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COBALT MOLYBDENUM OXIDE (CoMoO4)

HCID 61675
NotesReactions
Basic informationOverviewNames & identifiersPropertiesSafety & regulationChemistry & industryRelated reactionsCompound notes
Substructure searchFind similar structures

Basic information

CAS
13762-14-6
Standard SMILES
[Co+2].[O]=[Mo](=[O])([O-])[O-]
InChIKey
KYYSIVCCYWZZLR-UHFFFAOYSA-N
Molecular formula
CoMoO4
Average molar mass
218.88 g/mol
Monoisotopic mass
220.818256

Overview

Cobalt(II) molybdenum(VI) oxide is an oxide of cobalt and molybdenum. Cobalt is a metallic element with the atomic number 27. It is found naturally in rocks, soil, water, plants, and animals. In small amounts cobalt is an essential element for life, as it is part of vitamin B12. However, excess exposure is known to exhibit toxic effects. (L29, L30)

Names & identifiers

Preferred name
COBALT MOLYBDENUM OXIDE (CoMoO4)
IUPAC
cobalt(2+);dioxido(dioxo)molybdenum
English name
COBALT MOLYBDATE
Molecular formula
CoMoO4
Molecular weight
218.87

Names & synonyms

Cobalt molybdateCobalt(II) molybdateCobalt molybdenum oxide (CoMoO4)EINECS 237-358-4HT-400 E 1/8''EC 237-358-4RefChem:577886HT400 E 1/8237-358-413762-14-6Cobalt monomolybdateMolybdenum cobaltate
Show more names
COBALT (II) MOLYBDATECopalt molybdenum oxideCOBALT(II) MOLYBDENUM OXIDECOBALT9II)MOLBDENUM(IV)OXIDECobalt(Ⅱ)Molybdate AnhydrousCOBALT(II)MOLYBDENUM(VI)OXIDEMolybdic acid cobalt(II) saltCobalt(II) molybdate, anhydrous
cobalt(2+);dioxido(dioxo)molybdenumCobaltous molybdateCobalt molybdate(VI)Molybdenum cobalt oxideCobalt(2+) molybdateNKh 1 (metal oxide)NKh 1CoMoO4

Database identifiers

CAS
13762-14-6
PubChem CID
61675
EC Number
237-358-4

Properties

Computed structural properties

Topological polar surface area
80.3 Ų
Hydrogen bond donors
0
Hydrogen bond acceptors
4
Rotatable bonds
0
Heavy atoms
6
Formal charge
0
Complexity
62.2

Experimental & physicochemical properties

Chemical ClassesMetals -> Metals, Inorganic Compounds
Physical Description · 2 items

Liquid; Large Crystals

Gray-green solid; [Hawley] Green powder, insoluble in water; [MSDSonline]

Physicochemical properties

Melting point
1040 °C · 1040°C
Density
4.7 · 4.700
form
Powder
color
green
Water Solubility
508 mg/L · 508mg/L at 20℃
Exposure limits
0.5 mg/m3; · ACGIH: TWA 0.5 mg/m3; TWA 10 mg/m3; TWA 3 mg/m3; TWA 0.02 mg/m3NIOSH: IDLH 1000 mg/m3; IDLH 5000 mg/m3
CAS DataBase Reference
13762 · 13762-14-6
EPA Substance Registry System
Cobalt molybdenum oxide (CoMoO4) (13762-14-6)
Symbol(GHS)
5 · GHS05
Signal word
Danger

Safety & regulation

Safety information is for reference only and does not replace the supplier’s Safety Data Sheet (SDS), applicable regulations, or professional assessment.

GHS classification

GHS Classification · 6 items

This chemical does not meet GHS hazard criteria for 0.9% (1 of 114) of reports.

Danger

H317 (99.1%): May cause an allergic skin reaction [Warning Sensitization, Skin]

P203, P233, P260, P261, P271, P272, P273, P280, P284, P302+P352, P304+P340, P318, P321, P333+P317, P342+P316, P362+P364, P391, P403, P405, and P501 (click each P-code to see the statement)

Aggregated GHS information provided per 114 reports by companies from 5 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.

Danger

Hazard information

Regulatory Information · 3 items

Chemical: Cobalt molybdenum oxide (CoMoO4)

Cobalt molybdenum oxide (CoMoO4) is listed on the EPA's Chemical Data Reporting (CDR) system. Manufacturers and importers of Cobalt molybdenum oxide (CoMoO4) are required to report information about their production and use of this chemical to the EPA under the Toxic Substances Control Act (TSCA). (40 eCFR Part 711)

REACH registered substance: Cobalt molybdate (EC: 237-358-4)

Other Safety InformationIMAP assessments - Sparingly soluble cobalt salts: Human health tier II assessment
Hazards SummaryHarmful if swallowed; May cause skin sensitization; [MSDSonline] See Cobalt.
Hazard Classes and Categories · 2 items

Skin Sens. 1 (99.1%)

Acute toxicity - category 2

Safety & protection

Exposure Control and Personal Protection

Chemistry & industry

Pharmacology

Metabolism/Metabolites · 1 item

Cobalt is absorbed though the lungs, gastrointestinal tract, and skin. Since it is a component of the vitamin B12 (cyanocobalamin), it is distributed to most tissues of the body. It is transported in the blood, often bound to albumin, with the highest levels being found in the liver and kidney. Cobalt is excreted mainly in the urine and faeces. (L29)

