Manganese Chloride Tetrahydrate

HCID 643989

Basic information

CAS
13446-34-9
Standard SMILES
O.O.O.O.[Cl][Mn][Cl]
InChIKey
CNFDGXZLMLFIJV-UHFFFAOYSA-L
Molecular formula
Cl2H8MnO4
Average molar mass
197.9 g/mol
Monoisotopic mass
196.918007

Names & identifiers

Preferred name
Manganese Chloride Tetrahydrate
IUPAC
dichloromanganese;tetrahydrate
English name
Manganese chloride tetrahydrate
Molecular formula
Cl2H2MnO
Molecular weight
143.85

Names & synonyms

Manganese chloride tetrahydrateLumenhanceManganous chloride tetrahydrateManganese(2+) chloride tetrahydratemanganese chloride, tetrahydrateManganese chloride (USP)Manganese chloride in plastic containerCHEBI:86368DTXSID00858866MANGANESE(II) CHLORIDE, TETRAHYDRATEManganese chloride [USP]RefChem:55546
Show more names
MnClMANGANOUS CHLORIDEMANGANESE (II) CHLORIDEMANGANESE CHLORIDE TETRAHYDRATE INSEanese(Ⅱ) chLManganese(Ⅱ) chLdichloromanganeseoride tetrahydrateManganeseChlorideAr
DTXCID70809608603-826-513446-34-9Manganese dichloride tetrahydratemanganese(II) chloride tetrahydratedichloromanganese;tetrahydrateManganese chloride (MnCl2), tetrahydrateLumenhance (TN)

Database identifiers

CAS
13446-34-9
PubChem CID
643989
DTXSID
DTXSID00858866
ChEBI
CHEBI:86368
EC Number
603-826-5

Properties

Computed structural properties

Topological polar surface area
4 Ų
Hydrogen bond donors
4
Hydrogen bond acceptors
4
Rotatable bonds
0
Heavy atoms
7

Experimental & physicochemical properties

Density2.01 @25 °C
Melting Point58 °C
Physical DescriptionReddish solid; Slightly deliquescent; [Merck Index] Light red crystalline solid; [Aldrich MSDS]

Physicochemical properties

Melting point
58 °C · 58 °C(lit.)
Boiling point
1190 °C · 1190 °C
Density
2 · 2,01 g/cm3
bulk density
1150 kg/m3 · 1150kg/m3
storage temp.
5 °C · Store at +5°C to +30°C.
solubility
2 O: · H2O: 0.5 M at 20 °C, clear, colorless

Safety & regulation

GHS classification

GHS Classification · 6 items

This chemical does not meet GHS hazard criteria for 3.2% (5 of 158) of reports.

Danger

H301 (15.2%): Toxic if swallowed [Danger Acute toxicity, oral];H302 (81.6%): Harmful if swallowed [Warning Acute toxicity, oral];H318 (33.5%): Causes serious eye damage [Danger Serious eye damage/eye irritation];H319 (22.8%): Causes serious eye irritation [Warning Serious eye damage/eye irritation];H373 (32.9%): May causes damage to organs through prolonged or repeated exposure [Warning Specific target organ toxicity, repeated exposure];H411 (43%): Toxic to aquatic life with long lasting effects [Hazardous to the aquatic environment, long-term hazard]

P260, P264, P264+P265, P270, P273, P280, P301+P316, P301+P317, P305+P351+P338, P305+P354+P338, P317, P319, P321, P330, P337+P317, P391, P405, and P501 (click each P-code to see the statement)

Aggregated GHS information provided per 158 reports by companies from 12 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.;Reported as not meeting GHS hazard criteria per 5 of 158 reports by companies.;There are 11 notifications provided by 153 of 158 reports by companies with hazard statement code(s).;Information may vary between notifications depending on impurities, additives, and other factors. The percentage value in parenthesis indicates the notified classification ratio from companies that provide hazard codes. Only hazard codes with percentage values above 10% are shown. For more detailed information, please visit ECHA C&L website.

