Basic information
- CAS
13446-34-9- Standard SMILES
O.O.O.O.[Cl][Mn][Cl]- InChIKey
CNFDGXZLMLFIJV-UHFFFAOYSA-L- Molecular formula
- Cl2H8MnO4
- Average molar mass
- 197.9 g/mol
- Monoisotopic mass
- 196.918007
Names & identifiers
- Preferred name
- Manganese Chloride Tetrahydrate
- IUPAC
- dichloromanganese;tetrahydrate
- English name
- Manganese chloride tetrahydrate
- Molecular formula
- Cl2H2MnO
- Molecular weight
- 143.85
Names & synonyms
Show more names
Database identifiers
- CAS
13446-34-9- PubChem CID
- 643989
- DTXSID
DTXSID00858866- ChEBI
CHEBI:86368- EC Number
- 603-826-5
Properties
Computed structural properties
- Topological polar surface area
- 4 Ų
- Hydrogen bond donors
- 4
- Hydrogen bond acceptors
- 4
- Rotatable bonds
- 0
- Heavy atoms
- 7
- Formal charge
- 0
- Complexity
- 2
Experimental & physicochemical properties
Physicochemical properties
- Melting point
- 58 °C · 58 °C(lit.)
- Boiling point
- 1190 °C · 1190 °C
- Density
- 2 · 2,01 g/cm3
- bulk density
- 1150 kg/m3 · 1150kg/m3
- storage temp.
- 5 °C · Store at +5°C to +30°C.
- solubility
- 2 O: · H2O: 0.5 M at 20 °C, clear, colorless
- form
- Solid
- color
- Red
- Specific Gravity
- 2.01 · 2.01
- PH
- 3.5 · 3.5-6 (50g/l, H2O, 25℃)
- PH Range
- 4 · 4 - 6
- Odor Threshold
- Odorless
- Water Solubility
- 1980 g/L · 1980 g/L (20 ºC)
- Sensitive
- Hygroscopic
- λmax
- 260 nm · λ: 260 nm Amax: 0.01λ: 280 nm Amax: 0.01
- Merck
- 14 · 14,5728
- Exposure limits
- 0.02 mg/m3; · ACGIH: TWA 0.02 mg/m3; TWA 0.1 mg/m3OSHA: Ceiling 5 mg/m3NIOSH: IDLH 500 mg/m3; TWA 1 mg/m3; STEL 3 mg/m3
- Stability
- Stable. Incompatible with moisture, strong acids, sodium, potassium, zinc.
- InChI
- 1S/2ClH.Mn.4H2O/h2*1H;;4*1H2/q;;+2;;;;/p-2
- InChIKey
- CNFDGXZLMLFIJV-UHFFFAOYSA-L
- SMILES
- Cl[Mn]Cl.[H]O[H].[H]O[H].[H]O[H].[H]O[H]
- LogP
- -1.38 · -1.380 (est)
- CAS DataBase Reference
- 13446 · 13446-34-9(CAS DataBase Reference)
- Substances Added to Food (formerly EAFUS)
- MANGANESE CHLORIDE
- FDA UNII
- 170 PANO · QQE170PANO
- EPA Substance Registry System
- Manganese chloride (MnCl2), tetrahydrate (13446-34-9)
- UNSPSC Code
- 41116107 · 41116107
- NACRES
- 24 · NB.24
- Symbol(GHS)
- 5 · GHS05,GHS06,GHS08
- Signal word
- Danger
- Hazard statements
- 301 · H301-H318-H373
- Precautionary statements
- 260 · P260-P264-P280-P301+P310-P305+P351+P338-P314
- target organs
- Brain
- Hazard Codes
- Xn,Xi
- Risk Statements
- 22 · 22-52-48/22
- Safety Statements
- 61 · 61-45-24/25
- RIDADR
- 3077 · UN 3077 9 / PGIII
- WGK Germany
- 1 · 1
- RTECS
- 9650000 · OO9650000
- F
- 3 · 3
- TSCA
- Yes
- HS Code
- 2827 · 2827 39 85
- HazardClass
- 6.1 · 6.1
- PackingGroup
- III
- Storage Class
- 6.1 D · 6.1D - Non-combustible acute toxic Cat.3toxic hazardous materials or hazardous materials causing chronic effects
- Hazard Classifications
- 3 OralEye · Acute Tox. 3 OralEye Dam. 1STOT RE 2
- Toxicity
- 50 in · LD 50 in rats (mmole/kg): 7.5 orally; 0.70 i.p. (Holbrook)
- Limited Quantities
- 5 kg · 5.0 kg (11 lbs) (solid)
- Excepted Quantities
- Max Inner Pack (30g or 30ml) and Max Outer Pack (1Kg or 1L)
Safety & regulation
GHS classification
GHS Classification
This chemical does not meet GHS hazard criteria for 3.2% (5 of 158) of reports.
