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Sodium silicate nonahydrate

HCID 61639
NotesReactions
Basic informationOverviewNames & identifiersPropertiesSafety & regulationChemistry & industryRelated reactionsCompound notes
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Basic information

CAS
13517-24-3
Standard SMILES
O.O.O.O.O.O.O.O.O.O=[Si]([O-])[O-].[Na+].[Na+]
InChIKey
PHIQPXBZDGYJOG-UHFFFAOYSA-N
Molecular formula
H18Na2O12Si
Average molar mass
284.2 g/mol
Monoisotopic mass
284.03629111

Overview

Sodium silicate nonahydrate is a hydrate that is the nonahydrate form of sodium silicate. It contains a sodium silicate.

Names & identifiers

Preferred name
Sodium silicate nonahydrate
IUPAC
disodium;dioxido(oxo)silane;nonahydrate
English name
SODIUM METASILICATE NONAHYDRATE
Molecular formula
H5NaO4Si
Molecular weight
120.11

Names & synonyms

Sodium metasilicate nonahydrate13517-24-3Silicic acid (H2SiO3), disodium salt, nonahydratesodium silicate nonahydrateD8D44215LZDISODIUM METASILICATE NONAHYDRATEDTXSID9029728CHEBI:132108RefChem:183975DTXCID109728disodium;dioxido(oxo)silane;nonahydrateUNII-D8D44215LZ
Show more names
Sodium Meta Silicate LRSODIUM META-SILICATE 9 HYDSodiumsilicate,nonahydrateSODIUM M-SILICATE, HYDROUSSodium metasilicate nohydrateSodiummetasilicateenneahydrateSODIUM META-SILICATE, 9-HYDRATESodium metasilicale nonahydrateSODIUM SILICATE, META NONAHYDRATE
H18Na2O12SiSCHEMBL578147PHIQPXBZDGYJOG-UHFFFAOYSA-NAKOS030228265FS57695sodium oxosilanebis(olate)--water (1/9)SODIUM METASILICATE NONAHYDRATE [MI]Sodium oxosilanebis(olate)--water (2/1/9)

Database identifiers

CAS

Properties

Computed structural properties

Topological polar surface area
72.2 Ų
Hydrogen bond donors
9
Hydrogen bond acceptors
12
Rotatable bonds
0
Heavy atoms
15
Formal charge
0
Complexity
18.8

Experimental & physicochemical properties

Chemical ClassesMetals -> Metals, Inorganic Compounds
Density2.614 @25 °C
Melting Point1089 °C
Physical DescriptionEfflorescent solid; [Merck Index] Hygroscopic solid; [Sigma-Aldrich MSDS]

Physicochemical properties

Melting point
72.2 ℃ · 72.2℃ [OXY93]
Density
2.61 · 2.61
solubility
2 O: · H2O: soluble(lit.)
form
Solid
color
White
Water Solubility
100 parts · parts/100 parts solution in H2O: 27.5 (20°C), 44.5 (35°C), 62.8 (45°C), 80.9 (55°C), 84.0 (60°C), 91.2 (70°C) [OXY93]
Stability
Stable.
Major Application
agriculture
InChI
InChI=1S/Na.H2O3Si.H2O.H/c;1-4(2)3;;/h;1-2H;1H2;

Safety & regulation

Safety information is for reference only and does not replace the supplier’s Safety Data Sheet (SDS), applicable regulations, or professional assessment.

GHS classification

GHS Classification · 6 items

Danger

H314 (99.5%): Causes severe skin burns and eye damage [Danger Skin corrosion/irritation]

P260, P261, P264, P264+P265, P271, P280, P301+P330+P331, P302+P361+P354, P304+P340, P305+P354+P338, P316, P317, P319, P321, P363, P403+P233, P405, and P501 (click each P-code to see the statement)

Aggregated GHS information provided per 187 reports by companies from 9 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.

Danger

H314: Causes severe skin burns and eye damage [Danger Skin corrosion/irritation]

Hazard information

Regulatory InformationSilicic acid (H2SiO3), disodium salt, nonahydrate: Does not have an individual approval but may be used under an appropriate group standard
Hazards Summary · 1 item

Corrosive to moistened rabbit skin; Sodium metasilicate was not sensitizing in a local lymph node assay study of mice; Similar uses and adverse effects are expected from the hydrous and anhydrous forms (Sodium metasilicate pentahydrate, Sodium metasilicate nonahydrate, Sodium metasilicate, Sodium silicate, and Potassium silicate). One case of occupational contact urticaria reported from sodium silicate; [OECD SIDS: Soluble Silicates - 2004] Causes burns; Inhalation may cause corrosive injuries to upper respiratory tract; [Sigma-Aldrich MSDS] See Sodium metasilicate.

