HomeMCPWorkbenchSkills
HomeWorkbenchNotificationsMe
Huagongshe Open Program:[email protected]AI access: llms.txt · MCP GuidePrivacy Policy · Terms of Service · Supportv1.7.8
  1. Home
  2. /Compound

Lead perchlorate

HCID 61655
NotesReactions
Basic informationOverviewNames & identifiersPropertiesSafety & regulationChemistry & industryRelated reactionsCompound notes
Substructure searchFind similar structures

Basic information

CAS
13637-76-8
Standard SMILES
[O-][Cl+3]([O-])([O-])[O-].[O-][Cl+3]([O-])([O-])[O-].[Pb+2]
InChIKey
XOYUVEPYBYHIFZ-UHFFFAOYSA-L
Molecular formula
Cl2O8Pb
Average molar mass
406 g/mol
Monoisotopic mass
405.87367

Overview

Lead perchlorate appears as a white crystalline solid. A dangerous fire risk when in contact with reducing materials. Very toxic by ingestion. Used to make paints and in electric storage batteries.

Names & identifiers

Preferred name
Lead perchlorate
IUPAC
lead(2+) diperchlorate
English name
LEAD(II) PERCHLORATE SOLUTION
Molecular formula
Cl2O8Pb
Molecular weight
406.1012

Names & synonyms

Lead perchlorateLead diperchloratePerchloric acid, lead(2+) saltEINECS 237-125-7UN1470Perchloric acid, lead(2+) salt (2:1)Lead perchlorate, solidDTXSID10890712Lead(II) perchlorateLead perchloric acidRefChem:152649(perchloryloxy)plumbyl perchlorate
Show more names
leaddiperchlorateBlei(II)-perchloratlead(2+)perchloratePerchloric acid,leadsaltPerchloric acid, lead saltLEAD PERCHLORATE, HYDRATEDPerchloricacid,lead(2+)saltperchloricacid,lead(2++)saltLEAD(II) PERCHLORATE SOLUTIONLead(Ⅱ) perchlorate trihydrate
DTXCID401031062LEAD PERCHLORATE (PB(CLO4)2)PERCHLORIC ACID, LEAD (2+) SALT237-125-713637-76-8Lead (II) Perchloratelead(2+);diperchlorateLead(2+) perchlorate

Database identifiers

CAS
13637-76-8

Properties

Computed structural properties

Topological polar surface area
149 Ų
Hydrogen bond donors
0
Hydrogen bond acceptors
8
Rotatable bonds
0
Heavy atoms
11
Formal charge
0
Complexity
95.8

Experimental & physicochemical properties

Chemical Classes · 2 items

Metals -> Lead Compounds, Inorganic

Carcinogens

Physical Description · 2 items

Lead perchlorate appears as a white crystalline solid. A dangerous fire risk when in contact with reducing materials. Very toxic by ingestion. Used to make paints and in electric storage batteries.

White solid; [CAMEO]

Physicochemical properties

Melting point
100 ℃ · decomposes at 100℃ [HAW93]
Density
2.6 · 2.600
solubility
soluble in ethanol
form
white crystals
color
white crystals, crystalline
Water Solubility
81.5 g/100g · 81.5g/100g solution in H2O (25°C), solid phase is Pb(ClO4)2 · 3H2O [KRU93]
REACH Annex XVII Substances List
Lead diperchlorate (13637-76-8)
EPA Substance Registry System
Perchloric acid, lead(2+) salt (13637-76-8)

Safety & regulation

Safety information is for reference only and does not replace the supplier’s Safety Data Sheet (SDS), applicable regulations, or professional assessment.

GHS classification

GHS Classification · 4 items

Danger

H272 (50%): May intensify fire; oxidizer [Danger Oxidizing liquids; Oxidizing solids]

P203, P210, P220, P260, P261, P264, P270, P271, P273, P280, P301+P317, P304+P340, P317, P318, P319, P330, P370+P378, P391, P405, and P501 (click each P-code to see the statement)

Aggregated GHS information provided per 2 reports by companies from 2 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.

Hazard information

Regulatory Information · 3 items

Restricted substance: Lead diperchlorate

Perchloric acid, lead(2+) salt: HSNO Approval: HSR001362 Approved with controls

The New Jersey Worker and Community Right to Know Act requires public and private employers to provide information about hazardous substances at their workplaces. (N.J.S.A. 34:5A-1 et. seq.)

