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Borate(1-), tetrafluoro-, nickel(2+) (2:1)

HCID 61765
NotesReactions
Basic informationOverviewNames & identifiersPropertiesSafety & regulationChemistry & industryRelated reactionsCompound notes
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Basic information

CAS
14708-14-6
Standard SMILES
F[B-](F)(F)F.F[B-](F)(F)F.[Ni+2]
InChIKey
UTWSZAKRMXIKQI-UHFFFAOYSA-N
Molecular formula
B2F8Ni
Average molar mass
232.31 g/mol
Monoisotopic mass
231.941177

Overview

Nickel fluoroborate is a green odorless aqueous solution. Sinks in and mixes with water. (USCG, 1999)

Names & identifiers

Preferred name
Borate(1-), tetrafluoro-, nickel(2+) (2:1)
IUPAC
nickel(2+) ditetrafluoroborate
English name
Nickel tetrafluoroborate
Molecular formula
BF4Ni+
Molecular weight
145.5

Names & synonyms

14708-14-6Nickel(II) fluoborateNickel II fluoborateBorate(1-), tetrafluoro-, nickel(2+) (2:1)EINECS 238-753-4Tetrafluoroborate(1-) nickel(2+) (2:1)DTXSID00884766RefChem:120980DTXCID201024190Tetrafluoroborate(1) nickel(2+) (2:1)Borate(1), tetrafluoro, nickel(2+) (2:1)Nickel tetrafluoroborate
Show more names
tl1091NICKEL FLUOBORATEnickelborofluoridenickelfluoroboratenickel(ii)fluoboratenickeloustetrafluoroborateNickeltetrafluoroborate6H2Onickel(2+) tetrafluoroborate
Nickel(II) tetrafluoroboratenickel(2+);ditetrafluoroborateNickel fluoroborateNickel borofluorideNickelous tetrafluoroborateNickel bis(tetrafluoroborate)Nickelous fluoborateTL 1091

Database identifiers

CAS
14708-14-6
PubChem CID

Properties

Computed structural properties

Topological polar surface area
0 Ų
Hydrogen bond donors
0
Hydrogen bond acceptors
10
Rotatable bonds
0
Heavy atoms
11
Formal charge
0
Complexity
19.1

Experimental & physicochemical properties

Chemical ClassesMetals -> Nickel Compounds, Inorganic
Density1.5 at 68 °F (USCG, 1999) - Denser than water; will sink
Physical Description · 2 items

Nickel fluoroborate is a green odorless aqueous solution. Sinks in and mixes with water. (USCG, 1999)

Green liquid; [CAMEO] Apple-green needles; [Ullmann]

Physicochemical properties

Density
1.47 · 1.47
CAS DataBase Reference
14708 · 14708-14-6(CAS DataBase Reference)
REACH Annex XVII Substances List
Nickel bis(tetrafluoroborate) (14708-14-6)
EPA Substance Registry System
Borate(1-), tetrafluoro-, nickel(2+) (2:1) (14708-14-6)
Symbol(GHS)
8 · GHS08,GHS09
Signal word
Danger
Hazard statements
317 · H317-H334-H341-H350i-H360D-H372-H410
Precautionary statements

Safety & regulation

Safety information is for reference only and does not replace the supplier’s Safety Data Sheet (SDS), applicable regulations, or professional assessment.

GHS classification

GHS Classification · 6 items

Danger

H317: May cause an allergic skin reaction [Warning Sensitization, Skin]

P203, P233, P260, P261, P264, P270, P271, P272, P273, P280, P284, P302+P352, P304+P340, P318, P319, P321, P333+P317, P342+P316, P362+P364, P391, P403, P405, and P501 (click each P-code to see the statement)

Danger

H317 (97.7%): May cause an allergic skin reaction [Warning Sensitization, Skin]

P203, P233, P260, P261, P264, P270, P271, P272, P273, P280, P284, P302+P352, P304+P340, P318, P319, P321, P333+P317, P342+P316, P362+P364, P391, P403, P405, and P501 (click each P-code to see the statement)

Hazard information

Regulatory Information · 4 items

Chemical: Borate(1-), tetrafluoro-, nickel(2+) (2:1)

Hazard Traits - Carcinogenicity; Reproductive Toxicity; Respiratory Toxicity

Restricted substance: Nickel bis(tetrafluoroborate)

Borate(1-), tetrafluoro-, nickel(2+) (2:1): Does not have an individual approval but may be used as a component in a product covered by a group standard. It is not approved for use as a chemical in its own right.

