Bis(pentane-2,4-dionato-O,O')iron
Basic information
- CAS
14024-17-0- Standard SMILES
CC(=O)/C=C(/C)[O-].CC(=O)/C=C(/C)[O-].[Fe+2]- InChIKey
LFORAFQNBQKDRY-FDGPNNRMSA-L- Molecular formula
- C10H14FeO4
- Average molar mass
- 254.06 g/mol
- Monoisotopic mass
- 254.024144
Overview
See also: Iron(II) acetylacetonate (annotation moved to).
Names & identifiers
- Preferred name
- Bis(pentane-2,4-dionato-O,O')iron
- IUPAC
- iron(2+);bis((Z)-4-oxopent-2-en-2-olate)
- English name
- Ferrous acetylacetonate
- Molecular formula
- C10H14FeO4
- Molecular weight
- 254.06
Names & synonyms
Bis(pentane-2,4-dionato-O,O')ironAI3-61033EINECS 237-851-4NSC 141152RefChem:569240237-851-4MFCD00144506Iron, bis(2,4-pentanedionato)-14024-17-0Ferrous acetylacetonateFerrous acetyacetonateWS3J2LZ9RW
Show more names
Fe(acac)2IRON(II) ACETYLACETONATEIron(Ⅱ) acetylacetonateFerroacetylacetonateAcetylacetoneferrous(Acetylacetonato)ironIron(II) acetylacetonEisen(II)acetylacetonatBis(acetylacetonato)iron
bis(acetylacetonato)iron(ii)SCHEMBL144674AKOS032949942Bis[(4-oxo-2-penten-2-yl)oxy]ironferrous;(Z)-4-oxopent-2-en-2-olateSY116709iron(2+);(Z)-4-oxopent-2-en-2-olateCS-0188123
Database identifiers
- CAS
14024-17-0- PubChem CID
- 5486775
- DTXSID
DTXSID101313033- UNII
- WS3J2LZ9RW
- EC Number
- 237-851-4
Properties
Computed structural properties
- Topological polar surface area
- 80.3 Ų
- Hydrogen bond donors
- 0
- Hydrogen bond acceptors
- 4
- Rotatable bonds
- 2
- Heavy atoms
- 15
- Formal charge
- 0
- Complexity
- 90.4
Physicochemical properties
- Melting point
- 175 °C · 175 °C (dec.)(lit.)
- storage temp.
- Inert atmosphere,Room Temperature
- solubility
- slightly soluble in benzene, toluene
- color
- orange-brown crystals, crystalline
- InChI
- InChI=1S/2C5H8O2.Fe/c2*1-4(6)3-5(2)7;/h2*3,6H,1-2H3;/q;;+2/p-2/b2*4-3-;
- InChIKey
- LFORAFQNBQKDRY-FDGPNNRMSA-L
- SMILES
- O([Fe]O/C(/C)=C\C(=O)C)/C(/C)=C\C(=O)C
- CAS DataBase Reference
- 14024 · 14024-17-0(CAS DataBase Reference)
- NIST Chemistry Reference
- Bis(acetylacetonate)iron(14024-17-0)
- Symbol(GHS)
- 7 · GHS07
- Signal word
- Warning
- Hazard statements
- 315 · H315-H319-H335
- Precautionary statements
- 261 · P261-P305+P351+P338
- Hazard Codes
- Xi
- Risk Statements
- 36 · 36/37/38
Safety & regulation
Safety information is for reference only and does not replace the supplier’s Safety Data Sheet (SDS), applicable regulations, or professional assessment.
GHS classification
GHS Classification
Warning
H315 (100%): Causes skin irritation [Warning Skin corrosion/irritation]
P261, P264, P264+P265, P271, P280, P302+P352, P304+P340, P305+P351+P338, P319, P321, P332+P317, P337+P317, P362+P364, P403+P233, P405, and P501 (click each P-code to see the statement)
Aggregated GHS information provided per 39 reports by companies from 2 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.
Hazard information
Hazard Classes and CategoriesSkin Irrit. 2 (100%)
Safety data
- wgk
- 3
- risk_code
- 36/37/38
- Signal word
- Warning
- Symbol(GHS)
- GHS07
- hazard_code
- Xi
- safety_code
- 26-36
- Hazard statements
- H315-H319-H335
- Precautionary statements
- P261-P305+P351+P338
Chemistry & industry
Applications
UsesFerrous acetylacetonate is used as organic synthesis catalysts.
Upstream & downstream products
Upstream raw materials
Additional notes
DefinitionFerrous acetylacetonate (Iron(II) Acetylacetonate) is an Iron source soluble in organic solvents as an organometallic compound. The high-purity acetylacetonate anion complexes by bonding each oxygen atom to the metallic cation to form a chelate ring; because of this property, acetylacetonates are commonly used in various catalysts and catalytic reagents for organic synthesis, including the fabrication of various shapes of carbon nanostructures via the use of chemical vapour deposition (CVD) and laser evaporation techniques. The numerous commercial applications for Iron include primary colourant in glass and ceramics, catalyst, the basis for low-grade magnets, and, because of its magnetic properties, is used extensively in memory tape.
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Compound notes
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