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Vinyltriethoxysilane

HCID 6516
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Basic informationOverviewNames & identifiersPropertiesSafety & regulationChemistry & industryRelated reactionsCompound notes
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Basic information

CAS
78-08-0
Standard SMILES
C=C[Si](OCC)(OCC)OCC
InChIKey
FWDBOZPQNFPOLF-UHFFFAOYSA-N
Molecular formula
C8H18O3Si
Average molar mass
190.31 g/mol
Monoisotopic mass
190.10252097

Overview

aqueous adhesive for affixing sections to glass slides when hydrolyzed

Names & identifiers

Preferred name
Vinyltriethoxysilane
IUPAC
ethenyl(triethoxy)silane
English name
Triethoxyvinylsilane
Molecular formula
C8H18O3Si
Molecular weight
190.31

Names & synonyms

VinyltriethoxysilaneTRIETHOXYVINYLSILANE78-08-0Silane, ethenyltriethoxy-Triethoxy(vinyl)silaneTriethoxyvinylsilicaneSilane, triethoxyvinyl-VTESSilane A 151Triethoxyvinyl silaneethenyltriethoxysilaneKBE 1003
Show more names
VTEOEthenyltriethyloxy-silaneA 151nv1107CV-4910CFS-080kbe1003
NV 11078V1TKX755VRefChem:901964201-081-7Union carbide A-151ethenyl(triethoxy)silaneVTS-ECCRIS 2645

Database identifiers

CAS
78-08-0
PubChem CID
6516
DTXSID
DTXSID3044463
ChEMBL
CHEMBL3188350
UNII
8V1TKX755V
EC Number
201-081-7
Nikkaji
J44.149J

Properties

Computed structural propertiesFilling in

Topological polar surface area
27.7 Ų
Hydrogen bond donors
0
Hydrogen bond acceptors
3
Rotatable bonds
7
Heavy atoms
12
Formal charge
0
Complexity
110

Experimental & physicochemical properties

Chemical ClassesMetals -> Metalloid Compounds (Silicon)
SpringerMaterials PropertiesChemical shift
Density0.901 @25 °C
Vapor Pressure · 2 items

2.28 [mmHg]

2.25 [mm Hg] @20 °C

Physical Description · 2 items

Liquid

Colorless liquid with a fruity odor; [Alfa Aesar MSDS]

Physicochemical properties

Melting point
0 °C · <0°C
Boiling point
160 · 160-161 °C(lit.)
Density
0.903 g/mL · 0.903 g/mL at 25 °C(lit.)
vapor pressure
7 hPa · 7 hPa (20 °C)
refractive index
20 · n20/D 1.398(lit.)
Flash point
94 °F · 94 °F
storage temp.

Safety & regulation

Safety information is for reference only and does not replace the supplier’s Safety Data Sheet (SDS), applicable regulations, or professional assessment.

GHS classification

GHS Classification · 5 items

This chemical does not meet GHS hazard criteria for 17.7% (63 of 356) of reports.

Warning

H226 (82.3%): Flammable liquid and vapor [Warning Flammable liquids]

P210, P233, P240, P241, P242, P243, P261, P264+P265, P271, P280, P303+P361+P353, P304+P340, P305+P351+P338, P319, P337+P317, P370+P378, P403+P233, P403+P235, P405, and P501 (click each P-code to see the statement)

Aggregated GHS information provided per 356 reports by companies from 10 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.

Hazard information

Regulatory Information · 5 items

Chemical: Silane, ethenyltriethoxy-

Regulation (EC) No 1935/2004 (amended)

Silane, ethenyltriethoxy- is listed on the EPA's Chemical Data Reporting (CDR) system. Manufacturers and importers of Silane, ethenyltriethoxy- are required to report information about their production and use of this chemical to the EPA under the Toxic Substances Control Act (TSCA). (40 eCFR Part 711)

REACH registered substance: Triethoxy(vinyl)silane (EC: 201-081-7)

Silane, ethenyltriethoxy-: Does not have an individual approval but may be used under an appropriate group standard

Other Safety InformationEvaluation - Chemicals that are unlikely to require further regulation to manage risks to environment
Hazards SummaryA mild skin and eye irritant; [RTECS] Hydrolyzed by water; A mild skin and strong eye irritant; [Alfa Aesar MSDS] See Octamethyltrisiloxane and Dimethoxydimethylsilane.
Hazard Classes and CategoriesFlam. Liq. 3 (82.3%)

Safety & protection

Chemistry & industry

Pharmacology

MeSH Pharmacological ClassificationSubstances that cause the adherence of two surfaces. They include glues (properly collagen-derived adhesives), mucilages, sticky pastes, gums, resins, or latex.

