13682-94-5C[Si](C)(C)C=CBrFKXCNOSKBLGEMQ-UHFFFAOYSA-N13682-94-5DTXSID20929562UsesSilane, (2-broMoethenyl)triMethyl- can introduce a β-(trimethylsilyl)vinyl moiety; the resulting vinyl silane can undergo useful electrophilic substitution with a TMS group.
Preparation(E)-isomer: by the sequence of eq 1, or more directly from the readily available Vinyltrimethylsilane (eq 2). (Z)-isomer: by bromination-debromosilylation of 1,2- bis(trimethylsilyl)ethylene (eq 3).
No reaction records under the current filter.
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