Hazard information

Regulatory Information · 3 items

Chemical: Manganese chloride (MnCl2), tetrahydrate

Regulation (EC) No 1831/2003 (amended)

Manganese (II) chloride, tetrahydrate: Does not have an individual approval but may be used under an appropriate group standard

Other Safety InformationIMAP assessments - Soluble manganese compounds: Human health tier II assessment
Hazards Summary · 1 item

Causes changes in liver, surface EEG, and recordings from peripheral motor nerves in intraperitoneal toxic-dose studies of rats; Causes degenerative changes of brain and effects on dopamine in striatum and spermatogenesis in repeated oral studies of rats; [RTECS] May cause irritation; Harmful by ingestion and skin absorption; Targets CNS and lungs; [Aldrich MSDS] See Manganese and linked occupational diseases.

Hazard Classes and Categories · 3 items

Acute Tox. 3 (15.2%);Acute Tox. 4 (81.6%);Eye Dam. 1 (33.5%);Eye Irrit. 2 (22.8%);STOT RE 2 (32.9%);Aquatic Chronic 2 (43%)

Acute toxicity (ingestion) - category 4;Eye damage - category 1;Specific target organ toxicity (repeated exposure) - category 1

Acute toxicity (Oral) - Category 4;Reproductive toxicity - Category 2;Specific target organ toxicity - Repeated exposure - Category 1 (nervous system, respiratory organs);Hazardous to the aquatic environment (Acute) - Category 3;Hazardous to the aquatic environment (Long-term) - Category 2

Safety & protection

Exposure Control and Personal Protection0.2 [mg/m3], as Mn (inhalable fraction), 0.02 mg/m3, as Mn (respirable fraction)[German Research Foundation (DFG)]
Threshold Limit Values (TLV)0.02 [mg/m3], as Mn (respirable fraction), 0.1 mg/m3, as Mn (inhalable fraction)
Protective Action Criteria (PAC) · 3 items

11 [mg/m3]

18 [mg/m3]

290 [mg/m3]

Toxicology

Adverse EffectsNeurotoxin - Parkinsonism

Regulatory information

Regulatory Information · 3 items

Chemical: Manganese chloride (MnCl2), tetrahydrate

Regulation (EC) No 1831/2003 (amended)

Manganese (II) chloride, tetrahydrate: Does not have an individual approval but may be used under an appropriate group standard

Safety data

F
3
wgk
1
tsca
Yes
rtecs
OO9650000
ridadr
UN 3077 9 / PGIII
hs_code
2827 39 85

Chemistry & industry

Uses & manufacturing

Uses · 2 items

Used in dyeing, disinfecting, and purifying natural gas; Also used to make linseed oil (dryer) and batteries; [Merck Index] Used as nutrient supplement; [ExPub: FDA]

Petroleum Production and Refining [Category: Industry];Battery Manufacturing [Category: Industry];Using Disinfectants or Biocides [Category: Clean];Textiles (Printing, Dyeing, or Finishing) [Category: Industry]

Applications · 4 items

UsesManganese Chloride Tetrahydrate is an inorganic chemical reagent used in oxidation studies and reactions.

UsesManganese chloride tetrahydrate is a useful agent to detect phospholipid vesicles.

UsesIn dyeing (manganese bister); disinfecting; purifying natural gas; linseed oil drier; in electric batteries.

General DescriptionManganese(II) chloride tetrahydrate is a hydrated metal chloride.3 Its toxicity in Swiss mice has been assessed. It participates in the preparation of metal(II) complexes of mixed ligands-dimethydithiocarbamic and p-aminobenzoic acids.3

Upstream & downstream products

Suppliers100 total

国药集团化学试剂有限公司86-21-63210123 · [email protected]
梯希爱(上海)化成工业发展有限公司021-67121386 · [email protected]
上海阿拉丁生化科技股份有限公司400-6206333 13167063860 · [email protected]
合肥翰刚医药科技有限公司+8618062405514 · [email protected]
武汉欣扬瑞和化学科技有限公司153-07155313 15307155313 · [email protected]

Related reactions

1 records

Compound notes

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