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Cuprate(2-), tris(cyano-kappaC)-, sodium (1:2)

HCID 61722
NotesReactions
Basic informationOverviewNames & identifiersPropertiesSafety & regulationChemistry & industryRelated reactionsCompound notes
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Basic information

CAS
14264-31-4
Standard SMILES
[C-]#N.[C-]#N.[C-]#N.[Cu+].[Na+].[Na+]
InChIKey
JXWXJWOMXJKLOG-UHFFFAOYSA-N
Molecular formula
C3CuN3.2Na
Average molar mass
187.58 g/mol
Monoisotopic mass
186.918358

Overview

Sodium cuprocyanide, solid appears as a white powder. Decomposes at 212 °F. Toxic by inhalation, ingestion and skin absorption through open wounds. Reacts with acids to evolve hydrogen cyanide, which is a highly toxic and flammable. Used for preparing and maintaining copper plating baths.

Names & identifiers

Preferred name
Cuprate(2-), tris(cyano-kappaC)-, sodium (1:2)
IUPAC
disodium;copper(1+);tricyanide
English name
Sodium copper cyanide
Molecular formula
C3CuN3Na
Molecular weight
164.58797

Names & synonyms

Copper sodium cyanideDisodium tri(cyano-C)cuprate(2-)EINECS 238-155-3Sodium cuprocyanide, solidCuprate(2-), tris(cyano-C)-, disodiumCuprate(2-), tris(cyano-kappaC)-, disodiumCuprate(2-), tris(cyano-kappaC)-, sodium (1:2)SODIUM CUPROCYANIDE, (SOLID)SODIUM CUPROCYANIDE, [SOLID]RefChem:579675Cuprate(2-), tris(cyano-.kappa.C)-, sodium (1:2)238-155-3
Show more names
Sodium cuprocyanideSodium copper cyanideSodium cyanocuprate(I)disodium,copper(1+),tricyanide
disodium;copper(1+);tricyanide14264-31-4Sodium cuprocyanide solidSodium tricyanocuprate(I)Sodium copper cyanide, solidUN2316UN2317Sodium cyanocuprate(I) (Na2Cu(CN)3)

Database identifiers

CAS
14264-31-4
PubChem CID
61722
EC Number
238-155-3

Properties

Computed structural properties

Topological polar surface area
71.4 Ų
Hydrogen bond donors
0
Hydrogen bond acceptors
6
Rotatable bonds
0
Heavy atoms
9
Formal charge
0
Complexity
53.2

Experimental & physicochemical properties

Physical Description · 1 item

Sodium cuprocyanide, solid appears as a white powder. Decomposes at 212 °F. Toxic by inhalation, ingestion and skin absorption through open wounds. Reacts with acids to evolve hydrogen cyanide, which is a highly toxic and flammable. Used for preparing and maintaining copper plating baths.

Physicochemical properties

Density
1.013 · 1.0130
form
Crystal, powder
color
White
EWG's Food Scores
1 · 1
EPA Substance Registry System
Cuprate(2-), tris(cyano-.kappa.C)-, disodium (14264-31-4)
Symbol(GHS)
5 · GHS05,GHS06,GHS08,GHS09
Signal word
Warning
Hazard statements
300 · H300-H310-H317-H318-H332-H371-H373-H411
Precautionary statements
264 · P264-P270-P262-P280-P261-P272-P271-P260-P273-P301+P310-P330-P302+P352-P310-P361+P364-P333+P313-P362+P364-P305+P351+P338-P304+P340-P312-P308+P311-P314-P391-P405-P501

Safety & regulation

Safety information is for reference only and does not replace the supplier’s Safety Data Sheet (SDS), applicable regulations, or professional assessment.

GHS classification

GHS Classification · 6 items

Warning

H300 (100%): Fatal if swallowed [Danger Acute toxicity, oral]

P260, P261, P262, P264, P264+P265, P270, P271, P272, P273, P280, P301+P316, P302+P352, P304+P340, P305+P354+P338, P308+P316, P316, P317, P319, P321, P330, P333+P317, P361+P364, P362+P364, P391, P405, and P501 (click each P-code to see the statement)

The GHS information provided by 1 company from 1 notification to the ECHA C&L Inventory.