Uses & manufacturing

Uses · 2 items

Used as an adhesive for glass slides; [REPROTOX] Used as a coupling agent on inorganic substances (fillers) blended into polymers that function as adhesion promoters, crosslinkers, and/or surface modifiers; Also used to make general purpose polymers; [ExPub: EC: EFSA]

Working with Glues and Adhesives [Category: Other]

U.S. Production2023: 100,000 - <250,000 lb
Consumer UsesAdhesion/cohesion promoter
Industry UsesIntermediate
General Manufacturing Information · 2 items

Custom Compounding of Purchased Resins

Silane, ethenyltriethoxy-: ACTIVE

Applications · 3 items

Descriptionvinyltriethoxysilane, is a vinyl-functional silane that may be used to improve the bond between glass fiber or mineral fillers and resins that are reactive towards the vinyl group. It is also employed to functionalize resins via free radical mechanisms - copolymerization or grafting - and to modify surfaces. vinyltriethoxysilane is mainly applied in these aspects: In the preparation of moisture-curing polymers, e.g. polyethylene. Silane crosslinked polyethylene is widely used as cable isolation, and sheathing mainly in low voltage applications as well as for hot water/sanitary pipes and underfloor heating. As a co-monomer for the preparation of different polymers such as polyethylene or acrylics. Those polymers show an improved adhesion to inorganic surfaces and they can also be crosslinked with moisture. As an efficient adhesion promoter for various mineral-filled polymers, improving mechanical and electrical properties especially after exposure to moisture. Improving the compatibility of fillers with polymers, leading to a better dispersibility, reduced melt viscosity and easier processing of filled plastics. Pre-treating of glass, metals, or ceramic surfaces, improve the adhesion of coatings on these surfaces and corrosion resistance. As moisture scavenger, it reacts rapidly with water. This effect is used widely in sealants.

Related reactions

11 records
New reaction record
HRID 13726 reaction equation
HRID 13726As reactantuspto-grants-2010_06
HRID 674603 reaction equation
HRID 674603As productTraining data from https://doi.org/10.1039/C8SC04228D (3/10)
HRID 1287962 reaction equation
HRID 1287962As reactantuspto-grants-1976_10
HRID 1287963 reaction equation
HRID 1287963As reactantuspto-grants-1976_10
HRID 1380160 reaction equation
HRID 1380160As productuspto-grants-1986_04
HRID 1380161 reaction equation
HRID 1380161As reactantuspto-grants-1986_04
HRID 1449000 reaction equation
HRID 1449000As reactantuspto-grants-1980_02
HRID 1829950 reaction equation
HRID 1829950As reactantuspto-grants-2006_06
Page 1 of 2

