Tris(2,2,6,6-tetramethylheptane-3,5-dionato-O,O')europium
Basic information
- CAS
15522-71-1- Standard SMILES
CC(C)(C)C(=O)/C=C(\[O-])C(C)(C)C.CC(C)(C)C(=O)/C=C(\[O-])C(C)(C)C.CC(C)(C)C(=O)/C=C(\[O-])C(C)(C)C.[Eu+3]- InChIKey
DVUACRCEVJAWMS-LWTKGLMZSA-K- Molecular formula
- C33H57EuO6
- Average molar mass
- 701.8 g/mol
- Monoisotopic mass
- 702.33675
Names & identifiers
- Preferred name
- Tris(2,2,6,6-tetramethylheptane-3,5-dionato-O,O')europium
- IUPAC
- europium(3+);tris((Z)-2,2,6,6-tetramethyl-5-oxohept-3-en-3-olate)
- English name
- Tris(2,2,6,6-tetramethyl-3,5-heptanedionato)europium(III)
- Molecular formula
- C33H57EuO6
- Molecular weight
- 701.77
Names & synonyms
Tris(2,2,6,6-tetramethylheptane-3,5-dionato-O,O')europiumEuropium, tris(2,2,6,6-tetramethyl-3,5-heptanedionato-kappaO3,kappaO5)-, (OC-6-11)-Europium, tris(2,2,6,6-tetramethyl-3,5-heptanedionato-.kappa.O3,.kappa.O5)-, (OC-6-11)-RefChem:900152239-565-5(Dipivalomethanato)europium(III)15522-71-1NSC 147451Tris(dipivalomethanato)europiumTris(dipivaloylmethanato)europiumEuropium(III) 2,2,6,6-tetramethylheptane-3,5-dioneTris(2,2,6,6-tetramethyl-3,5-heptanedionato)europium
Show more names
EU(DPM)3Nsc147451EU(TMHD)3Resolve-ALEUROPIUM-THDRESOLVE-AL(TM)resolve-altm euResolve-Al?EuTMHDTris(tmhd)europium
Europium tris(2,2,6,6-tetramethyl-3,5-heptanedionate)Europium, tris(2,2,6,6-tetramethyl-3,5-heptanedionato-O,O')-, (OC-6-11)-Europium, tris(2,2,6,6-tetramethyl-3,5-heptanedionato-.kappa.O,.kappa.O')-, (OC-6-11)-EINECS 239-565-5Tris(2,2,6,6-tetramethyl-3,5-heptanedionato)europium(III)EUROPIUM(III)-DPMSCHEMBL29531991DTXSID601015363
Properties
Computed structural properties
- Topological polar surface area
- 120 Ų
- Hydrogen bond donors
- 0
- Hydrogen bond acceptors
- 6
- Rotatable bonds
- 9
- Heavy atoms
- 40
- Formal charge
- 0
- Complexity
- 199
Physicochemical properties
- Melting point
- 187 · 187-191 °C
- Boiling point
- 275 °C · 275°C
- storage temp.
- 2 · 2-8°C, protect from light, stored under nitrogen
- form
- Powder
- color
- yellow
- Sensitive
- Hygroscopic
- Hydrolytic Sensitivity
- 4 · 4: no reaction with water under neutral conditions
- InChIKey
- DVUACRCEVJAWMS-LWTKGLMZSA-K
- CAS DataBase Reference
- 15522 · 15522-71-1
- EPA Substance Registry System
- Europium, tris(2,2,6,6-tetramethyl-3,5-heptanedionato-.kappa.O,.kappa.O')-, (OC-6-11)- (15522-71-1)
- Symbol(GHS)
- 7 · GHS07
- Signal word
- Warning
- Hazard statements
- 315 · H315-H319-H335
- Precautionary statements
- 261 · P261-P280a-P304+P340-P305+P351+P338-P405-P501a
- Risk Statements
- 36 · 36/37/38
Safety & regulation
Safety information is for reference only and does not replace the supplier’s Safety Data Sheet (SDS), applicable regulations, or professional assessment.
GHS classification
GHS Classification
Warning
H315 (100%): Causes skin irritation [Warning Skin corrosion/irritation]
P261, P264, P264+P265, P271, P280, P302+P352, P304+P340, P305+P351+P338, P319, P321, P332+P317, P337+P317, P362+P364, P403+P233, P405, and P501 (click each P-code to see the statement)
Aggregated GHS information provided per 4 reports by companies from 1 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.
Safety data
- wgk
- 3
- tsca
- TSCA listed
- hs_code
- 2931.90.9051
- risk_code
- 36/37/38
- Signal word
- Warning
- Symbol(GHS)
- GHS07
- safety_code
- 26-36/37/39
- Hazard statements
- H315-H319-H335
- Precautionary statements
- P261-P280a-P304+P340-P305+P351+P338-P405-P501a
Chemistry & industry
Uses & manufacturing
General Manufacturing InformationEuropium, tris(2,2,6,6-tetramethyl-3,5-heptanedionato-.kappa.O3,.kappa.O5)-, (OC-6-11)-: ACTIVE
Applications
UsesTris(2,2,6,6-tetramethyl-3,5-heptanedionato)europium(III) (CAS# 15522-71-1) is a lanthanide-containing coordination complex which is used as an NMR shift reagent. Tris(2,2,6,6-tetramethyl-3,5-heptanedionato)europium(III) has also been used as a doping agent in GaN light-emitting diodes, providing improved luminescence properties.
Related reactions
0 records
No reaction records under the current filter.
Compound notes
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