Propyne, mixed with propadiene

HCID 62152

Basic information

CAS
59355-75-8
Standard SMILES
C#CC.C=C=C
InChIKey
VBUBYMVULIMEHR-UHFFFAOYSA-N
Molecular formula
C6H8
Average molar mass
80.13 g/mol
Monoisotopic mass
80.06260026

Names & identifiers

Preferred name
Propyne, mixed with propadiene
IUPAC
propa-1,2-diene;prop-1-yne
English name
Methylacetylene and propadiene mixture,stabilized
Molecular formula
C6H8
Molecular weight
80.12772

Names & synonyms

59355-75-8Propadiene-methyl acetyleneMAPP gasRefChem:176562Methyl acetylene-propadiene mixture (ACGIH:OSHA)METHYL ACETYLENE-PROPADIENE MIXTURE (STABILIZED)MAPPUN1060propa-1,2-diene;prop-1-yneAllene PropynePropadien PropinSCHEMBL447120
Show more names
MAPDPROPYNE-ALLENEMIXTUREMethyl acetylene propadienePROPYL-ALLENEMIXTURE(MAPPGAS)Methyl acetylene propadiene mixture.Propyne and allene mixtures,stabilizedMethylacetylene and propadiene mixture,stabilized
56960-91-9

Database identifiers

CAS
59355-75-8
PubChem CID
62152

Properties

Computed structural properties

Topological polar surface area
0 Ų
Hydrogen bond donors
0
Hydrogen bond acceptors
0
Rotatable bonds
0
Heavy atoms
6

Experimental & physicochemical properties

Density · 2 items

0.576 at 59 °F

1.48(relative gas density)

SolubilityInsoluble
Flash PointNA (Gas)
Boiling Point · 2 items

-36 to -4 °F

-36 to -4 °F

Melting Point · 2 items

-213 °F

-213 °F

Vapor Density1.48

Physicochemical properties

Exposure limits
1000 ppm · TLV-TWA: 1000 ppm (1640 mg/m3), Explosion hazard; TLV-STEL: 1250 ppm (2050 mg/m3), Explosion hazard
EPA Substance Registry System
MAPP (59355-75-8)
OEB
A
OEL
1000 ppm · TWA: 1000 ppm (1800 mg/m3), STEL: 1250 ppm (2250 mg/m3)
IDLA
3 · 3,400 ppm [10% LEL]

Safety & regulation

Hazard information

Regulatory Information · 2 items

Chemical: Methyl acetylene-propadiene mixture

MAPP: Does not have an individual approval but may be used as a component in a product covered by a group standard. It is not approved for use as a chemical in its own right.

Other Safety InformationIMAP assessments - Methyl acetylene-propadiene mixture: Human health tier I assessment;IMAP assessments - Methyl acetylene-propadiene mixture: Environment tier I assessment
Hazards Summary · 1 item

Possible frostbite from contact with liquid; [NIOSH] MAPP gas is an explosive hazard. Reduce hazard by keeping concentrations below 10% of lower explosive limit (3400 ppm). It can cause anesthetic effects and at very high concentrations, asphyxiation. At an exposure level of 5000 ppm 7 hours/day, 5 days/week, experimental animals show decreased body weight. [ACGIH] Classified as Simple asphyxiant; [CAMEO] Methylacetylene-propadiene mixture, stabilized (UN1060) has warning of explosive polymerization; [ERG 2016] See Methylacetylene and Propadiene.

DOT ID and Guide1060 116P(stabilized)
Flammable LimitsFlammable Gas
Lower Explosive Limit (LEL) · 2 items

3.4%

3.4%

Safety & protection

First Aid · 1 item

(General first aid procedures);Eye: Frostbite - If eye tissue is frozen, seek medical attention immediately; if tissue is not frozen, immediately and thoroughly flush the eyes with large amounts of water for at least 15 minutes, occasionally lifting the lower and upper eyelids. If irritation, pain, swelling, lacrimation, or photophobia persist, get medical attention as soon as possible.;Skin: Frostbite - Compressed gases may create low temperatures when they expand rapidly. Leaks and uses that allow rapid expansion may cause a frostbite hazard. Wear appropriate personal protective clothing to prevent the skin from becoming frozen.;Breathing: Respiratory support

