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9H-Fluoren-2-aMine, N-[1,1'-biphenyl]-4-yl-9,9-diMethyl-N-[4-(9-phenyl-9H-carbazol-3-yl)phenyl]-

HCID 57746495
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Basic informationNames & identifiersPropertiesSafety & regulationChemistry & industryRelated reactionsCompound notes
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Basic information

CAS
1242056-42-3
Standard SMILES
CC1(C)c2ccccc2-c2ccc(N(c3ccc(-c4ccccc4)cc3)c3ccc(-c4ccc5c(c4)c4ccccc4n5-c4ccccc4)cc3)cc21
InChIKey
GJWBRYKOJMOBHH-UHFFFAOYSA-N
Molecular formula
C51H38N2
Average molar mass
678.86 g/mol

Names & identifiers

Preferred name
9H-Fluoren-2-aMine, N-[1,1'-biphenyl]-4-yl-9,9-diMethyl-N-[4-(9-phenyl-9H-carbazol-3-yl)phenyl]-
English name
9H-Fluoren-2-aMine, N-[1,1'-biphenyl]-4-yl-9,9-diMethyl-N-[4-(9-phenyl-9H-carbazol-3-yl)phenyl]-
Molecular formula
C51H38N2
Molecular weight
678.86

Names & synonyms

BCFNBCFN,99.9%9H-Fluoren-2-amine, N-[1,1'-biphenyl]-4-yl-9,9-dimethyl-N-[4...9,9-dimethyl-N-[4-(9-phenylcarbazol-3-yl)phenyl]-N-(4-phenylphenyl)fluoren-2-amineN-(4-Biphenylyl)-9,9-dimethyl-N-[4-(9-phenyl-9H-carbazol-3-yl)phenyl]-9H-fluoren-2-amineN-(biphenyl-4-yl)-9,9-dimethyl-N-(4-(9-phenyl-9H-carbazol-3-yl)phenyl)-9H-fiuoren-2-amineN-[1,1'-Diphenyl]-4-yl-9,9-dimethyl-N-[4-(9-phenyl-9H-carbazol-3-yl)phenyl]-9H-fluoren-2-amineN-[1,1′-biphenyl]-4-yl-9,9-dimethyl-N-[4-(9-phenyl-9H-carbazol-3-yl)phenyl]-9H-fluorene-2-amineN-[1,1'-Diphenyl]-4-yl-9,9-dimethyl-N-[4-(9-phenyl-9H-carbazol-3-yl)phenyl]-9H-fluorene-2-amineN-[[1,1'-Biphenyl]-4-yl]-9,9-dimethyl-N-[4-(9-phenyl-9H-carbazol-3-yl)phenyl]-9H-fluoren-2-amine

Database identifiers

CAS
1242056-42-3
PubChem CID
57746495
EC Number
801-651-0

Properties

Physicochemical properties

Melting point
155 · 155-156 °C
Density
1.14 · 1.14
storage temp.
Keep in dark place,Sealed in dry,Room Temperature
form
powder
pka
-2.8 · -2.80±0.40(Predicted)
color
white to yellow
InChIKey
GJWBRYKOJMOBHH-UHFFFAOYSA-N
SMILES
[n]2(c3c(c%10c2cccc%10)cc(cc3)c4ccc(cc4)N(c8ccc(cc8)c9ccccc9)c5cc6c(cc5)c7c(cccc7)C6(C)C)c1ccccc1
UNSPSC Code
12352116 · 12352116
NACRES
23 · NA.23
Symbol(GHS)
7 · GHS07
Signal word
Warning
Hazard statements
315 · H315-H302-H335-H319
Precautionary statements
264 · P264-P270-P301+P312-P330-P501-P264-P280-P302+P352-P321-P332+P313-P362-P264-P280-P305+P351+P338-P337+P313P
WGK Germany
3 · WGK 3
Storage Class
11 · 11 - Combustible Solids

Safety & regulation

Safety information is for reference only and does not replace the supplier’s Safety Data Sheet (SDS), applicable regulations, or professional assessment.

Safety data

wgk
WGK 3
Signal word
Warning
Symbol(GHS)
GHS07
Storage Class
11 - Combustible Solids
Hazard statements
H315-H302-H335-H319
Precautionary statements
P264-P270-P301+P312-P330-P501-P264-P280-P302+P352-P321-P332+P313-P362-P264-P280-P305+P351+P338-P337+P313P