DOT LabelOxidizer Poison
Fire Hazards · 3 items

Excerpt from ERG Guide 141 [Oxidizers - Toxic]:

· These substances will accelerate burning when involved in a fire.

· These substances will accelerate burning when involved in a fire.

Health Hazards · 3 items

Excerpt from ERG Guide 141 [Oxidizers - Toxic]:

· Toxic by ingestion.

· Toxic by ingestion.

Hazards SummaryToxic by ingestion and inhalation; Can cause severe burns to eyes and skin; [CAMEO] See Lead and linked occupational diseases. See PERCHLORATES.
DOT ID and Guide · 2 items

1470 141

3408 141

Chemistry & industry

Pharmacology

Metabolism/Metabolites · 1 item

Lead is absorbed following inhalation, oral, and dermal exposure. It is then distributed mainly to the bones and red blood cells. In the blood lead may be found bound to serum albumin or the metal-binding protein metallothionein. Organic lead is metabolized by cytochrome P-450 enzymes, whereas inorganic lead forms complexes with delta-aminolevulinic acid dehydratase. Lead is excreted mainly in the urine and faeces. (L136)

Uses & manufacturing

Uses · 2 items

Used to make paints and storage batteries; [CAMEO]

Battery Manufacturing [Category: Industry]

General Manufacturing InformationPerchloric acid, lead(2+) salt (2:1): ACTIVE

Applications

General DescriptionA white crystalline solid. A dangerous fire risk when in contact with reducing materials. Very toxic by ingestion. Used to make paints and in electric storage batteries.

Suppliers3 total

陕西缔都新材料有限公司029-63373950 17392216152 · [email protected]
斯百全化学(上海)有限公司021-021-021-67601398-809-809-809 15221380277 · [email protected]
DAYANG CHEM (HANGZHOU) CO.,LTD+86-88938639 +86-17705817739 · [email protected]

Related reactions

0 records
New reaction record

No reaction records under the current filter.

Compound notes

Loading…

On this pageBasic informationOverviewNames & identifiersPropertiesSafety & regulationChemistry & industryRelated reactionsCompound notes
PubChem CID
61655
DTXSID
DTXSID10890712
EC Number
237-125-7
Nikkaji
J43.846D
Symbol(GHS)
7 · GHS07,GHS08,GHS09
Signal word
Danger
Hazard statements
302 · H302-H360-H373-H410
Precautionary statements
264 · P264-P270-P201-P202-P280-P260-P273-P301+P312-P330-P308+P313-P314-P391-P405-P501
Hazard Codes
O,T,N
Risk Statements
61 · 61-8-20/22-33-50/53-62
Safety Statements
53 · 53-45-60-61
RIDADR
3408 · UN 3408
TSCA
TSCA listed
HazardClass
5.1 · 5.1
PackingGroup
II/III
Reactive GroupOxidizing Agents, Strong
Reactivity AlertsExplosive
Reactivity Profile · 1 item

LEAD PERCHLORATE is a strong oxidizing agent. Can react with reducing agents to generate heat and products that may be gaseous (causing pressurization in closed containers). The products may themselves be capable of further reactions (such as combustion in the air). Redox reactions can be rapid or even explosive, but often requires initiation (heat, spark, catalyst, addition of a solvent). Consequently explosive mixtures with reducing agents often persist unchanged for long periods. Such systems are typically mixtures of solids, but may involve any combination of physical states. Can react violently with active metals, cyanides, esters, and thiocyanates. May cause the acceleration of the burning of combustible materials. Prolonged exposure to heat of flames may result in an explosion. A flask of anhydrous lead perchlorate dissolved in methyl alcohol exploded when it was disturbed [J. Am. Chem. Soc. 52:2391. 1930].