Danger

H316: Causes mild skin irritation [Warning Skin corrosion/irritation]

Hazard information

DOT LabelPoison
Fire HazardsExcerpt from ERG Guide 157 [Substances - Toxic and/or Corrosive (Non-Combustible / Water-Sensitive)]:
Health HazardsExcerpt from ERG Guide 157 [Substances - Toxic and/or Corrosive (Non-Combustible / Water-Sensitive)]:
Reactive GroupCyanides, Inorganic
Reactivity ProfileSODIUM CUPROCYANIDE reacts with acids to evolve hydrogen cyanide, which is a highly toxic and flammable gas.
DOT Hazard Classification · 6 items

Sodium cuprocyanide, solid

Severe marine pollutant

Sodium cuprocyanide, solid

UN2316

Div 6.1 Poisonous materials (49 eCFR § 173.132)

PG I: the degree of danger presented by the material is great

Air and Water ReactionsSoluble in water.
Hazard Classes and Categories

Chemistry & industry

Uses & manufacturing

General Manufacturing InformationCuprate(2-), tris(cyano-.kappa.C)-, sodium (1:2): ACTIVE

Applications

UsesFor preparing and maintaining cyanide copper plating baths based on sodium cyanide.

General DescriptionA colorless to light yellow liquid. Denser than water. Contact may irritate skin, eyes and mucous membranes. May be toxic by ingestion, inhalation and skin absorption.

Suppliers4 total

厦门盈融达化工有限公司+86-0592-6210733 · [email protected]
陕西缔都医药化工有限公司029-029-029-81148696 18161915376 · [email protected]
DAYANG CHEM (HANGZHOU) CO.,LTD+86-88938639 +86-17705817739 · [email protected]
Dideu Industries Group Limited+86-29-81148696 +86-15129568250 · [email protected]

Related reactions

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Compound notes

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On this pageBasic informationOverviewNames & identifiersPropertiesSafety & regulationChemistry & industryRelated reactionsCompound notes
RIDADR
2316 · UN 2316 6.1/PG I (SODIUM CUPROCYANIDE, SOLID)
TSCA
TSCA listed
HazardClass
6.1 · 6.1
PackingGroup
I
· 2 items

Acute Tox. 2 (100%)

Skin corrosion/irritation - Category 3

Safety & protection

Fire FightingExcerpt from ERG Guide 157 [Substances - Toxic and/or Corrosive (Non-Combustible / Water-Sensitive)]:
First AidExcerpt from ERG Guide 157 [Substances - Toxic and/or Corrosive (Non-Combustible / Water-Sensitive)]:
Nonfire Spill ResponseExcerpt from ERG Guide 157 [Substances - Toxic and/or Corrosive (Non-Combustible / Water-Sensitive)]:
Isolation and EvacuationExcerpt from ERG Guide 157 [Substances - Toxic and/or Corrosive (Non-Combustible / Water-Sensitive)]:
Personal Protective Equipment (PPE)Excerpt from ERG Guide 157 [Substances - Toxic and/or Corrosive (Non-Combustible / Water-Sensitive)]:

Safety data

tsca
TSCA listed
ridadr
UN 2317 6.1/PG I (SODIUM CUPROCYANIDE SOLUTION)
Signal word
Warning
Symbol(GHS)
GHS05,GHS06,GHS08,GHS09
hazard_class
6.1
packing_group
I
Hazard statements
H300-H310-H317-H318-H332-H371-H373-H411
Precautionary statements
P264-P270-P262-P280-P261-P272-P271-P260-P273-P301+P310-P330-P302+P352-P310-P361+P364-P333+P313-P362+P364-P305+P351+P338-P304+P340-P312-P308+P311-P314-P391-P405-P501