Chemistry & industry

Applications · 1 item

UsesN-([1,1μ-biphenyl]-4-yl)-9,9-dimethyl-N-(4-(9-phenyl-9H-carbazol-3-yl)phenyl)-9H-fluoren-2-amine (BCFN) is an electron-rich material, with the HOMO energy level of 5.3 eV, the LUMO energy level of 2.2 eV and high hole mobility of 5.43 * 10-5 cm2V-1s-1. As a result, it is used as a hole-transport and hole-injection material in organic light-emitting diodes. BCFN has shown its advantages in improving the hole mobility of polymer-based hole transport layer; lower driving voltage of device, better efficiency, and higher EQE due to exciplex formation by utilizing in EML; and better device lifetimes in the combination of Ir(piq)2(acac) to act as an electron scavenger layer for an reported device. BCFN is a good morphologically stable material with Tg of 125 °C and Td of 375 °C. With a ET of 2.58 eV, BCFN is also a very good charge transporting layer material due to its large band gap (Eg = 3.1 eV) 2 for green, red and white phosphorescent organic light-emitting diodes (PhOLEDs).OLED Device Performance:BCFN increase the hole transport mobility of PVK (pure PVK: 2.09*10-9 V cm-1 S-1; 30% of BCFN in PVK: 9.86*10-7 V cm-1 S-1; 50% of BCFN in PVK: 1.15*10-5 V cm-1 S-1):1. ITO/PEDOT:PSS (40 nm)/PVK:BCFN (3:7, 20 nm)/BCFN:PFO (x:1-x, 80 nm)/CsF (1.5 nm)/Al (120 nm)Color: BlueBCFN in combination of ET1 to act as EML in forming exciplex and improve device performance:2. ITO/HIL/HTL/(ET1+P1) or (ET1+BCFN+P1(doped)/ETL/ LiF/AlColor: redDevice emission area of 81cm2, and at 1000 cd m-2, the efficiency exceeds 200 lm/W and the EQE exceeds 50 %.lifespan@95: from 71h to 133hBCFN in combination with Ir(piq)2(acac) as electron scavenger layer:3. ITO/NDP series in BCFN (3wt.%, 10nm)/BCFN(160nm) or BCFN(130nm)+BCFN:Ir(piq)2(acac)(2wt.%, 10nm)+BCFN(20)/ [Ir(TMSBppy)ppy2]:BPTZBC (10 wt.%, 40nm))/ TPBi:Liq (1:1 wt. % ratio, 36nm)/ Liq (0.1nm)/Al (60 nm)Color: yellowEfficiencies are not affected.lifespan@95: from 71h to 133h', 'N-([1,1μ-Biphenyl]-4-yl)-9,9-dimethyl-N-(4-(9-phenyl-9H-carbazol-3-yl)phenyl)-9H-fluoren-2-amine can be used in different application areas as an emissive layer or hole transport layer due the presence of π-conjugated structure and electron-donating/accepting groups. It is suitable to be used in R&D studies such as organic field-effect transistors (OFETs), molecular electronics, sensors, organic photovoltaics (OPVs), and organic light-emitting diodes (OLEDs).

Upstream & downstream products

Upstream raw materials

9-Phenyl-9H-carbazol-3-ylboronic acid

Related reactions

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Compound notes

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On this pageBasic informationNames & identifiersPropertiesSafety & regulationChemistry & industryRelated reactionsCompound notes
N-(4-biphenyl)-(9,9-dimethylfluoren-2--yl)Amine
3-(4-Chlorophenyl)-9-phenyl-9H-carbazole
3-(4-bromophenyl)-N-phenylcarbazole
N-[1,1'-biphenyl]-4-yl-N-(4-broMophenyl)-9,9-diMethyl-9H-Fluoren-2-aMine
Triphenylphosphine
Sodium tert-butoxide
Tris(dibenzylideneacetone)dipalladium
Toluene

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Jilin Uland Tech Co.,Ltd.+86-16643553268 · [email protected]
武汉敬康恩生物医药科技有限公司13720134139 086-15871494362 13720134139 · [email protected]
毕佳索(上海毕得医药科技股份有限公司)400-6005915 · [email protected]
BAYNOE CHEM CO.,LTD+86-21-34783353 +8615000719740 · [email protected]
杭州品高化工有限公司0571-87658025 · [email protected]
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上海遐瑞医药科技有限公司+86-021-61551413 · [email protected]
深圳睿迅光电材料科技有限公司0755-26718755; 15889762949 · [email protected]
上海药诚医药科技合伙企业(有限合伙)400-6181121 18616381138 · [email protected]
Hangzhou IKSChem Technology Co., Limited13625816949 · [email protected]
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山东大有药物研发有限公司[email protected] 15165037910 · [email protected]
石家庄斯迪亚诺精细化工有限公司0311-89250318 13582355795 · [email protected]
陕西莱特光电材料股份有限公司88320727 17691239725 · [email protected]
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上海毕得医药科技股份有限公司400-164-7117 18317119277 · [email protected]
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Alfa Chemistry1-516-6625404 · [email protected]
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上海源叶生物科技有限公司18916372613 · [email protected]
河北赛利生物科技有限公司18932901920 · [email protected]
上海麦克林生化科技股份有限公司50706066 15221275939 · [email protected]
Yurui (Shanghai) Chemical Co., Ltd.+86-021-50456736 +8613331628239;+8619121032725 · [email protected]