Other Safety InformationIMAP assessments - Soluble nickel compounds (Group 1): Human health tier II assessment
DOT LabelClass 9
Fire HazardsExcerpt from ERG Guide 171 [Substances (Low to Moderate Hazard)]:
Health HazardsIngestion causes irritation of mouth and stomach. Liquid irritates eyes and skin and may cause dermatitis. (USCG, 1999)
Hazards SummarySkin and eye irritant; [CAMEO] See Potassium tetrafluoroborate. See Nickel and linked occupational diseases.

Chemistry & industry

Uses & manufacturing

Uses · 2 items

Limited use in specialty nickel plating; [Ullmann]

Electroplating [Category: Plate]

General Manufacturing InformationBorate(1-), tetrafluoro-, nickel(2+) (2:1): ACTIVE

Applications

UsesNICKEL TETRAFLUOROBORATE is used in the manufacture of organic synthesis catalysts, nickel plating flux, nickel soldering flux, etc.

General DescriptionGreen odorless aqueous solution. Sinks in and mixes with water.

Suppliers37 total

北京华美互利生物化工010-56205725 · [email protected]
湖北鑫杰成化工科技有限公司13554075426 · [email protected]
陕西缔都新材料有限公司029-63373950 17392216152 · [email protected]
江苏艾康生物医药研发有限公司025-025-66113011 15955137747 · [email protected]
广东百科试剂有限公司13532366769 13686183698 · [email protected]
武汉易泰科技有限公司上海分公司18930552037 · [email protected]
武汉市聚舜化工有限公司027-02783261126 18971318572 · [email protected]
湖北兴琰新材料科技有限公司13129948835 · [email protected]

Related reactions

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Compound notes

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On this pageBasic informationOverviewNames & identifiersPropertiesSafety & regulationChemistry & industryRelated reactionsCompound notes
61765
DTXSID
DTXSID00884766
EC Number
238-753-4
261 · P261-P272-P280-P302+P352-P333+P313-P321-P363-P501-P261-P285-P304+P341-P342+P311-P501-P201-P202-P281-P308+P313-P405-P501-P260-P264-P270-P314-P501-P273-P391-P501
Hazard Codes
T,C
Risk Statements
45 · 45-34-42/43-31
Safety Statements
53 · 53-45-36/37/39-26-23
RIDADR
1759 · 1759
RTECS
6650000 · QR6650000
Hazard Note
Corrosive
TSCA
TSCA listed
HazardClass
6.1 · 6.1(b)
PackingGroup
III
HS Code
28269080 · 28269080
Reactive GroupNon-Redox-Active Inorganic Compounds
Reactivity Profile · 1 item

Acidic inorganic salts, such as NICKEL FLUOROBORATE, are generally soluble in water. The resulting solutions contain moderate concentrations of hydrogen ions and have pH's of less than 7.0. They react as acids to neutralize bases. These neutralizations generate heat, but less or far less than is generated by neutralization of inorganic acids, inorganic oxoacids, and carboxylic acid. They usually do not react as either oxidizing agents or reducing agents but such behavior is not impossible. Many of these compounds catalyze organic reactions.