Danger
H301 (15.2%): Toxic if swallowed [Danger Acute toxicity, oral];H302 (81.6%): Harmful if swallowed [Warning Acute toxicity, oral];H318 (33.5%): Causes serious eye damage [Danger Serious eye damage/eye irritation];H319 (22.8%): Causes serious eye irritation [Warning Serious eye damage/eye irritation];H373 (32.9%): May causes damage to organs through prolonged or repeated exposure [Warning Specific target organ toxicity, repeated exposure];H411 (43%): Toxic to aquatic life with long lasting effects [Hazardous to the aquatic environment, long-term hazard]
P260, P264, P264+P265, P270, P273, P280, P301+P316, P301+P317, P305+P351+P338, P305+P354+P338, P317, P319, P321, P330, P337+P317, P391, P405, and P501 (click each P-code to see the statement)
Aggregated GHS information provided per 158 reports by companies from 12 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.;Reported as not meeting GHS hazard criteria per 5 of 158 reports by companies.;There are 11 notifications provided by 153 of 158 reports by companies with hazard statement code(s).;Information may vary between notifications depending on impurities, additives, and other factors. The percentage value in parenthesis indicates the notified classification ratio from companies that provide hazard codes. Only hazard codes with percentage values above 10% are shown. For more detailed information, please visit ECHA C&L website.
Hazard information
Regulatory Information
Chemical: Manganese chloride (MnCl2), tetrahydrate
Regulation (EC) No 1831/2003 (amended)
Manganese (II) chloride, tetrahydrate: Does not have an individual approval but may be used under an appropriate group standard
Hazards Summary
Causes changes in liver, surface EEG, and recordings from peripheral motor nerves in intraperitoneal toxic-dose studies of rats; Causes degenerative changes of brain and effects on dopamine in striatum and spermatogenesis in repeated oral studies of rats; [RTECS] May cause irritation; Harmful by ingestion and skin absorption; Targets CNS and lungs; [Aldrich MSDS] See Manganese and linked occupational diseases.
Hazard Classes and Categories
Acute Tox. 3 (15.2%);Acute Tox. 4 (81.6%);Eye Dam. 1 (33.5%);Eye Irrit. 2 (22.8%);STOT RE 2 (32.9%);Aquatic Chronic 2 (43%)
Acute toxicity (ingestion) - category 4;Eye damage - category 1;Specific target organ toxicity (repeated exposure) - category 1
Acute toxicity (Oral) - Category 4;Reproductive toxicity - Category 2;Specific target organ toxicity - Repeated exposure - Category 1 (nervous system, respiratory organs);Hazardous to the aquatic environment (Acute) - Category 3;Hazardous to the aquatic environment (Long-term) - Category 2
Safety & protection
Protective Action Criteria (PAC)
11 [mg/m3]
18 [mg/m3]
290 [mg/m3]
Toxicology
Regulatory information
Regulatory Information
Chemical: Manganese chloride (MnCl2), tetrahydrate
Regulation (EC) No 1831/2003 (amended)
Manganese (II) chloride, tetrahydrate: Does not have an individual approval but may be used under an appropriate group standard
Safety data
- F
- 3
- wgk
- 1
- tsca
- Yes
- rtecs
- OO9650000
- ridadr
- UN 3077 9 / PGIII
- hs_code
- 2827 39 85
- Toxicity
- LD 50 in rats (mmole/kg): 7.5 orally; 0.70 i.p. (Holbrook)
- risk_code
- 22-52-48/22
- Signal word
- Danger
- Symbol(GHS)
- GHS05,GHS06,GHS08
- hazard_code
- Xn,Xi
- safety_code
- 61-45-24/25
- hazard_class
- 6.1
- Storage Class
- 6.1D - Non-combustible acute toxic Cat.3toxic hazardous materials or hazardous materials causing chronic effects
- packing_group
- III
- target organs
- Brain
- Hazard statements
- H301-H318-H373
- Limited Quantities
- 5.0 kg (11 lbs) (solid)
- Excepted Quantities
- Max Inner Pack (30g or 30ml) and Max Outer Pack (1Kg or 1L)
- Hazard Classifications
- Acute Tox. 3 OralEye Dam. 1STOT RE 2
- Precautionary statements
- P260-P264-P280-P301+P310-P305+P351+P338-P314
Chemistry & industry
Uses & manufacturing
Uses
Used in dyeing, disinfecting, and purifying natural gas; Also used to make linseed oil (dryer) and batteries; [Merck Index] Used as nutrient supplement; [ExPub: FDA]
Petroleum Production and Refining [Category: Industry];Battery Manufacturing [Category: Industry];Using Disinfectants or Biocides [Category: Clean];Textiles (Printing, Dyeing, or Finishing) [Category: Industry]
Applications
UsesManganese Chloride Tetrahydrate is an inorganic chemical reagent used in oxidation studies and reactions.
UsesManganese chloride tetrahydrate is a useful agent to detect phospholipid vesicles.
UsesIn dyeing (manganese bister); disinfecting; purifying natural gas; linseed oil drier; in electric batteries.
General DescriptionManganese(II) chloride tetrahydrate is a hydrated metal chloride.3 Its toxicity in Swiss mice has been assessed. It participates in the preparation of metal(II) complexes of mixed ligands-dimethydithiocarbamic and p-aminobenzoic acids.3
Upstream & downstream products
Upstream raw materials
Suppliers100 total
Related reactions
Compound notes
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