Ferric acetylacetonate
Basic information
- CAS
14024-18-1- Standard SMILES
CC(=O)/C=C(/C)[O-].CC(=O)/C=C(/C)[O-].CC(=O)/C=C(/C)[O-].[Fe+3]- InChIKey
AQBLLJNPHDIAPN-LNTINUHCSA-K- Molecular formula
- C15H21FeO6
- Average molar mass
- 353.17 g/mol
- Monoisotopic mass
- 353.068749
Overview
See also: Iron (III) acetylacetonate (annotation moved to); tris(pentane-2,4-dionato)iron(III) (annotation moved to).
Names & identifiers
- Preferred name
- Ferric acetylacetonate
- IUPAC
- iron(3+);tris((Z)-4-oxopent-2-en-2-olate)
- English name
- Ferric acetylacetonate
- Molecular formula
- C15H21FeO6
- Molecular weight
- 353.17
Names & synonyms
Iron(III) acetylacetonateIron acetylacetonateIron tris(acetoacetonate)Iron tris(acetylacetonate)Nasemu IronFerric acetylacetonateTris(acetylacetonato)ironAcetope Fe(II)(Acetylacetonato)iron(III)Tris(actylacetone)ironTris(acetylacetone)ironIron tris(2,4-pentanedioate)
Show more names
Fe(acac)3TRIS(2,4-PENTANEDIONATO)IRON(III)acetonateIron (Ⅲ) acetylacetonateIRON (III) 2,4-PENTANEDIONATETRIS(ACETYLACETONATO)IRON(III)
Tris(actylacetonato) ironFerric tris(acetylacetonate)Iron acetylacetonate (VAN)Iron triacetylacetonateNSC 43622Iron tris(2,4-pentanedionato)Iron(3+) acetylacetonateAI3-60038
Database identifiers
- CAS
14024-18-1- PubChem CID
- 5483663
- UNII
- 118BHF260P
Properties
Computed structural properties
- Topological polar surface area
- 120 Ų
- Hydrogen bond donors
- 0
- Hydrogen bond acceptors
- 6
- Rotatable bonds
- 3
- Heavy atoms
- 22
- Formal charge
- 0
- Complexity
- 90.4
Experimental & physicochemical properties
Chemical ClassesMetals -> Organic Compounds, Metal Salts
Physical Description
Dry Powder
Dark red powder; Insoluble in water; [Alfa Aesar MSDS]
Physicochemical properties
- Melting point
- 180 · 180-182 °C (dec.)(lit.)
- Boiling point
- 110 °C · 110°C 2mm
- Density
- 5.24 g/mL · 5.24 g/mL at 25 °C(lit.)
- bulk density
- 500 kg/m3 · 500kg/m3
- vapor pressure
- 2.6 hPa · 2.6 hPa (110 °C)
- storage temp.
- 30 °C · Store below +30°C.
- solubility
- Soluble in toluene.
- form
- Powder
- color
- Red
- Specific Gravity
- 5.24 · 5.24
- Water Solubility
- 2 g/L · 2 g/L (20 ºC)
Safety & regulation
Safety information is for reference only and does not replace the supplier’s Safety Data Sheet (SDS), applicable regulations, or professional assessment.
Hazard information
Regulatory Information
Iron, tris(2,4-pentanedionato-.kappa.O2,.kappa.O4)-, (OC-6-11)- is listed on the EPA's Chemical Data Reporting (CDR) system. Manufacturers and importers of Iron, tris(2,4-pentanedionato-.kappa.O2,.kappa.O4)-, (OC-6-11)- are required to report information about their production and use of this chemical to the EPA under the Toxic Substances Control Act (TSCA). (40 eCFR Part 711)
Hazards SummaryIntraperitoneal LD50 (mouse) = 76 mg/kg; [RTECS] An eye irritant; Harmful by ingestion; [Alfa Aesar MSDS] See Iron oxide (Fe2O3).
Safety data
- F
- 21
- PPE
- dust mask type N95 (US), Eyeshields, Gloves
- wgk
- 3
- tsca
- TSCA listed
- rtecs
- NO8960000
- hs_code
- 29420000
- Toxicity
- LD50 orally in Rabbit: 1872 mg/kg
- risk_code
- 22-36
- Signal word
- Danger
- Symbol(GHS)
- GHS05,GHS07
- hazard_code
- Xn
- safety_code
- 26-37/39
- Storage Class
- 11 - Combustible Solids
- Hazard statements
- H302+H312+H332-H318
- REACH Registrations
- Active
- Hazard Classifications
- Acute Tox. 4 DermalAcute Tox. 4 InhalationAcute Tox. 4 OralEye Dam. 1
- Precautionary statements
- P261-P280-P301+P312-P302+P352+P312-P304+P340+P312-P305+P351+P338
Chemistry & industry
Uses & manufacturing
UsesUsed for scientific research and development; [Alfa Aesar MSDS]
U.S. Production2023: 4,200 lb
Industry UsesCatalyst
General Manufacturing Information
All Other Basic Organic Chemical Manufacturing
Iron, tris(2,4-pentanedionato-.kappa.O2,.kappa.O4)-, (OC-6-11)-: ACTIVE
Applications
UsesModerating and combustion catalyst, solid fuel catalyst, bonding agent, curing accelerator, intermediate.
UsesIron(III) 2,4-pentanedionate is used as a precatalyst and reagent in organic chemistry. It acts as a precursor for highly crystalline (Zn, Fe)Fe2O4
UsesChemical Synthesis of Monodisperse Magnetic Nanoparticles
General DescriptionThis product has been enhanced for catalytic efficiency.
Preparation methods
PreparationFerric acetylacetonate is prepared by shaking ferric hydroxide with an alcoholic solution of the reagent. It is an excellent quencher of triplet states.
Upstream & downstream products
Downstream products
Related reactions
473 records
Compound notes
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