Silver mesylate
Basic information
- CAS
2386-52-9- Standard SMILES
CS(=O)(=O)O.[Ag]- InChIKey
GTBQRHOYAUGRPV-UHFFFAOYSA-N- Molecular formula
- CH4AgO3S
- Average molar mass
- 203.98 g/mol
- Monoisotopic mass
- 202.89321
Names & identifiers
- Preferred name
- Silver mesylate
- IUPAC
- methanesulfonic acid;silver
- English name
- Silver mesylate
- Molecular formula
- CH3AgO3S
- Molecular weight
- 202.97
Names & synonyms
Silver mesylatemethanesulfonic acid silverNCI60_041828SCHEMBL564772Silver methanesulfonate, 98%Methanesulfonic acid silver saltCHEMBL1996983NSC83223NSC-83223WLN: WS1&O &-AG- &9/5WS-03235CS-0035248
Show more names
SMSSILVER METHANESULFONATEMRSRSPMSYSilver Mesylate 99%Silver methylsulfonatesilver methanesulphonatemethanesulfonylacidsilverSilver(I) methanesulfonate
Database identifiers
- CAS
2386-52-9- PubChem CID
- 6712944
- ChEMBL
CHEMBL1996983
Properties
Computed structural properties
- Topological polar surface area
- 62.8 Ų
- Hydrogen bond donors
- 1
- Hydrogen bond acceptors
- 3
- Rotatable bonds
- 0
- Heavy atoms
- 6
- Formal charge
- 0
- Complexity
- 92.6
Physicochemical properties
- Melting point
- 252 · 252-256 °C (lit.)
- Density
- 1.405 at · 1.405 at 20℃
- storage temp.
- Keep in dark place,Inert atmosphere,Room temperature
- form
- Powder
- color
- White to beige or light gray
- PH
- 1 at · 1 at 20℃ and 10g/L
- Water Solubility
- Soluble in water, alcohol, ether and benzene. Slightly soluble in toluene, o-chlorotoluene and ethyl disulfide. Insoluble in hexane and methylcyclopentane.
- Sensitive
- Light Sensitive
- InChI
- InChI=1S/CH4O3S.Ag/c1-5(2,3)4;/h1H3,(H,2,3,4);/q;+1/p-1
- InChIKey
- MLKQJVFHEUORBO-UHFFFAOYSA-M
- SMILES
- S([O-])(=O)(=O)C.[Ag+]
- Surface tension
- 77.8 mN/m · 77.8mN/m at 1g/L and 20℃
- Dissociation constant
- 1.9 at · 1.9 at 20℃
- CAS DataBase Reference
- 2386 · 2386-52-9(CAS DataBase Reference)
- EPA Substance Registry System
Safety & regulation
Safety information is for reference only and does not replace the supplier’s Safety Data Sheet (SDS), applicable regulations, or professional assessment.
Safety data
- PPE
- dust mask type N95 (US), Eyeshields, Gloves
- wgk
- 3
- tsca
- TSCA listed
- rtecs
- PB2685000
- ridadr
- 1759
- hs_code
- 28432900
- risk_code
- 36/37/38-20/21/22
- Signal word
- Warning
- Symbol(GHS)
- GHS07
- hazard_code
- Xi,Xn
- safety_code
- 26-36-36/37/39-22
- hazard_class
- 8
- Storage Class
- 11 - Combustible Solids
- packing_group
- III
- target organs
- Respiratory system
- Hazard statements
- H315-H319-H335
- REACH Registrations
- Active
- Hazard Classifications
- Eye Irrit. 2Skin Irrit. 2STOT SE 3
- Precautionary statements
- P261-P264-P271-P280-P302+P352-P305+P351+P338
Chemistry & industry
Applications
UsesSilver methanesulfonate is used as a catalyst for heterocyclization reactions. Further, it is used in the synthesis of unsaturated ketones and esters.
UsesGold Catalysts—21st Century'Gold Rush' Catalyst for: .Heterocyclization reactions . CO2-mediated rearrangement of propargyl alcohols for the synthesis of a,-unsaturated ketones and esters
Upstream & downstream products
Upstream raw materials
Downstream products
Related reactions
0 records
No reaction records under the current filter.
Compound notes
Loading…