Compound notes

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On this pageBasic informationOverviewNames & identifiersPropertiesSafety & regulationChemistry & industryRelated reactionsCompound notes
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30 °C · Store below +30°C.
solubility
Miscible with organic solvents.
form
liquid
color
colorless
Specific Gravity
0.903 · 0.903
Odor
Fruity odor
Viscosity
0.7 cs · 0.70 cs (25C)
explosive limit
0.53 · 0.53-15%(V)
Water Solubility
decomposes
FreezingPoint
0 · <0
Hydrolytic Sensitivity
7 · 7: reacts slowly with moisture/water
Sensitive
Moisture Sensitive
BRN
1767229 · 1767229
Cosmetics Ingredients Functions
FILM FORMING
InChI
1S/C8H18O3Si/c1-5-9-12(8-4,10-6-2)11-7-3/h8H,4-7H2,1-3H3
InChIKey
FWDBOZPQNFPOLF-UHFFFAOYSA-N
SMILES
CCO[Si](OCC)(OCC)C=C
CAS DataBase Reference
78 · 78-08-0(CAS DataBase Reference)
EWG's Food Scores
1 · 1
FDA UNII
8 V1TKX755V · 8V1TKX755V
NIST Chemistry Reference
Silane, ethenyltriethoxy-(78-08-0)
EPA Substance Registry System
Silane, ethenyltriethoxy- (78-08-0)
UNSPSC Code
12352103 · 12352103
NACRES
23 · NA.23
Symbol(GHS)
2 · GHS02,GHS07
Signal word
Warning
Hazard statements
315 · H315-H319-H226
Precautionary statements
501 · P501-P240-P210-P233-P243-P241-P242-P264-P280-P370+P378-P337+P313-P305+P351+P338-P362+P364-P303+P361+P353-P332+P313-P403+P235
target organs
Respiratory system
PPE
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
Hazard Codes
Xi
Risk Statements
10 · 10-36/37
Safety Statements
26 · 26-36
RIDADR
1993 · UN 1993 3/PG 3
WGK Germany
2 · 2
RTECS
6700000 · VV6700000
F
21 · 21
Autoignition Temperature
265 °C · 265 °C
TSCA
TSCA listed
HazardClass
3 · 3
PackingGroup
III
HS Code
29310095 · 29310095
Storage Class
3 · 3 - Flammable liquids
Hazard Classifications
2 Flam · Eye Irrit. 2Flam. Liq. 3STOT SE 3
Toxicity
50 orally · LD50 orally in Rabbit: 7280 mg/kg LD50 dermal Rabbit 9100 mg/kg
REACH Registrations
Active
Limited Quantities
5 L · 5.0 L (1.3 gallons) (liquid)
Excepted Quantities
Max Inner Pack (30g or 30ml) and Max Outer Pack (1Kg or 1L)
Protective Action Criteria (PAC) · 3 items

2.6 [ppm]

29 [ppm]

170 [ppm]

Toxicology

Toxicity DataLCLo (rat) = 4,000 ppm/4hr

Safety data

F
21
PPE
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
wgk
2
tsca
TSCA listed
rtecs
VV6700000
ridadr
UN 1993 3/PG 3
hs_code
29310095
Toxicity
LD50 orally in Rabbit: 7280 mg/kg LD50 dermal Rabbit 9100 mg/kg
risk_code
10-36/37
Signal word
Warning
Symbol(GHS)
GHS02,GHS07
hazard_code
Xi
safety_code
26-36
hazard_class
3
Storage Class
3 - Flammable liquids
packing_group
III
target organs
Respiratory system
Hazard statements
H315-H319-H226
Limited Quantities
5.0 L (1.3 gallons) (liquid)
Excepted Quantities
Max Inner Pack (30g or 30ml) and Max Outer Pack (1Kg or 1L)
REACH Registrations
Active
Hazard Classifications
Eye Irrit. 2Flam. Liq. 3STOT SE 3
Autoignition Temperature
265 °C
Precautionary statements
P501-P240-P210-P233-P243-P241-P242-P264-P280-P370+P378-P337+P313-P305+P351+P338-P362+P364-P303+P361+P353-P332+P313-P403+P235

UsesVinyltriethoxysilane is used as an adhesive for glass slides. It acts as a coupling agent on inorganic substances blended into polymers that function as adhesion promoters, crosslinkers, and surface modifiers. Further, it is used to prepare polymers.

General DescriptionTriethoxyvinylsilane(TEVS) is a silane coupling agent and an adhesion promoter which can be used for cross-linking and for providing an insulating layer with good mechanical and thermal properties.

Upstream & downstream products

Upstream raw materials

EthanolTrichlorovinylsilane

Downstream products

2-(DIPHENYLPHOSPHINO)ETHYLTRIETHOXYSILANE4-FluorostyreneVinyl tris(2-methoxyethoxy) silane4,4'-VINYLIDENEBIS(N,N-DIMETHYLANILINE)2-FluorostyreneNonafluorohexyltriethoxysilane