Basic information
- CAS
7775-41-9- Standard SMILES
[F][Ag]- InChIKey
REYHXKZHIMGNSE-UHFFFAOYSA-M- Molecular formula
- AgF
- Average molar mass
- 126.867 g/mol
Overview
See also: Silver fluoride (preferred); Agaricus Phosphorus (FDA NDC: 48951-1023) (component of).
Names & identifiers
- Preferred name
- Caswell No. 736
- IUPAC
- fluorosilver
- English name
- Silver fluoride
- Molecular formula
- AgF
- Molecular weight
- 126.87
Names & synonyms
Show more names
Database identifiers
- CAS
7775-41-9- PubChem CID
- 62656
Properties
Computed structural properties
- Topological polar surface area
- 0 Ų
- Hydrogen bond donors
- 0
- Hydrogen bond acceptors
- 1
- Rotatable bonds
- 0
- Heavy atoms
- 2
- Formal charge
- 0
- Complexity
- 2
Physicochemical properties
- Melting point
- 300 °C · ≥300 °C(lit.)
- Boiling point
- 1150 °C · 1150 °C
- Density
- 5.852 g/mL · 5.852 g/mL at 25 °C(lit.)
- Flash point
- 1150 °C · 1150°C
- storage temp.
- Keep in dark place,Inert atmosphere,Room temperature
- solubility
- Methanol (Slightly), Water (Slightly)
- form
- solid
- color
- orange to brown
- Specific Gravity
- 5.852 · 5.852
- Water Solubility
- 182 g/100 · 182 g/100 mL (15.5 ºC)
- Sensitive
- Moisture Sensitive & Hygroscopic
- Crystal Structure
- NaCl type
- crystal system
- Cube
- Merck
- 14 · 14,8514
- Space group
- 3 m · Fm3m
- Lattice constant
- a/nm
- Symbol(GHS)
- 5 · GHS05
- Signal word
- Danger
- Hazard statements
- 314 · H314
- Precautionary statements
- 260 · P260-P280-P301+P330+P331-P303+P361+P353-P304+P340+P310-P305+P351+P338
- PPE
- 3 · Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges
- Hazard Codes
- C
- Risk Statements
- 34 · 34-23/24/25-35
- Safety Statements
- 26 · 26-36/37/39-45-25-28
- RIDADR
- 3260 · UN 3260 8/PG 2
- WGK Germany
- 3 · 3
- RTECS
- 4250000 · VW4250000
- F
- 3 · 3-8-10-21
- Hazard Note
- Corrosive
- TSCA
- TSCA listed
- HazardClass
- HYGROSCOPIC, CORROSIVE
- HS Code
- 28432900 · 28432900
- Storage Class
- 8 A · 8A - Combustible corrosive hazardous materials
- Hazard Classifications
- 1 B · Skin Corr. 1B
- Limited Quantities
- 1 Kg · 1 Kg (2.2 lbs) (solid)
- Excepted Quantities
- Max Inner Pack (30g or 30ml) and Max Outer Pack (500g or 500ml)
Safety & regulation
Safety data
- F
- 3-8-10-21
- PPE
- Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges
- wgk
- 3
- tsca
- TSCA listed
- rtecs
- VW4250000
- ridadr
- UN 3260 8/PG 2
- hs_code
- 28432900
- risk_code
- 34-23/24/25-35
- Signal word
- Danger
- Symbol(GHS)
- GHS05
- hazard_code
- C
- hazard_note
- Corrosive
- safety_code
- 26-36/37/39-45-25-28
- hazard_class
- 8
- Storage Class
- 8A - Combustible corrosive hazardous materials
- Hazard statements
- H314
- Limited Quantities
- 1 Kg (2.2 lbs) (solid)
- Excepted Quantities
- Max Inner Pack (30g or 30ml) and Max Outer Pack (500g or 500ml)
- Hazard Classifications
- Skin Corr. 1B
- Precautionary statements
- P260-P280-P301+P330+P331-P303+P361+P353-P304+P340+P310-P305+P351+P338
Chemistry & industry
Applications
UsesSilver(I) fluoride is used as a fluorination and desilylation reagent in organic synthesis. In medical filed, it is used as topical caries in aqueous form in dentistry. It is employed in organofluorine chemistry for addition of fluoride across multiple bonds, especially to prepare perfluoroalkylsilver(I) by reacting with alkenes. Further, it is involved in the preparation of tetralkylammonium fluorides by the reaction with tetralkylammonium bromide. In addition to this, it is used as a desulfuration-fluorination reagent on thiourea derived substrates.
UsesSilver fluoride is applied to convert organic Br and Cl Compounds to their fluoro analogs; as antiseptic. Preparation of bromoacetylenes from bulky, trialkylsilylacetylenes. Also used in a palladium-catalyzed cross coupling of acetanilides with trialkoxysilanes. Silver(I) fluoride is used as a fluorination and desilylation reagent in organic synthesis. In medical filed, it is used as topical caries in aqueous form in dentistry. It is employed in organofluorine chemistry for addition of fluoride across multiple bonds, especially to prepare perfluoroalkylsilver(I) by reacting with alkenes. Further, it is involved in the preparation of tetralkylammonium fluorides by the reaction with tetralkylammonium bromide. In addition to this, it is used as a desulfuration-fluorination reagent on thiourea derived substrates.
Uses▼▲ Industry Application Role/benefit Organic synthesis Fluorination of alkyl halides Fluorination agent/source of fluoride, both soluble in water and organic solvents Desulfuration-fluorination of thiourea derived substrates Inorganic synthesis Preparation of tetralkylammonium fluorides Reactant/reacts with tetralkylammonium bromide Preparation of chandelier-like [Ag10]2+ cluster Reactant/reacts with silver acetylide Dental caries Prevention of dental caries Anti-caries agent/little used for the instability of concentrated AgF solutions Preparation of anti-caries agent (Ag(NH3)2F) with good stability Raw material/source of the effective component Others Coating silicon surface with uniform silver microlayer Reactant/source of Ag
General DescriptionOdorless yellow to gray solid. Sinks and mixes with water.
Preparation methods
PreparationSilver(I) fluoride was prepared by reacting hydrogen fluoride with the carbonate and with the oxide.
Upstream & downstream products
Upstream raw materials
Suppliers100 total
Additional notes
DefinitionChEBI: Silver monofluoride is a silver salt and a fluoride salt.
Related reactions
Compound notes
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