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Barium perchlorate

HCID 61623
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Basic informationOverviewNames & identifiersPropertiesSafety & regulationChemistry & industryRelated reactionsCompound notes
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Basic information

CAS
13465-95-7
Standard SMILES
[Ba+2].[O-][Cl+3]([O-])([O-])[O-].[O-][Cl+3]([O-])([O-])[O-]
InChIKey
OOULUYZFLXDWDQ-UHFFFAOYSA-L
Molecular formula
BaCl2O8
Average molar mass
336.23 g/mol
Monoisotopic mass
335.802269

Overview

Barium perchlorate appears as a white crystalline solid. Noncombustible, but accelerates burning of combustible materials. May explode if large quantities are involved in a fire or the combustible material is finely divided. Prolonged exposure to fire or heat may result in an explosion. Used to make explosives. (NTP, 1992)

Names & identifiers

Preferred name
Barium perchlorate
IUPAC
barium(2+) diperchlorate
English name
BARIUM PERCHLORATE HYDRATE 98
Molecular formula
BaCl2H2O9
Molecular weight
354.24348

Names & synonyms

BARIUM PERCHLORATE13465-95-7Barium diperchloratePerchloric acid, barium saltPerchloric acid, barium salt (2:1)CPS 55REY48PA0C98(perchloryloxy)bario perchlorateDTXSID90890699RefChem:116546DTXCID101029947236-710-4
Show more names
BARIUM PERCHLORATE HYDRATE 98BARIUM PERCHLORATE HYDRATE, 99+%
682-755-1barium(2+);diperchlorateBARIUM PERCHLORATE, ANHYDROUSMFCD00003440BaCl2O8BARIUM PERCHLORATE (BA(CLO4)2)Perchloric acid, bariumsalt (2:1)EINECS 236-710-4

Database identifiers

CAS
13465-95-7、15318-52-2
PubChem CID
61623
DTXSID
DTXSID90890699
UNII
EY48PA0C98
EC Number
236-710-4、682-755-1
Nikkaji
J43.690I

Properties

Computed structural properties

Topological polar surface area
149 Ų
Hydrogen bond donors
0
Hydrogen bond acceptors
8
Rotatable bonds
0
Heavy atoms
11
Formal charge
0
Complexity
95.8

Experimental & physicochemical properties

Chemical ClassesOther Classes -> Perchlorates
Density3.2 at 68 °F (USCG, 1999) - Denser than water; will sink
Melting Point941 °F (USCG, 1999)
Physical Description · 2 items

Barium perchlorate appears as a white crystalline solid. Noncombustible, but accelerates burning of combustible materials. May explode if large quantities are involved in a fire or the combustible material is finely divided. Prolonged exposure to fire or heat may result in an explosion. Used to make explosives. (NTP, 1992)

White solid; [CAMEO] White powder; [MSDSonline] Solubility--no data found;

Physicochemical properties

Symbol(GHS)
3 · GHS03,GHS07
Signal word
Danger
Hazard statements
332 · H332-H302-H271
Precautionary statements
264 · P264-P270-P301+P312-P330-P501-P210-P220-P221-P280-P283-P306+P360-P371+P380+P375-P370+P378-P501-P261-P271-P304+P340-P312
Hazard Codes
O,Xn

Safety & regulation

Safety information is for reference only and does not replace the supplier’s Safety Data Sheet (SDS), applicable regulations, or professional assessment.

GHS classification

GHS Classification · 6 items

Danger

H271: May cause fire or explosion; strong Oxidizer [Danger Oxidizing liquids; Oxidizing solids]

P210, P220, P261, P264, P270, P271, P280, P283, P301+P317, P304+P340, P306+P360, P317, P330, P370+P378, P371+P380+P375, P420, and P501 (click each P-code to see the statement)

Danger

H271 (98%): May cause fire or explosion; strong Oxidizer [Danger Oxidizing liquids; Oxidizing solids]

P210, P220, P261, P264, P270, P271, P280, P283, P301+P317, P304+P340, P306+P360, P317, P330, P370+P378, P371+P380+P375, P420, and P501 (click each P-code to see the statement)

Hazard information

Regulatory Information · 3 items

Chemical: Perchloric acid, barium salt

Perchloric acid, barium salt: HSNO Approval: HSR001313 Approved with controls

The New Jersey Worker and Community Right to Know Act requires public and private employers to provide information about hazardous substances at their workplaces. (N.J.S.A. 34:5A-1 et. seq.)

