Basic information
- CAS
13782-33-7- Standard SMILES
N.N.[Cl][Pd][Cl]- InChIKey
WIEZTXFTOIBIOC-UHFFFAOYSA-L- Molecular formula
- Cl2H6N2Pd
- Average molar mass
- 211.38 g/mol
- Monoisotopic mass
- 209.89428
Overview
cis-Diamminedichloro-palladium(II) is a chemical compound of palladium. Palladium is a chemical element with the chemical symbol Pd and an atomic number of 46. It is found as a free metal alloyed with gold and other platinum group metals and in the rare minerals cooperite and polarite. (L794)
Names & identifiers
- Preferred name
- Palladium, diamminedichloro-
- IUPAC
- azane;dichloropalladium
- English name
- Diamminedichloropalladium
- Molecular formula
- Cl2H6N2Pd
- Molecular weight
- 211.38
Names & synonyms
RefChem:858352238-269-314323-43-4ChloropalladosamineDiammine palladium (II) chlorideDiamminedichloropalladium (II)DiamminodichloropalladiumPalladium (II) diammine dichloridePalladium diammine dichloridePalladium, diamminedichloro-13782-33-7Diamminedichloropalladium
Show more names
50%PdTRANS-DIAMMITranspalladinTRANSPALLADIUMDiaMMine dichloropalDichlorodiaminopalladiumdichlorodiaminepalladiumPALLADIUM DICHLORODIAMINEPALLADIUM AMMINE CHLORIDE
trans-Diamminedichloropalladium(II)Diammine dichloropalladiumazane;dichloropalladiumtrans-Diammine dichloropalladiumtrans-Dichlorodiammine palladium (II)trans-Dichlorodiammine palladium(II)Palladium, diamminedichloro-, (SP-4-1)- (9CI)Diammine dichloropalladium ( cento)
Database identifiers
- CAS
13782-33-7、14323-43-4、15684-18-1
Properties
Computed structural properties
- Topological polar surface area
- 2 Ų
- Hydrogen bond donors
- 2
- Hydrogen bond acceptors
- 2
- Rotatable bonds
- 0
- Heavy atoms
- 5
- Formal charge
- 0
- Complexity
- 2.8
Experimental & physicochemical properties
Physical DescriptionWet Solid
Physicochemical properties
- Density
- 2.5 g/mL · 2.5 g/mL at 25 °C(lit.)
- storage temp.
- 2 · under inert gas (nitrogen or Argon) at 2-8°C
- form
- Powder
- color
- yellow
- InChI
- InChI=1S/2ClH.2H2N.Pd/h2*1H;2*1H2;/q;;2*-1;+4/p-2
- InChIKey
- LXSVNTRDMUGFLL-UHFFFAOYSA-L
- SMILES
- [Pd+2](N)(N)([Cl-])[Cl-]
- EPA Substance Registry System
- Palladium, diamminedichloro-, (SP-4-1)- (13782-33-7)
- Symbol(GHS)
- 6 · GHS06
- Signal word
- Danger
- Hazard statements
- 335 · H335-H301-H311-H331-H315-H319
- Precautionary statements
- 264 · P264-P280-P305+P351+P338-P337+P313P-P261-P271-P304+P340-P311-P321-P403+P233-P405-P501-P264-P280-P302+P352-P321-P332+P313-P362-P264-P270-P301+P310-P321-P330-P405-P501-P280-P302+P352-P312-P322-P361-P363-P405-P501
Safety & regulation
Safety information is for reference only and does not replace the supplier’s Safety Data Sheet (SDS), applicable regulations, or professional assessment.
GHS classification
GHS Classification
Danger
H302+H332 (34%): Harmful if swallowed or if inhaled [Warning Acute toxicity, oral; acute toxicity, inhalation]
P261, P264, P264+P265, P270, P271, P273, P280, P301+P317, P304+P340, P305+P354+P338, P317, P330, P391, and P501 (click each P-code to see the statement)
Aggregated GHS information provided per 215 reports by companies from 6 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.
Danger
H301 (95.1%): Toxic if swallowed [Danger Acute toxicity, oral]
Hazard information
Regulatory Information
Chemical: Palladium, diamminedichloro-
Palladium, diamminedichloro- is listed on the EPA's Chemical Data Reporting (CDR) system. Manufacturers and importers of Palladium, diamminedichloro- are required to report information about their production and use of this chemical to the EPA under the Toxic Substances Control Act (TSCA). (40 eCFR Part 711)
REACH registered substance: Diamminedichloropalladium (EC: 238-269-3)
Other Safety InformationIMAP assessments - Palladium, diamminedichloro-: Environment tier I assessment
Hazard Classes and Categories
Acute Tox. 3 (95.1%)
Acute Tox. 4 (98.1%)
Toxicology
Treatment
EYES: irrigate opened eyes for several minutes under running water. INGESTION: do not induce vomiting. Rinse mouth with water (never give anything by mouth to an unconscious person). Seek immediate medical advice. SKIN: should be treated immediately by rinsing the affected parts in cold running water for at least 15 minutes, followed by thorough washing with soap and water. If necessary, the person should shower and change contaminated clothing and shoes, and then must seek medical attention. INHALATION: supply fresh air. If required provide artificial respiration.
Chemistry & industry
Pharmacology
Metabolism/Metabolites
Palladium may be absorbed through oral, dermal, and inhalation exposure. Once in the body it distributes to the kidney, liver, spleen, lymph nodes, adrenal gland, lung and bone. Palladium's ability to form complexes allows it the bind to amino acids, proteins, DNA, and other macromolecules. Palladium and its metabolites are excreted in the urine and faeces. (A21)
Palladium may be absorbed through oral, dermal, and inhalation exposure. Once in the body it distributes to the kidney, liver, spleen, lymph nodes, adrenal gland, lung and bone. Palladium's ability to form complexes allows it the bind to amino acids, proteins, DNA, and other macromolecules. Palladium and its metabolites are excreted in the urine and faeces. (A21)
Uses & manufacturing
U.S. Production2023: 75,000 - <500,000 lb
Industry UsesIntermediate
General Manufacturing Information
Other (requires additional information)
Palladium, diamminedichloro-: ACTIVE
Applications
UsesDiamminedichloropalladium (also known as trans-Diamminedichloropalladium(II), TDPD) is a chiral analytical reagent that can be used as an internal standard for determining cisplatin-derived platinum in human plasma ultrafiltrate. In addition, trace elements Cu, Ni, and Zn in TDPD and diamminedinitropalladium can be determined by flame atomic absorption spectroscopy.
Suppliers100 total
北京华美互利生物化工010-56205725 · [email protected]
Related reactions
0 records
No reaction records under the current filter.
Compound notes
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