Air and Water ReactionsWater soluble.
Hazard Classes and Categories · 3 items

Skin Sens. 1 (97.7%)

Acute toxicity - category 4

Carc. 1A

Safety & protection

Fire FightingExcerpt from ERG Guide 171 [Substances (Low to Moderate Hazard)]:
First AidINGESTION: give large amount of water; induce vomiting; get medical attention.
Exposure Control and Personal Protection1.0 [mg/m3]
Nonfire Spill ResponseExcerpt from ERG Guide 171 [Substances (Low to Moderate Hazard)]:
Isolation and EvacuationExcerpt from ERG Guide 171 [Substances (Low to Moderate Hazard)]:
Threshold Limit Values (TLV)0.1 [mg/m3], inhalable fraction, as Ni
Permissible Exposure Limit (PEL)1.0 [mg/m3], as Ni
Personal Protective Equipment (PPE)Safety glasses and face shield; rubber gloves; rubber apron (USCG, 1999)
Immediately Dangerous to Life or Health (IDLH) · 2 items

10 mg Ni/m3 ; A potential occupational carcinogen. (NIOSH, 2024)

250.0 [mg/m3], as Ni

Toxicology

Adverse EffectsSkin Sensitizer - An agent that can induce an allergic reaction in the skin.
Toxicity DataLCLo (mice) = 530 mg/m3/10min

Safety data

tsca
TSCA listed
rtecs
QR6650000
ridadr
1759
hs_code
28269080
risk_code
45-34-42/43-31
Signal word
Danger
Symbol(GHS)
GHS08,GHS09
hazard_code
T,C
hazard_note
Corrosive
safety_code
53-45-36/37/39-26-23
hazard_class
6.1(b)
packing_group
III
Hazard statements
H317-H334-H341-H350i-H360D-H372-H410
Precautionary statements
P261-P272-P280-P302+P352-P333+P313-P321-P363-P501-P261-P285-P304+P341-P342+P311-P501-P201-P202-P281-P308+P313-P405-P501-P260-P264-P270-P314-P501-P273-P391-P501
广东云星生物技术有限公司
0751-18902340975/189023400307 18902340307 · [email protected]
斯百全化学(上海)有限公司021-021-021-67601398-809-809-809 15221380277 · [email protected]
广东元丰化学试剂有限公司0751-2829979 13376591640 · [email protected]
赛默飞世尔科技(中国)有限公司800-810-5118 · [email protected]
广东顺奥化学试剂有限公司19928586137 · [email protected]
上海馨远医药科技有限公司021-24206007 13764915196 · [email protected]
南京恰风和医药科技有限公司025-57018978 18251899859 · [email protected]
上海孚一生物科技有限公司+86 (21) 61124340
长沙晶康新材料科技有限公司0731-85118349 18874718518 · [email protected]
广东翁江化学试剂有限公司0751-2815987 13927875076 · [email protected]
山东西亚化学有限公司4009903999 13395398332 · [email protected]
山东小野化学股份有限公司0539-6362799 20)
金锦乐(湖南)化学有限公司18001959627(微信同号) 18001959627 · [email protected]
Shaanxi Didu New Materials Co. Ltd+86-86-17392712779 +86-13289823923 · [email protected]
厦门盈融达化工有限公司+86-0592-6210733 · [email protected]
career henan chemical co+86-0371-86658258 · [email protected]
南京克罗托鲁宁医药科技有限公司13382066392
广东翁江化学试剂有限公司0751-2815688 13927872512 · [email protected]
深圳聚合生化科技有限公司+86-400-002-6226 13028896684 · [email protected]
湖北摆渡化学有限公司027-59106051 13627137652 · [email protected]
爆牛贸易重庆有限公司+86-023-6139-8061 +86-86-13650506873 · [email protected]
重庆博涛生物科技有限公司15223382610 · [email protected]
XIAMEN AMITY INDUSTRY AND TRADE CO., LTD.+8618950047208 · [email protected]
苏州启航生物科技有限公司18662190603 · [email protected]
北京百灵威科技有限公司18210857532 18210857532 · [email protected]
HANGZHOU CLAP TECHNOLOGY CO.,LTD86-571-88216897,88216896 13588875226 · [email protected]
DAYANG CHEM (HANGZHOU) CO.,LTD+86-88938639 +86-17705817739 · [email protected]
Hefei TNJ Chemical Industry Co.,Ltd.+86-0551-65418671 +86-189 4982 3763 · [email protected]
宝鸡福诺康实业有限公司0917-3236817 13220096790 · [email protected]