Basic information
- CAS
592-55-2- Standard SMILES
CCOCCBr- InChIKey
MMYKTRPLXXWLBC-UHFFFAOYSA-N- Molecular formula
- C4H9BrO
- Average molar mass
- 153.02 g/mol
- Monoisotopic mass
- 151.98367701
Overview
2-bromoethyl ethyl ether appears as a colorless liquid. Vapors are heavier than air.
Names & identifiers
- Preferred name
- 2-Bromoethyl ethyl ether
- IUPAC
- 1-bromo-2-ethoxyethane
- English name
- 2-Bromoethyl ethyl ether
- Molecular formula
- C4H9BrO
- Molecular weight
- 153.02
Names & synonyms
2-Bromoethyl ethyl ether1-Bromo-2-ethoxyethane592-55-22-Ethoxyethyl bromideETHANE, 1-BROMO-2-ETHOXY-2-Bromoethoxyethane1-Ethoxy-2-bromoethaneEther, 2-bromoethyl ethyl1-Bromo-3-oxapentanebromoethyl ethyl ether1-Bromo-2-ethoxyethyleneAK4DQ3EL7A
Show more names
TIMTEC-BB SBB0083322-BROMODIETHYL ETHER2-BroMoethyl ethyl e2-Bromo-2-ethoxyethane1-bromo-2-ethoxy-ethan
NSC 8026NSC-8026EINECS 209-763-6UN23405-BROMO-3-OXAPENTANEAI3-52299DTXSID2060464MMYKTRPLXXWLBC-UHFFFAOYSA-
Database identifiers
- CAS
592-55-2- PubChem CID
- 61141
- DTXSID
DTXSID2060464- UNII
- AK4DQ3EL7A
- EC Number
- 209-763-6
- Nikkaji
- J450B
Properties
Computed structural properties
- XLogP
- 1.2
- Topological polar surface area
- 9.2 Ų
- Hydrogen bond donors
- 0
- Hydrogen bond acceptors
- 1
- Rotatable bonds
- 3
- Heavy atoms
- 6
- Formal charge
- 0
- Complexity
- 23.5
Experimental & physicochemical properties
Chemical Classes
Other Classes -> Halogenated Ethers
Flammable agents - 3rd degree
SpringerMaterials PropertiesOptical coefficient
Physical Description
2-bromoethyl ethyl ether appears as a colorless liquid. Vapors are heavier than air.
Colorless liquid; [CAMEO]
Physicochemical properties
- Boiling point
- 149 · 149-150 °C750 mm Hg(lit.)
- Density
- 1.357 g/mL · 1.357 g/mL at 25 °C(lit.)
- refractive index
- 20 · n20/D 1.445(lit.)
- Flash point
- 70 °F · 70 °F
- storage temp.
- Freezer
- form
- Liquid
- Specific Gravity
- 1.357 · 1.357
- color
- Clear colorless to brown
- Water Solubility
- SLIGHTLY SOLUBLE
- Sensitive
- Moisture Sensitive
- BRN
- 1731362 · 1731362
- InChI
- InChI=1S/C4H9BrO/c1-2-6-4-3-5/h2-4H2,1H3
- InChIKey
- MMYKTRPLXXWLBC-UHFFFAOYSA-N
- SMILES
- C(Br)COCC
- CAS DataBase Reference
- 592 · 592-55-2(CAS DataBase Reference)
- FDA UNII
- 4 DQ3EL7A · AK4DQ3EL7A
- NIST Chemistry Reference
- 1 · Ethane, 1-bromo-2-ethoxy-(592-55-2)
- EPA Substance Registry System
- 1 · Ethane, 1-bromo-2-ethoxy- (592-55-2)
- UNSPSC Code
- 12352112 · 12352112
- NACRES
- 22 · NA.22
- Symbol(GHS)
- 2 · GHS02,GHS07
- Signal word
- Danger
- Hazard statements
- 315 · H315-H319-H225
- Precautionary statements
- 501 · P501-P240-P210-P233-P243-P241-P242-P264-P280-P370+P378-P337+P313-P305+P351+P338-P362+P364-P303+P361+P353-P332+P313-P403+P235
- Hazard Codes
- Xi
- Risk Statements
- 10 · 10-36/37/38
- Safety Statements
- 26 · 26-37/39-16
- RIDADR
- 2340 · UN 2340
- WGK Germany
- 3 · 3
- RTECS
- 3950000 · KN3950000
- TSCA
- TSCA listed
- HazardClass
- 3 · 3
- PackingGroup
- II
- HS Code
- 29091900 · 29091900
- Storage Class
- 3 · 3 - Flammable liquids
- Hazard Classifications
- 2 · Flam. Liq. 2
- Limited Quantities
- 1 L · 1.0 L (0.3 gallon) (liquid)
- Excepted Quantities
- Max Inner Pack (30g or 30ml) and Max Outer Pack (500g or 500ml)
Safety & regulation
GHS classification
GHS Classification
Danger
H225 (100%): Highly Flammable liquid and vapor [Danger Flammable liquids]
P210, P233, P240, P241, P242, P243, P261, P264, P264+P265, P271, P280, P302+P352, P303+P361+P353, P304+P340, P305+P351+P338, P319, P321, P332+P317, P337+P317, P362+P364, P370+P378, P403+P233, P403+P235, P405, and P501 (click each P-code to see the statement)
Aggregated GHS information provided per 46 reports by companies from 5 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.