DOT LabelOxidizer Poison
Fire Hazards · 3 items

Behavior in Fire: Increases the intensity of fire. Containers may explode. (USCG, 1999)

· These substances will accelerate burning when involved in a fire.

· These substances will accelerate burning when involved in a fire.

Health Hazards · 3 items

Inhalation or contact with eyes or skin causes irritation. Ingestion causes excessive salivation, vomiting, colic, diarrhea, convulsive tremors, slow, hard pulse, and elevated blood pressure; hemorrhages may occur in the stomach, intestines, and kidneys; muscular paralysis may follow. (USCG, 1999)

· Toxic by ingestion.

· Toxic by ingestion.

Chemistry & industry

Pharmacology

Metabolism/Metabolites · 1 item

Barium compounds are absorbed via ingestion and inhalation, the extent of which depends on the individual compound. In the body, the majority of the barium is found in the bone, while small amounts exists in the muscle, adipose, skin, and connective tissue. Barium is not metabolized in the body, but it may be transported or incorporated into complexes or tissues. Barium is excreted in the urine and faeces. (L214)

Uses & manufacturing

UsesUsed in chemical analyses; [Merck Index] Used to make explosives; [Hawley]
General Manufacturing InformationPerchloric acid, barium salt (2:1): ACTIVE

Suppliers5 total

Career Henan Chemica Co+86-0371-86658258 +86-13203830695 · [email protected]
梯希爱(上海)化工贸易有限公司021-61109150 · [email protected]
天津希恩思生化科技有限公司400 638 7771 · [email protected]
天津希恩思生化科技有限公司400-6387771-6039 18920764717 · [email protected]
DAYANG CHEM (HANGZHOU) CO.,LTD+86-88938639 +86-17705817739 · [email protected]

Related reactions

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Compound notes

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On this pageBasic informationOverviewNames & identifiersPropertiesSafety & regulationChemistry & industryRelated reactionsCompound notes
Risk Statements
9 · 9-20/22
Safety Statements
27 · 27
RIDADR
1447 · UN 1447 5.1/PG 2
WGK Germany
1 · 1
Hazards Summary · 1 item

Fire and explosion risk on contact with organic materials; Toxic by ingestion; [Hawley] A strong oxidizing agent; Explosive; A skin and eye irritant; [CAMEO] A skin and eye irritant; [eChemPortal: ERMA] An oxidizing agent that may explode on contact with combustible materials; An irritant; [MSDSonline] See Barium. See PERCHLORATES.

DOT ID and Guide · 2 items

1447 141

3406 141

Reactive GroupOxidizing Agents, Strong
Reactivity AlertsExplosive
Reactivity ProfileReflux heating of BARIUM PERCHLORATE with alcohols yields perchlorate esters, which are highly explosive [Kirk-Othmer 2nd ed. 5:75 1963]. A strong oxidizing agent. May react violently with organic materials.
DOT Hazard Classification · 6 items

Barium perchlorate, solid

UN1447

Div 5.1 Oxidizer (49 eCFR § 173.127)

Div 5.1 Oxidizer (49 eCFR § 173.127)

PG II: the degree of danger presented by the material is medium

Barium perchlorate, solution

Air and Water ReactionsWater soluble.
Hazard Classes and Categories · 5 items

Ox. Sol. 1 (98%)

Ox. Sol. 1 (100%)

Oxidising solid - category 1

Oxidizing solids - Category 2

Ox. Sol. 1

Safety & protection

Fire FightingExcerpt from ERG Guide 141 [Oxidizers - Toxic]:
Accidental Release Measures · 4 items

· CALL 911. Then call emergency response telephone number on shipping paper. If shipping paper not available or no answer, refer to appropriate telephone number listed on the inside back cover.

