Caswell No. 736

HCID 62656

Basic information

CAS
7775-41-9
Standard SMILES
[F][Ag]
InChIKey
REYHXKZHIMGNSE-UHFFFAOYSA-M
Molecular formula
AgF
Average molar mass
126.867 g/mol

Overview

See also: Silver fluoride (preferred); Agaricus Phosphorus (FDA NDC: 48951-1023) (component of).

Names & identifiers

Preferred name
Caswell No. 736
IUPAC
fluorosilver
English name
Silver fluoride
Molecular formula
AgF
Molecular weight
126.87

Names & synonyms

Caswell No. 736EINECS 231-895-8EPA Pesticide Chemical Code 072502UNII-1Z00ZK3E66silver (I)fluorideSilver(I) fluoride, 99%SCHEMBL110576orb3144214TYD-03554AKOS017344338PD205080CS-0015954
Show more names
AgFSILVER(I) FLUORIDESILVER MONOFLUORIDEuoridePRO178UNQ152IachiolTachiolTachyolver(I) fL
Q414689Silver(I) fluoride, >=99.9% trace metals basisAg-F; Silver fluoride (AgF); Silver(1+) fluoride; Silver(I) Fluoride

Database identifiers

CAS
7775-41-9
PubChem CID
62656

Properties

Computed structural properties

Topological polar surface area
0 Ų
Hydrogen bond donors
0
Hydrogen bond acceptors
1
Rotatable bonds
0
Heavy atoms
2

Physicochemical properties

Melting point
300 °C · ≥300 °C(lit.)
Boiling point
1150 °C · 1150 °C
Density
5.852 g/mL · 5.852 g/mL at 25 °C(lit.)
Flash point
1150 °C · 1150°C
storage temp.
Keep in dark place,Inert atmosphere,Room temperature
solubility
Methanol (Slightly), Water (Slightly)

Safety & regulation

Safety data

F
3-8-10-21
PPE
Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges
wgk
3
tsca
TSCA listed
rtecs
VW4250000
ridadr
UN 3260 8/PG 2

Chemistry & industry

Applications · 4 items

UsesSilver(I) fluoride is used as a fluorination and desilylation reagent in organic synthesis. In medical filed, it is used as topical caries in aqueous form in dentistry. It is employed in organofluorine chemistry for addition of fluoride across multiple bonds, especially to prepare perfluoroalkylsilver(I) by reacting with alkenes. Further, it is involved in the preparation of tetralkylammonium fluorides by the reaction with tetralkylammonium bromide. In addition to this, it is used as a desulfuration-fluorination reagent on thiourea derived substrates.

UsesSilver fluoride is applied to convert organic Br and Cl Compounds to their fluoro analogs; as antiseptic. Preparation of bromoacetylenes from bulky, trialkylsilylacetylenes. Also used in a palladium-catalyzed cross coupling of acetanilides with trialkoxysilanes. Silver(I) fluoride is used as a fluorination and desilylation reagent in organic synthesis. In medical filed, it is used as topical caries in aqueous form in dentistry. It is employed in organofluorine chemistry for addition of fluoride across multiple bonds, especially to prepare perfluoroalkylsilver(I) by reacting with alkenes. Further, it is involved in the preparation of tetralkylammonium fluorides by the reaction with tetralkylammonium bromide. In addition to this, it is used as a desulfuration-fluorination reagent on thiourea derived substrates.

Uses▼▲ Industry Application Role/benefit Organic synthesis Fluorination of alkyl halides Fluorination agent/source of fluoride, both soluble in water and organic solvents Desulfuration-fluorination of thiourea derived substrates Inorganic synthesis Preparation of tetralkylammonium fluorides Reactant/reacts with tetralkylammonium bromide Preparation of chandelier-like [Ag10]2+ cluster Reactant/reacts with silver acetylide Dental caries Prevention of dental caries Anti-caries agent/little used for the instability of concentrated AgF solutions Preparation of anti-caries agent (Ag(NH3)2F) with good stability Raw material/source of the effective component Others Coating silicon surface with uniform silver microlayer Reactant/source of Ag

General DescriptionOdorless yellow to gray solid. Sinks and mixes with water.

Preparation methods

PreparationSilver(I) fluoride was prepared by reacting hydrogen fluoride with the carbonate and with the oxide.

Upstream & downstream products

Suppliers100 total

上海阿拉丁生化科技股份有限公司400-6206333 13167063860 · [email protected]
上海凌富药物研究有限公司+86(21)5895 0110 19945755304 · [email protected]
合肥翰刚医药科技有限公司+8618062405514 · [email protected]
环生美森医药技术(山东)有限公司0531-88762217 18301471076 · [email protected]
Baoji Guokang Healthchem co.,ltd+8615604608665 15604608665 · [email protected]

Additional notes

DefinitionChEBI: Silver monofluoride is a silver salt and a fluoride salt.

Related reactions

300 records

Compound notes

Loading…