DOT Hazard Classification · 6 items

Lead perchlorate, solid or solution

Marine pollutant

Lead perchlorate, solid

UN1470

Div 5.1 Oxidizer (49 eCFR § 173.127)

Div 5.1 Oxidizer (49 eCFR § 173.127)

Air and Water ReactionsWater soluble.
Hazard Classes and Categories · 2 items

Ox. Sol. 2 (50%)

Carcinogens

Safety & protection

Fire FightingExcerpt from ERG Guide 141 [Oxidizers - Toxic]:
Accidental Release Measures · 4 items

· CALL 911. Then call emergency response telephone number on shipping paper. If shipping paper not available or no answer, refer to appropriate telephone number listed on the inside back cover.

· Keep combustibles (wood, paper, oil, etc.) away from spilled material.

· CALL 911. Then call emergency response telephone number on shipping paper. If shipping paper not available or no answer, refer to appropriate telephone number listed on the inside back cover.

· Keep combustibles (wood, paper, oil, etc.) away from spilled material.

First Aid · 3 items

Excerpt from ERG Guide 141 [Oxidizers - Toxic]:

General First Aid:

General First Aid:

Exposure Control and Personal Protection · 3 items

· Wear positive pressure self-contained breathing apparatus (SCBA).

· Wear positive pressure self-contained breathing apparatus (SCBA).

Biological Exposure Indices (BEI) [ACGIH] - Lead in blood = 200 ug/L (20 ug/100 ml); sampling time not critical; [ACGIH]

Nonfire Spill ResponseExcerpt from ERG Guide 141 [Oxidizers - Toxic]:
Isolation and Evacuation · 3 items

Excerpt from ERG Guide 141 [Oxidizers - Toxic]:

Immediate precautionary measure

Immediate precautionary measure

Minimum Risk LevelChronic Inhalation: 0.05 mg/m3 (L134)
Threshold Limit Values (TLV)0.05 [mg/m3], as Pb
Permissible Exposure Limit (PEL)0.05 [mg/m3], as Pb
Personal Protective Equipment (PPE)Excerpt from ERG Guide 141 [Oxidizers - Toxic]:
Emergency Response Planning Guidelines · 2 items

Small Fire

Small Fire

Toxicology

TreatmentLead poisoning is usually treated with chelation therapy using DMSA, EDTA, or dimercaprol. (L21)
Health Effects · 1 item

Lead is a neurotoxin and has been known to cause brain damage and reduced cognitive capacity, especially in children. Lead exposure can result in nephropathy, as well as blood disorders such as high blood pressure and anemia. Lead also exhibits reproductive toxicity and can results in miscarriages and reduced sperm production. (L21)

Adverse EffectsNeurotoxin - Predominantly motor
Exposure RoutesOral (L136) ; inhalation (L136) ; dermal (L136)
Toxicity Summary · 1 item

Lead mimics other biologically important metals, such as zinc, calcium, and iron, competing as cofactors for many of their respective enzymatic reactions. For example, lead has been shown to competitively inhibit calcium's binding of calmodulin, interferring with neurotransmitter release. It exhibits similar competitive inhibition at the NMDA receptor and protein kinase C, which impairs brain microvascular formation and function, as well as alters the blood-brain barrier. Lead also affects the nervous system by impairing regulation of dopamine synthesis and blocking evoked release of acetylcholine. However, it's main mechanism of action occurs by inhibiting delta-aminolevulinic acid dehydratase, an enzyme vital in the biosynthesis of heme, which is a necesssary cofactor of hemoglobin. (T4, A20, A22, L136)

Signs and Symptoms · 1 item

Symptions of chronic lead poisoning include reduced cognitive abilities, nausea, abdominal pain, irritability, insomnia, metal taste in the mouth, excess lethargy or hyperactivity, chest pain, headache and, in extreme cases, seizures, comas, and death. There are also associated gastrointestinal problems, such as constipation, diarrhea, vomiting, poor appetite, weight loss, which are common in acute poisoning. (A2, L21)

Carcinogen Classification2A, probably carcinogenic to humans. (L135)

Safety data

tsca
TSCA listed
ridadr
UN 3408
risk_code
61-8-20/22-33-50/53-62
Signal word
Danger
Symbol(GHS)
GHS07,GHS08,GHS09
hazard_code
O,T,N
safety_code
53-45-60-61
hazard_class
5.1
packing_group
II/III
Hazard statements
H302-H360-H373-H410
Precautionary statements
P264-P270-P201-P202-P280-P260-P273-P301+P312-P330-P308+P313-P314-P391-P405-P501