Respirator Recommendations · 1 item

NIOSH/OSHA;Up to 3400 ppm:;(APF = 10) Any supplied-air respirator;(APF = 50) Any self-contained breathing apparatus with a full facepiece;Emergency or planned entry into unknown concentrations or IDLH conditions:;(APF = 10,000) Any self-contained breathing apparatus that has a full facepiece and is operated in a pressure-demand or other positive-pressure mode;(APF = 10,000) Any supplied-air respirator that has a full facepiece and is operated in a pressure-demand or other positive-pressure mode in combination with an auxiliary self-contained positive-pressure breathing apparatus;Escape:;(APF = 50) Any air-purifying, full-facepiece respirator (gas mask) with a chin-style, front- or back-mounted canister providing protection against the compound of concern;Any appropriate escape-type, self-contained breathing apparatus;Important additional information about respirator selection

Threshold Limit Values (TLV) · 4 items

1000.0 [ppm]

1250.0 [ppm]

1000 ppm [1964]

1250 ppm [1964]

Permissible Exposure Limit (PEL) · 3 items

1000.0 [ppm]

1000 ppm (1800 mg/m³)

TWA 1000 ppm (1800 mg/m3) See Appendix G

Protective Action Criteria (PAC) · 3 items

1250 [ppm]

2500 [ppm]

15000 [ppm]

Recommended Exposure Limit (REL) · 3 items

1000 ppm (1800 mg/m³)

1250 ppm (2250 mg/m³)

TWA 1000 ppm (1800 mg/m3) ST 1250 ppm (2250 mg/m3)

Toxicology

Target Organsrespiratory system, central nervous system
Adverse EffectsNeurotoxin - Acute solvent syndrome;Other Poison - Simple Asphyxiant
Exposure Routesinhalation, skin and/or eye contact (liquid)
Signs and Symptomsirritation respiratory system; excitement, confusion, anesthesia; liquid: frostbite

Regulatory information

Regulatory Information · 2 items

Chemical: Methyl acetylene-propadiene mixture

MAPP: Does not have an individual approval but may be used as a component in a product covered by a group standard. It is not approved for use as a chemical in its own right.

Safety data

OEB
A
OEL
TWA: 1000 ppm (1800 mg/m3), STEL: 1250 ppm (2250 mg/m3)
IDLA
3,400 ppm [10% LEL]

Chemistry & industry

Uses & manufacturing

Uses · 2 items

Used as fuel for industrial cutting; [ACGIH]

Gas Welding and Cutting [Category: Weld]

Applications · 3 items

DescriptionThismixtureofC3H4isomersisa flammable,colorlessgaswithastrong,characteristic,foulodor.Theodorthreshold is 100 ppm.Boiling point=38 to 20℃; Freezing/ Melting point=136℃; Relative vapor density (air= 1)= 1.48. Explosive limits: LEL= 3.4%; UEL= 10.8%. Hazard Identification(basedonNFPA-704MRatingSystem):Health0, Flammability 0, Reactivity 0. Insoluble in water. A fuel that is shipped as a liquefied compressed gas mixture containing 606.5%methylacetyleneandpropadiene;thebalanceisbutane andpropane.

UsesIndustrial fuel gas for cutting, welding, brazing, heat treating, and metallizing.

General DescriptionMethylacetylene-propadiene stabilized is a colorless gas with an acetylene like odor. Methylacetylene and propadiene mixture,stabilized is shipped as a liquefied gas under its vapor pressure. Contact with the liquid can cause frostbite. Methylacetylene and propadiene mixture,stabilized is easily ignited. The vapors are heavier than air. Any leak can either be liquid or vapor. Methylacetylene and propadiene mixture,stabilized can asphyxiate by the displacement of air. Under prolonged exposure to fire or intense heat the containers may rupture violently and rocket.

Suppliers3 total

南通合润生物科技有限公司18362409333 · [email protected]
淄博桓明新材料有限公司15264351707 15264351707 · [email protected]
天津荣燊化工有限公司18317763565; 18317763565 · [email protected]

Related reactions

3 records

Compound notes

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