Hazard information
Regulatory Information
Bromoethyl ethyl ether: Does not have an individual approval but may be used under an appropriate group standard
The New Jersey Worker and Community Right to Know Act requires public and private employers to provide information about hazardous substances at their workplaces. (N.J.S.A. 34:5A-1 et. seq.)
DOT LabelFlammable Liquid
Fire Hazards
Excerpt from ERG Guide 130 [Flammable Liquids (Water-Immiscible / Noxious)]:
· HIGHLY FLAMMABLE: Will be easily ignited by heat, sparks or flames.
Health Hazards
Excerpt from ERG Guide 130 [Flammable Liquids (Water-Immiscible / Noxious)]:
· May cause toxic effects if inhaled or absorbed through skin.
Hazards SummaryA skin and strong eye irritant; [Alfa Aesar MSDS] See beta-Chloroethyl methyl ether.
DOT ID and Guide2340 130
Reactive GroupEthers
Reactivity AlertsHighly Flammable
Reactivity Profile
Ethers, such as 2-BROMOETHYL ETHYL ETHER, can act as bases. They form salts with strong acids and addition complexes with Lewis acids. The complex between diethyl ether and boron trifluoride is an example. Ethers may react violently with strong oxidizing agents. In other reactions, which typically involve the breaking of the carbon-oxygen bond, ethers are relatively inert.
DOT Hazard Classification
2-Bromoethyl ethyl ether
UN2340
Class 3 Flammable and combustible liquid (49 eCFR § 173.120)
PG II: the degree of danger presented by the material is medium
Air and Water ReactionsHighly flammable. Soluble in water and slightly denser than water.
Hazard Classes and Categories
Flam. Liq. 2 (100%)
Flammable agents - 3rd degree, Reactive agents - 1st degree
Safety & protection
Fire FightingExcerpt from ERG Guide 130 [Flammable Liquids (Water-Immiscible / Noxious)]:
Accidental Release Measures
· CALL 911. Then call emergency response telephone number on shipping paper. If shipping paper not available or no answer, refer to appropriate telephone number listed on the inside back cover.
· ELIMINATE all ignition sources (no smoking, flares, sparks or flames) from immediate area.
First Aid
Excerpt from ERG Guide 130 [Flammable Liquids (Water-Immiscible / Noxious)]:
General First Aid:
Exposure Control and Personal Protection· Wear positive pressure self-contained breathing apparatus (SCBA).
Nonfire Spill ResponseExcerpt from ERG Guide 130 [Flammable Liquids (Water-Immiscible / Noxious)]:
Isolation and Evacuation
Excerpt from ERG Guide 130 [Flammable Liquids (Water-Immiscible / Noxious)]:
Immediate precautionary measure
Personal Protective Equipment (PPE)Excerpt from ERG Guide 130 [Flammable Liquids (Water-Immiscible / Noxious)]:
Emergency Response Planning GuidelinesCAUTION: The majority of these products have a very low flash point. Use of water spray when fighting fire may be inefficient.
Safety data
- wgk
- 3
- tsca
- TSCA listed
- rtecs
- KN3950000
- ridadr
- UN 2340
- hs_code
- 29091900
- risk_code
- 10-36/37/38
- Signal word
- Danger
- Symbol(GHS)
- GHS02,GHS07
- hazard_code
- Xi
- safety_code
- 26-37/39-16
- hazard_class
- 3
- Storage Class
- 3 - Flammable liquids
- packing_group
- II
- Hazard statements
- H315-H319-H225
- Limited Quantities
- 1.0 L (0.3 gallon) (liquid)
- Excepted Quantities
- Max Inner Pack (30g or 30ml) and Max Outer Pack (500g or 500ml)
- Hazard Classifications
- Flam. Liq. 2
- Precautionary statements
- P501-P240-P210-P233-P243-P241-P242-P264-P280-P370+P378-P337+P313-P305+P351+P338-P362+P364-P303+P361+P353-P332+P313-P403+P235
Chemistry & industry
Uses & manufacturing
UsesUsed to make other chemicals and insecticides; [NJ-HSFS]
General Manufacturing InformationEthane, 1-bromo-2-ethoxy-: ACTIVE
Applications
Uses2-Bromoethyl ethyl ether is an important raw material and intermediate used in organic synthesis, pharmaceuticals, agrochemicals and dyestuff fields.
General DescriptionA colorless liquid. Flash point 5°F. Vapors are heavier than air.
Upstream & downstream products
Upstream raw materials
Downstream products
Suppliers100 total
国药集团化学试剂有限公司86-21-63210123 · [email protected]
梯希爱(上海)化成工业发展有限公司021-67121386 · [email protected]
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Related reactions
202 records
Compound notes
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