· Keep combustibles (wood, paper, oil, etc.) away from spilled material.

· CALL 911. Then call emergency response telephone number on shipping paper. If shipping paper not available or no answer, refer to appropriate telephone number listed on the inside back cover.

· Keep combustibles (wood, paper, oil, etc.) away from spilled material.

First Aid · 3 items

Get medical attention. Alert doctor to possibility of barium poisoning, particularly if compound was swallowed.

General First Aid:

General First Aid:

Exposure Control and Personal Protection · 3 items

· Wear positive pressure self-contained breathing apparatus (SCBA).

· Wear positive pressure self-contained breathing apparatus (SCBA).

0.5 [mg/m3], as Ba, inhalable fraction(soluble compds)[German Research Foundation (DFG)]

Nonfire Spill ResponseExcerpt from ERG Guide 141 [Oxidizers - Toxic]:
Isolation and Evacuation · 3 items

Excerpt from ERG Guide 141 [Oxidizers - Toxic]:

Immediate precautionary measure

Immediate precautionary measure

Minimum Risk LevelIntermediate Oral: 0.2 mg/kg/day (L134) Chronic Oral: 0.2 mg/kg/day (L134)
Threshold Limit Values (TLV)0.5 [mg/m3], as Ba
Permissible Exposure Limit (PEL)0.5 [mg/m3], as Ba
Personal Protective Equipment (PPE)Goggles or face shield; dust respirator; rubber gloves and shoes; suitable coveralls. (USCG, 1999)
Emergency Response Planning Guidelines · 2 items

Small Fire

Small Fire

Immediately Dangerous to Life or Health (IDLH)50.0 [mg/m3], as Ba

Toxicology

TreatmentIntravenous infusion of potassium often relieves many of the symptoms of barium toxicity. (L214)
Health Effects · 1 item

The health effects of the different barium compounds depend on how well the compound dissolves in water or the stomach contents. At low doses, barium acts as a muscle stimulant, while higher doses affect the nervous system, causing cardiac irregularities, tremors, weakness, anxiety, dyspnea, paralysisand possibly death. Barium may also cause gastrointestinal disturbances, damage the kidneys and cause decreases in body weight. (L214)

Adverse EffectsNephrotoxin - The chemical is potentially toxic to the kidneys in the occupational setting.
Exposure RoutesOral (L214) ; inhalation (L214)
Toxicity Summary · 1 item

Barium is a competitive potassium channel antagonist that blocks the passive efflux of intracellular potassium, resulting in a shift of potassium from extracellular to intracellular compartments. The intracellular translocation of potassium results in a decreased resting membrane potential, making the muscle fibers electrically unexcitable and causing paralysis. Some of these barium's effects may also be due to barium induced neuromuscular blockade and membrane depolarization. (L214)

Signs and Symptoms · 1 item

Ingesting excess barium may cause vomiting, abdominal cramps, diarrhea, difficulties in breathing, increased or decreased blood pressure, numbness around the face, and muscle weakness. High levels may result in changes in heart rhythm or paralysis and possibly death. (L214)

Carcinogen ClassificationNo indication of carcinogenicity to humans (not listed by IARC).

Safety data

wgk
1
ridadr
UN 1447 5.1/PG 2
risk_code
9-20/22
Signal word
Danger
Symbol(GHS)
GHS03,GHS07
hazard_code
O,Xn
safety_code
27
Hazard statements
H332-H302-H271
Precautionary statements
P264-P270-P301+P312-P330-P501-P210-P220-P221-P280-P283-P306+P360-P371+P380+P375-P370+P378-P501-P261-P271-P304+P340-P312