Hazard Classes and Categories · 2 items

Skin Corr. 1B (99.5%)

Skin corrosion/irritation - Category 1

Safety & protection

Protective Action Criteria (PAC) · 3 items

Chemistry & industry

Uses & manufacturing

Uses · 2 items

Used as a starting material for zeolites and silica catalysts, as an adhesive and binder, corrosion inhibitor, penetrating sealant, fireproofing agent (wood, paper, and fabric), detergent booster, and shell coating material to preserve eggs; Also used in cements, drilling fluids, and waste water treatment; [Merck Index] Alkali metal silicates are used as starting materials for products like silicas and zeolites, in detergents and cleaners, and pulp and paper production; Also used to a lesser extent in soil stabilization and sealing, adhesives and binders (construction materials, paperboard and cardboard, ceramic binders, refractories, welding rods, and foundry molds and cores), surface coatings (titanium dioxide production, paints for masonry and glass, and spray coatings for tunnel construction and mining), water treatment (corrosion protection), enhanced oil recovery, and textile processing (bleach and dye stabilizing); [OECD SIDS: Soluble Silicates - 2004]

Molding and Core Making [Category: Foundry]

Household ProductsInformation on 2 consumer products that contain Sodium metasilicate nonahydrate in the following categories is provided:
Applications · 3 items

DescriptionSodium metasilicate non-hydrate is the non-hydrate form of sodium metasilicate. Sodium metasilicate (chemical formula: Na2SiO3) is a kind of sodium silicate, appearing as a powdered or flaked solid. It is used in cements, passive fire protection, textile and lumber processing, refractories, and automobiles. It has various kinds of applications. The major applications are in detergents, paper, water treatment, and construction materials as well as dye auxiliary. In addition, it also has many niche and hobby applications such as used in food preservation, metal repair, automotive repair, home-brewing, aquaculture and pottery. It is manufactured through the reaction between sodium carbonate and silicon dioxide.

UsesSodium Metasilicate Nonahydrate is used in preparation method and application of Cationic Polyacrylamide modified Silicon Dioxide/Calcium Inosilicate material in wastewater treatment.

UsesSilicon (Si) has been reported to effectively manage some pests and diseases of plants.Exogenous application of silicon (Si) in the form of sodium metasilicate reduced disease development caused by Penicillium expansum and Monilinia fructicola in sweet cherry fruit at 20 degrees C. The inhibition of fruit decay was correlated closely with Si concentrations.

Related reactions

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Compound notes

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On this pageBasic informationOverviewNames & identifiersPropertiesSafety & regulationChemistry & industryRelated reactionsCompound notes
13517-24-3
PubChem CID
61639
DTXSID
DTXSID9029728
ChEBI
CHEBI:132108
UNII
D8D44215LZ
EC Number
603-903-3
InChIKey
PHIQPXBZDGYJOG-UHFFFAOYSA-N
SMILES
[Si](=O)(O)O.[NaH].O
CAS DataBase Reference
13517 · 13517-24-3(CAS DataBase Reference)
FDA UNII
8 D44215LZ · D8D44215LZ
EPA Substance Registry System
Silicic acid (H2SiO3), disodium salt, nonahydrate (13517-24-3)
UNSPSC Code
12352302 · 12352302
NACRES
72 · NA.72
Symbol(GHS)
5 · GHS05,GHS07
Signal word
Danger
Hazard statements
290 · H290-H314-H335
Precautionary statements
260 · P260-P280-P303+P361+P353-P305+P351+P338+P310
target organs
Respiratory system
PPE
3 · Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges
Hazard Codes
C
Risk Statements
34 · 34-37
Safety Statements
13 · 13-36/37/39-45-24/25
RIDADR
3253 · UN 3253 8/PG 3
WGK Germany
1 · 1
HazardClass
8 · 8
PackingGroup
III
HS Code
28391100 · 28391100
Storage Class
8 A · 8A - Combustible corrosive hazardous materials
Hazard Classifications
1 Met · Eye Dam. 1Met. Corr. 1Skin Corr. 1BSTOT SE 3

8.1 [mg/m3]

89 [mg/m3]

530 [mg/m3]

Toxicology

Adverse EffectsDermatotoxin - Skin burns.

