternatively through the reaction between ammonium nitrate with potassium chloride. Potassium nitrate has various applications. Its major applications include: fertilizer, tree stump removal, rocket propellant and fireworks. It can also be used for the nitric acid production. It is also useful for food preservation and food preparation. In pharmacology, it can be used to treat asthma and relieving high blood pressure.

UsesPotassium nitrate is used chiefly in the manufacture of gunpowder or other explosives, but is also used for fireworks,for lucifer matches, for curing meat, for manufacture of certain kinds of glass, for flux in metallurgical assays, for some dyeing, and in medicine. In agriculture, potassium nitrate is used as a water-soluble and virtually chloride-free source of nitrate-nitrogen and potassium nutrients. Due to the product's specific characteristics and benefits, target markets are related to high-value crops such as vegetables, fruits and flowers. Furthermore, chloride-sensitive crops, such as potato, strawberry, beans, cabbage, lettuce, peanut, carrot, onion, blackberry tobacco, apricot, grapefruit and avocado, will depend for their quality on the use of chloride-free K sources, such as potassium nitrate. Potassium nitrate is used in a wide variety of applications including glass manufacturing, explosives for mining and civil works, metal treatment, fireworks, and recently, as a means to drastically increase the efficiency of Concentrating Solar Power (CSP) plants as described in the following paragraph.

DescriptionPotassium nitrate is a solid, colorless, crystalline ionic compound that exists as the mineral niter.Potassium nitrate is also known as saltpeter. The name saltpeter comes from the Latin sal petrae, meaning salt of stone or salt of Petra. he term saltpeter or Chilean saltpeter is also used for sodium nitrate, NaNO3.

HistorySaltpeter’s most prominent use in human history is as the principal ingredient in gunpowder.The potassium nitrate used in gunpowder was originally obtained from natural mineral deposits of niter. Small quantities formed as efflorescence deposits on damp stone walls were identified as early as 2000 b.c.e. in Sumerian writings. As the use of black powder expanded with the development of weapons, the demand for saltpeter exceeded supply. This was exacerbated during times of war. To meet the demand for saltpeter to produce black powder, a saltpeter industry developed that followed prescribed methods to produce large quantities of saltpeter. The method depended on processing dirt obtained from areas where nitrates would naturally form. These were areas in which animal waste had accumulated such as the dirt floors of barns, stables, herding pens, caves, or cellars. The ammonia compounds in the urine and fecal wastes in these areas underwent nitrifi cation to produce nitrates, which combined with potassium in the soil to form saltpeter.

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Compound notes

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On this pageBasic informationNames & identifiersPropertiesSafety & regulationChemistry & industryRelated reactionsCompound notes
Sensitive
Hygroscopic
Merck
14 · 14,7648
Dielectric constant
5 · 5(0.0℃)
Stability
Stable. Strong oxidizer - contact with combustible material may cause fire. Incompatible with combustible materials, strong reducing agents.
Cosmetics Ingredients Functions
SOOTHINGORAL CARE
InChI
1S/K.NO3/c;2-1(3)4/q+1;-1
InChIKey
FGIUAXJPYTZDNR-UHFFFAOYSA-N
SMILES
[K+].[O-][N+]([O-])=O
LogP
-0.129 · -0.129 (est)
CAS DataBase Reference
7757 · 7757-79-1(CAS DataBase Reference)
Substances Added to Food (formerly EAFUS)
POTASSIUM NITRATE
FDA 21 CFR
172.16 · 172.160; 310.545
EWG's Food Scores
1 · 1
FDA UNII
45 X2JN0Z · RU45X2JN0Z
EPA Substance Registry System
Potassium nitrate (7757-79-1)
UNSPSC Code
41116107 · 41116107
NACRES
24 · NB.24
Symbol(GHS)
3 · GHS03
Signal word
Warning
Hazard statements
272 · H272
Precautionary statements
210 · P210-P220-P280-P370+P378-P501
Hazard Codes
O,Xi,Xn
Risk Statements
8 · 8-36/38-36/37/38-22
Safety Statements
26 · 26-17-36-7-24/25
RIDADR
1486 · UN 1486
WGK Germany
1 · 1
RTECS
3700000 · TT3700000
TSCA
TSCA listed
HS Code
2834 · 2834 21 00
HazardClass
5.1 · 5.1
PackingGroup
III
Storage Class
5.1 B · 5.1B - Oxidizing hazardous materials
Hazard Classifications
3 · Ox. Sol. 3
Hazardous Substances Data
7757 · 7757-79-1(Hazardous Substances Data)
Toxicity
50 orally · LD50 orally in rabbits: 1.166 g anion/kg, Dollahite, Rowe, Southwest. Vet. 27, 246 (1974)
REACH Registrations
Active
Limited Quantities
5 kg · 5.0 kg (11 lbs) (solid)
Excepted Quantities
Max Inner Pack (30g or 30ml) and Max Outer Pack (1Kg or 1L)