Uses & manufacturing

UsesUsed as a catalyst in the production of petrochemicals; [Hawley]
U.S. Production2023: 500,000 - <1,000,000 lb
Consumer UsesOther
Industry UsesOther
General Manufacturing Information · 2 items

All Other Basic Inorganic Chemical Manufacturing

Cobalt molybdenum oxide (CoMoO4): ACTIVE

Suppliers20 total

湖北蝶化新材料科技有限公司86-18372897-544 18995560451 · [email protected]
北京华美互利生物化工010-56205725 · [email protected]
陕西缔都新材料有限公司029-63373950 17392216152 · [email protected]
江苏艾康生物医药研发有限公司025-66061636 19370895928 · [email protected]
上海迈瑞尔生化科技有限公司4006356688 18621169109 · [email protected]

Related reactions

1 records
New reaction record
HRID 1277530 reaction equation
HRID 1277530As catalystuspto-grants-1981_07

Compound notes

Loading…

On this pageBasic informationOverviewNames & identifiersPropertiesSafety & regulationChemistry & industryRelated reactionsCompound notes
Hazard statements
314 · H314-H290
Precautionary statements
501 · P501-P234-P264-P280-P390-P303+P361+P353-P301+P330+P331-P363-P304+P340+P310-P305+P351+P338+P310-P406-P405
Risk Statements
20 · 20/21/22
Safety Statements
22 · 22-36/37/39
TSCA
TSCA listed
REACH Registrations
Active
Biological Exposure Indices (BEI) [ACGIH] - Cobalt in urine = 15 ug/L; sample at end of shift at end of workweek;
Minimum Risk LevelChronic Inhalation: 0.0001 mg/m3 (L134) Intermediate Oral: 0.01 mg/kg/day (L134)
Threshold Limit Values (TLV)0.02 [mg/m3], as Co

Toxicology

TreatmentTreatment of cobalt poisoning is symptomatic. (L29)
Health EffectsExposure to high amount of cobalt can cause heart, lung, kidney, and liver damage. Skin contact is known to result in contact dermatitis. Cobalt may also have mutagenic and carcinogenic effects. (L29, L30)
Adverse EffectsSkin Sensitizer - An agent that can induce an allergic reaction in the skin.
Exposure RoutesInhalation (L29) ; oral (L29) ; dermal (L29)
Toxicity Summary · 1 item

Cobalt is believed to exhibit its toxicity through a oxidant-based and free radical-based processes. It produces oxygen radicals and may be oxidized to ionic cobalt, causing increased lipid peroxidation, DNA damage, and inducing certain enzymes that lead to cell apoptosis. Cobalt has also been shown to block inorganic calcium channels, possibly impairing neurotransmission. Cobalt can also chelate lipoic acids, impairing oxidation of pyruvate or fatty acids. In addition, cobalt may inhibit DNA repair by interacting with zinc finger DNA repair proteins, and has also been shown to inhibit heme synthesis and glucose metabolism. Cobalt may activate specific helper T-lymphocyte cells and interact directly with immunologic proteins, such as antibodies (IgA and IgE) or Fc receptors, resulting in immunosensitization. (L29)

Signs and SymptomsCobalt inhalation can cause asthma-like breathing problems. Skin contact is known to result in contact dermatitis, which is characterized by irritation and rashes. Ingesting large amounts of cobalt may cause nausea and vomiting. (L2090)
Carcinogen Classification2B, possibly carcinogenic to humans. (L135)

Safety data

tsca
TSCA listed
risk_code
20/21/22
Signal word
Danger
Symbol(GHS)
GHS05
safety_code
22-36/37/39
Hazard statements
H314-H290
REACH Registrations
Active
Precautionary statements
P501-P234-P264-P280-P390-P303+P361+P353-P301+P330+P331-P363-P304+P340+P310-P305+P351+P338+P310-P406-P405
阿法埃莎(中国)化学有限公司400-6106006 · [email protected]
安耐吉化学&3A(安徽泽升科技股份有限公司)400-0056266 · [email protected]
青岛海智微元生物科技有限公司18317699790 18317699790 · [email protected]
长沙晶康新材料科技有限公司0731-85118349 18874718518 · [email protected]
上海阿拉丁生化科技股份有限公司6206333 13167063860 · [email protected]
上海源叶生物科技有限公司18916372613 · [email protected]
安泰精细化工技术有限公司18503026267 · [email protected]
Shaanxi Didu New Materials Co. Ltd+86-86-17392712779 +86-13289823923 · [email protected]
海蔚化学86-21-51086038 · [email protected]
Aladdin Scientific[email protected]
重庆博涛生物科技有限公司15223382610 · [email protected]
XIAMEN AMITY INDUSTRY AND TRADE CO., LTD.+8618950047208 · [email protected]
北京百灵威科技有限公司18210857532 18210857532 · [email protected]
DAYANG CHEM (HANGZHOU) CO.,LTD+86-88938639 +86-17705817739 · [email protected]
宝鸡福诺康实业有限公司0917-3236817 13220096790 · [email protected]

Additional notes

DefinitionA molybdenum catalyst (a gray–green powder) used in petroleum technology, in reforming and desulfurization.