Safety data

PPE
Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges
wgk
1
ridadr
UN 3253 8/PG 3
hs_code
28391100
risk_code
34-37
Signal word
Danger
Symbol(GHS)
GHS05,GHS07
hazard_code
C
safety_code
13-36/37/39-45-24/25
hazard_class
8
Storage Class
8A - Combustible corrosive hazardous materials
packing_group
III
target organs
Respiratory system
Hazard statements
H290-H314-H335
Hazard Classifications
Eye Dam. 1Met. Corr. 1Skin Corr. 1BSTOT SE 3
Precautionary statements
P260-P280-P303+P361+P353-P305+P351+P338+P310

Upstream & downstream products

Upstream raw materials

SODIUM METASILICATE PENTAHYDRATE

Suppliers101 total

国药集团化学试剂有限公司86-21-63210123 · [email protected]
北京华美互利生物化工010-56205725 · [email protected]
上海阿拉丁生化科技股份有限公司400-6206333 13167063860 · [email protected]
湖南韵邦生物科技股份有限公司0731-88532326 13319508186 · [email protected]
广州纳珑化工有限公司13192879270; 13192879270 · [email protected]
湖北成丰化工有限公司13125175253 · [email protected]
武汉欣扬瑞和化学科技有限公司13720274133 · [email protected]
河南赢创生物科技有限公司16650615803 · [email protected]
Baoji Guokang Healthchem co.,ltd+8615604608665 15604608665 · [email protected]
Dayang Chem (Hangzhou) Co.,Ltd.+86-0571-88938639 17705817739 · [email protected]
郑州鸿晟医药科技有限公司0371-55695890 15637198702 · [email protected]
上海迈瑞尔生化科技有限公司4006356688 18621169109 · [email protected]
上海颖心实验室设备有限公司021-59178156 17002132182 · [email protected]
武汉市聚舜化工有限公司027-02783261126 18971318572 · [email protected]
上海德默医药科技有限公司400-021-7337 2355568890 · [email protected]
安耐吉化学&3A(安徽泽升科技股份有限公司)400-0056266 · [email protected]
梯希爱(上海)化工贸易有限公司021-61109150 · [email protected]
广东云星生物技术有限公司0751-18902340975/189023400307 18902340307 · [email protected]
山东洛克化工有限公司17653113209 13065062079 · [email protected]
山东西亚化学有限公司13355009207 13355009207 · [email protected]
四川库利南科技有限公司400-1166-196 18981987031 · [email protected]
天津希恩思生化科技有限公司400 638 7771 · [email protected]
南京化学试剂股份有限公司025-58369808 17895012682 · [email protected]
斯百全化学(上海)有限公司021-021-021-67601398-809-809-809 15221380277 · [email protected]
赛默飞世尔科技(中国)有限公司800-810-5118 · [email protected]
北京伊诺凯科技有限公司400-810-7969 010-59572699 · [email protected]
南京杜莱生物技术有限公司025-84699383-8003;025-846993838003-8003 18013301590 · [email protected]
上海将来实业股份有限公司400-0066400 13621662912 · [email protected]
上海将来实业股份有限公司021-61552785 · [email protected]
安徽科迪达化工有限公司0554-2106669 · [email protected]
成都零六生物科技有限公司400-1166-196 13458535857 · [email protected]
陕西缔都医药化工有限公司+86-029-81138252 +86-173 9270 1263 · [email protected]
天津普西唐生物医药科技有限公司010-60605840 · [email protected]
上海德榜化工有限公司021-61531158 · [email protected]
上海麦克林生化科技股份有限公司15221275939 15221275939 · [email protected]
康迪斯化工(湖北)有限公司13125172151 · [email protected]
成都润泽本土化工有限公司13096311329 028-88469284 616445927 · [email protected]
Sigma-Aldrich西格玛奥德里奇(上海)贸易有限公司021-61415566 800-8193336 · [email protected]
九鼎化学(上海)科技有限公司4009209199 · [email protected]
广东翁江化学试剂有限公司0751-2815987 13927875076 · [email protected]
昆山中莱特贸易有限公司0512-55170668 13913095008;13770601296 · [email protected]
山东智尚新材料有限公司+8617653113209 · [email protected]
上海珈得尔化学技术有限公司13564435016 13564435016 · [email protected]
浙江珲达生物科技有限公司0571-89903022 18679456698 · [email protected]
湖北万业众诚化学试剂有限责任公司18671296875 · [email protected]
启源(广东)医药化工有限公司18026564465 · [email protected]
上海炎泽化工有限公司15345144255 19901447308 · [email protected]
艾万拓威达优尔国际贸易(上海)有限公司400-821-8006 · [email protected]
上海源叶生物科技有限公司18916372613 · [email protected]
武汉市承天精细化工有限公司18164098996 · [email protected]

Additional notes

DefinitionChEBI: A hydrate that is the nonahydrate form of sodium silicate.