UsesAlthough the most prominent use of saltpeter is for the production of black powder,potassium nitrate is also used as fertilizer. In the first half of the 17th century, JohannRudolf Glauber (1604–1668) obtained saltpeter from animal pens and discovered its useto promote plant growth. Glauber included saltpeter with other nutrients in fertilizer mixtures. Glauber’s work was one of the first to indicate the importance of nutrient cyclingin plant nutrition.

UsesPotassium Nitrate is a preservative and color fixative in meats which exists as colorless prisms or white granules or powder. it has a solubility of 1 g in 3 ml of water at 25°c. see nitrate.

UsesThis natural substance is the product of the decomposition of lime and urine. The white granules or powder are soluble in water 1:3 but insoluble in alcohol. Potassium nitrate, also called saltpeter or nitre, was combined with sulfuric acid to nitrate cotton for the manufacture of collodion. It was also used with magnesium to make flash powder and added to ferrous sulfate developers to produced cool white tones in collodion positives.

UsesIn fireworks, fluxes, pickling meats; production of nitric acid; manufacture of glass, matches, gunpowder; freezing mixtures. Agricultural fertilizer. Preservative in foods. In dentrifices to reduce tooth hypersensitivity.

General DescriptionA white to dirty gray crystalline solid. Water soluble. Noncombustible, but accelerates the burning of combustible materials. If large quantities are involved in fire or the combustible material is finely divided an explosion may result. May explode under prolonged exposure to heat or fire. Toxic oxides of nitrogen are produced in fires. Used in solid propellants, explosives, fertilizers.

Upstream & downstream products

Upstream raw materials

Potassium hydroxideSodium chlorideAmmonium nitratePotassium carbonateAmmonium chlorideNitric acidSodium nitratePotassium chlorideAmmonium bicarbonate

Downstream products

1-Bromo-4-(methylsulphonyl)-2-nitrobenzeneCompound fertilizerTrimethylquinone7-Methyladenine8-Aminoisoquinoline4-Nitroquinoline N-oxideAcifluorfenammonia synthesis Fe catalysts1-Fluoro-4-(trifluoromethylthio)benzene2,6-Dinitroaniline4-Methyl-5-nitro-2-pyridinecarboxylic acidNitrogen phosphorus potassium mixed fertilizerIsopropylsulfonyl chloride5-Nitro-6-methyluracilGentamicin sulfate7-AminoisoquinolineSilver iodide3-Amino-4,6-dimethylpyridineethybenzene dehydrogenation catayst NCY6-Amino-2-N-Boc-1,2,3,4-tetrahydro-isoquinolineDimidium bromideAlizarin1-Methyl-4-nitro-1H-imidazole-5-carbonitrile8-Bromoisoquinoline3-Amino-2-bromo-4,6-dimethylpyridineAMMONIA SYNTHESIS CATALYST5-Chloro-1-methyl-4-nitroimidazole3-Amino-4-nitrobenzitrifluoride6-Nitroindole3-NitrobenzaldehydeCalcium iodate4-Amino-3-formylpyridinePotassium periodate6-AminoindoleSodium tungstate dihydratePOTASSIUM NITRITE4-Methyl-3-nitropyridine4-Vinylpyridine7-Nitro-3,4-dihydroisoquinoline2,4-Dichloro-3-methyl-5-nitrobenzoic acid

Additional notes

DefinitionChEBI: The inorganic nitrate salt of potassium.