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Thallium iodide (TlI)

HCID 62679
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Basic information

CAS
7790-30-9
Standard SMILES
[I][Tl]
InChIKey
CMJCEVKJYRZMIA-UHFFFAOYSA-M
Molecular formula
ITl
Average molar mass
331.288 g/mol
Monoisotopic mass
331.8789

Names & identifiers

Preferred name
Thallium iodide (TlI)
IUPAC
iodothallium
English name
THALLIUM(I) IODIDE
Molecular formula
ITl
Molecular weight
331.29

Names & synonyms

Thallium iodideThallous iodide7790-30-9Thallium iodide (TlI)Thallium(1+) iodideThallium monoiodideThallium iodide (TlI), dimer98W17EMO3CDTXSID10894795NSC-15201RefChem:1099771DTXCID801324376
Show more names
TlIThalium IodidethalllumiodideTHALLIUM IODIDIEThalliuM PURATREMThallium(Ⅰ)iodideTHALLIUM(I) IODIDEthallium(1+)iodide
232-199-7Thallium iodide, TlIThallium iodide (Tl2I2)Thallium iodide (VAN)EINECS 232-199-7NSC 15201UNII-98W17EMO3CThallium iodide

Database identifiers

CAS
7790-30-9
PubChem CID
62679
DTXSID
DTXSID10894795
EC Number
232-199-7

Properties

Computed structural properties

Topological polar surface area
0 Ų
Hydrogen bond donors
0
Hydrogen bond acceptors
0
Rotatable bonds
0
Heavy atoms
2
Formal charge
0
Complexity
2

Experimental & physicochemical properties

Chemical ClassesMetals -> Metals, Inorganic Compounds
SpringerMaterials Propertiesnuclear quadrupole moment
Physical DescriptionYellow solid; Nearly insoluble in water; [Merck Index] Yellow powder; [Aldrich MSDS] Insoluble in water; [Alfa Aesar MSDS]

Physicochemical properties

Melting point
440 °C · 440 °C(lit.)
Boiling point
823 °C · 823°C
Density
7.29 g/mL · 7.29 g/mL at 25 °C(lit.)
Flash point
824 °C · 824°C
storage temp.
10 · 10-30°C
solubility
insoluble in ethanol
form
Powder
Specific Gravity
7.09 · 7.09
color
Yellow
Water Solubility
Practically insoluble in water

Safety & regulation

Safety information is for reference only and does not replace the supplier’s Safety Data Sheet (SDS), applicable regulations, or professional assessment.

GHS classification

GHS Classification · 5 items

Danger

H300 (100%): Fatal if swallowed [Danger Acute toxicity, oral]

P260, P264, P270, P271, P273, P284, P301+P316, P304+P340, P316, P319, P320, P321, P330, P391, P403+P233, P405, and P501 (click each P-code to see the statement)

Aggregated GHS information provided per 84 reports by companies from 7 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.

Not Classified

Hazard information

Regulatory InformationThallium (I) iodide: HSNO Approval: HSR006162 Approved with controls
Hazards Summary · 1 item

Poisonous; [Merck Index] Caused muscle weakness and lowered blood pressure in an oral toxic-dose study of men; [RTECS] May be decomposed by light; May cause irritation and blindness; May be fatal by inhalation and ingestion; Danger of cumulative effects; Targets kidneys, cardiovascular system, skin, liver, male reproductive system, nerves, and eyes; [Aldrich MSDS] See Thallium and the linked occupational disease. See Iodine for the TLV of Iodides.

Hazard Classes and CategoriesAcute Tox. 2 (100%)

Safety & protection

Threshold Limit Values (TLV)0.01 [ppm], inhalable fraction and vapor (iodides)

Toxicology

Adverse EffectsNeurotoxin - Sensorimotor

Chemistry & industry

Uses & manufacturing

UsesUsed as infrared radiation transmitter (crystals mixed with thallium bromide); [Hawley]
General Manufacturing InformationThallium iodide (TlI): ACTIVE
Applications · 3 items

DescriptionThallium (I) iodide is a yellow solid, nearly insoluble in water. It is used as infrared radiation transmitter (crystals mixed with thallium bromide).

UsesMixed crystals with thallium bromide for infrared radiation transmitters.

UsesThallium(I) iodide is used in mercury lamp to enhance its performance. It is mainly used for underwater lighting, since the blue green light produced has least absorption in water. Scintillator made by using iodide salt of thallium, sodium and cesium is utilized for radiation scintillation detectors.

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Compound notes

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On this pageBasic informationNames & identifiersPropertiesSafety & regulationChemistry & industryRelated reactionsCompound notes
Sensitive
Light Sensitive
Merck
14 · 14,9264
Solubility Product Constant (Ksp)
7.26 · pKsp: 7.26
Exposure limits
0.02 mg/m3 · ACGIH: TWA 0.02 mg/m3 (Skin)
InChI
1S/HI.Tl/h1H;/q;+1/p-1
InChIKey
CMJCEVKJYRZMIA-UHFFFAOYSA-M
SMILES
I[Tl]
CAS DataBase Reference
7790 · 7790-30-9(CAS DataBase Reference)
EWG's Food Scores
1 · 1
FDA UNII
98 W17EMO3C · 98W17EMO3C
EPA Substance Registry System
Thallium iodide (TlI) (7790-30-9)
UNSPSC Code
12352302 · 12352302
NACRES
23 · NA.23
Symbol(GHS)
6 · GHS06,GHS08,GHS09
Signal word
Danger
Hazard statements
300 · H300-H330-H373-H411
Precautionary statements
264 · P264-P270-P260-P271-P284-P273-P301+P310-P330-P304+P340-P310-P314-P391-P405-P403+P233-P501
Hazard Codes
T+,N
Risk Statements
26 · 26/28-33-51/53
Safety Statements
13 · 13-28-45-61
RIDADR
1707 · UN 1707 6.1/PG 2
WGK Germany
3 · 3
RTECS
5425000 · XG5425000
TSCA
TSCA listed
HazardClass
6.1 · 6.1
PackingGroup
II
Storage Class
6.1 A · 6.1A - Combustible acute toxic Cat. 1 and 2very toxic hazardous materials
Hazard Classifications
2 InhalationAcute · Acute Tox. 2 InhalationAcute Tox. 2 OralAquatic Chronic 2STOT RE 2
Limited Quantities
0.5 Kg · 0.5 Kg (solid)
Excepted Quantities
Max Inner Pack (1g or 1ml) and Max Outer Pack (500g or 500ml)

Safety data

wgk
3
tsca
TSCA listed
rtecs
XG5425000
ridadr
UN 1707 6.1/PG 2
risk_code
26/28-33-51/53
Signal word
Danger
Symbol(GHS)
GHS06,GHS08,GHS09
hazard_code
T+,N
safety_code
13-28-45-61
hazard_class
6.1
Storage Class
6.1A - Combustible acute toxic Cat. 1 and 2very toxic hazardous materials
packing_group
II
Hazard statements
H300-H330-H373-H411
Limited Quantities
0.5 Kg (solid)
Excepted Quantities
Max Inner Pack (1g or 1ml) and Max Outer Pack (500g or 500ml)
Hazard Classifications
Acute Tox. 2 InhalationAcute Tox. 2 OralAquatic Chronic 2STOT RE 2
Precautionary statements
P264-P270-P260-P271-P284-P273-P301+P310-P330-P304+P340-P310-P314-P391-P405-P403+P233-P501