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Lithium dichromate

HCID 61692
NotesReactions
Basic informationOverviewNames & identifiersPropertiesSafety & regulationRelated reactionsCompound notes
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Basic information

CAS
13843-81-7
Standard SMILES
[Li+].[Li+].[O]=[Cr](=[O])([O-])[O][Cr](=[O])(=[O])[O-]
InChIKey
GLGSRACCZFMWDT-UHFFFAOYSA-N
Molecular formula
Cr2Li2O7
Average molar mass
229.9 g/mol
Monoisotopic mass
229.877419

Overview

Lithium dichromate is an orange red to black brown crystalline powder. Denser than water. (USCG, 1999)

Names & identifiers

Preferred name
Lithium dichromate
IUPAC
dilithium;oxido-(oxido(dioxo)chromio)oxy-dioxochromium

Names & synonyms

Lithium dichromate13843-81-7Lithium dichromate(VI)Chromic acid (H2Cr2O7), dilithium saltdilithium;oxido-(oxido(dioxo)chromio)oxy-dioxochromium9C9VO53SW9UNII-9C9VO53SW9EINECS 237-567-0DILITHIUM DICHROMATESCHEMBL226639CHROMIC ACID DILITHIUM SALTLITHIUM DICHROMATE(V) [MI]
Show more names
LITHIUM DICHROMATE(VI) (LI2CR2O7)Q4162567LITHIUM DICHROMATE, LI(2)CR(2)O(7)2H(2)O

Database identifiers

CAS
13843-81-7
PubChem CID
61692
UNII
9C9VO53SW9
EC Number
237-567-0

Properties

Computed structural properties

Topological polar surface area
124 Ų
Hydrogen bond donors
0
Hydrogen bond acceptors
7
Rotatable bonds
0
Heavy atoms
11
Formal charge
0
Complexity
194

Experimental & physicochemical properties

Density2.34 at 86 °F (USCG, 1999) - Denser than water; will sink
Boiling PointDecomposes 368.6 °F (USCG, 1999)
Melting Point266 °F (USCG, 1999)
Physical DescriptionLithium dichromate is an orange red to black brown crystalline powder. Denser than water. (USCG, 1999)

Safety & regulation

Safety information is for reference only and does not replace the supplier’s Safety Data Sheet (SDS), applicable regulations, or professional assessment.

GHS classification

GHS Classification · 4 items

Danger

H272 (100%): May intensify fire; oxidizer [Danger Oxidizing liquids; Oxidizing solids]

P203, P210, P220, P233, P260, P261, P264, P264+P265, P271, P272, P280, P284, P302+P352, P304+P340, P305+P351+P338, P318, P319, P321, P332+P317, P333+P317, P337+P317, P342+P316, P362+P364, P370+P378, P403, P403+P233, P405, and P501 (click each P-code to see the statement)

The GHS information provided by 1 company from 1 notification to the ECHA C&L Inventory.

Hazard information

DOT LabelPoison
Fire HazardsBehavior in Fire: May decompose giving off oxygen with supports further combustion. (USCG, 1999)
Health Hazards · 1 item

INHALATION: Corrosive to mucous membranes. SKIN: Causes dermatitis and slow-healing ulcers. EYES: Conjunctivitis and lacrimation. INGESTION: Violent gastroenteritis, peripheral vascular collapse, vertigo, muscle cramps, coma, hemorrhagic diathesis, fever, liver damage and renal failure. (USCG, 1999)

Reactive GroupSalts, Basic
Reactivity AlertsStrong Oxidizing Agent
Reactivity ProfileLITHIUM DICHROMATE is an oxidizer. Can react with combustibles. May decompose when heated giving off oxygen that further supports combustion (USCG, 1999).
Air and Water ReactionsHygroscopic. Water soluble.
Hazard Classes and CategoriesOx. Sol. 2 (100%)

Related reactions

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Compound notes

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On this pageBasic informationOverviewNames & identifiersPropertiesSafety & regulationRelated reactionsCompound notes

Safety & protection

Fire FightingFire Extinguishing Agents: Flood spill area with water. (USCG, 1999)
First AidCall a doctor.
Nonfire Spill ResponseExcerpt from ERG Guide 151 [Substances - Toxic (Non-Combustible)]:
Isolation and EvacuationExcerpt from ERG Guide 151 [Substances - Toxic (Non-Combustible)]:
Personal Protective Equipment (PPE)Approved dust mask, goggles or face shield, rubber gloves. (USCG, 1999)