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Beryllium carbide

HCID 68173
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Basic informationNames & identifiersPropertiesSafety & regulationChemistry & industryRelated reactionsCompound notes
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Basic information

CAS
506-66-1
Standard SMILES
[Be]=[C]=[Be]
InChIKey
UQVOJETYKFAIRZ-UHFFFAOYSA-N
Molecular formula
CBe2
Average molar mass
30.035 g/mol
Monoisotopic mass
30.024366

Names & identifiers

Preferred name
Beryllium carbide
English name
Beryllium carbide
Molecular formula
C2Be
Molecular weight
33.033582

Names & synonyms

Beryllium carbide506-66-1Beryllium carbide (Be2C)Beryllium acetylideUNII-F5D2F26ONXEINECS 208-050-7F5D2F26ONXDTXSID6060137SCHEMBL29354122NS00125761Q411605Beryllium dicarbide
Show more names
1,3-DiberyllapropadieneMethanetetrayldiberyllium

Database identifiers

CAS
506-66-1
PubChem CID
68173
DTXSID
DTXSID6060137
EC Number
208-050-7
Nikkaji
J358.696K

Properties

Computed structural properties

Topological polar surface area
0 Ų
Hydrogen bond donors
0
Hydrogen bond acceptors
0
Rotatable bonds
0
Heavy atoms
3
Formal charge
0
Complexity
18.3

Experimental & physicochemical properties

Chemical ClassesMetals -> Beryllium Compounds, Inorganic
Physical DescriptionBrick-red or yellow-red solid; [Merck Index] Yellow odorless powder; [MSDSonline]

Physicochemical properties

Melting point
2100 ℃ · decomposes at >2100℃ [MER06]
Density
1.9 · 1.90
solubility
2 O · reacts with H2O
form
red cubic crystals
color
red cubic crystals, crystalline
Water Solubility
2 O; · decomposed very slowly by H2O; hydrolysis yields methane and beryllium hydroxide [KIR78] [MER06]
Thermal Conductivity
23.43 W/ · 23.43 W/(m·K)
Crystal Structure
Cubic
CAS DataBase Reference
506 · 506-66-1
FDA UNII
5 D2F26ONX · F5D2F26ONX
EPA Substance Registry System

Safety & regulation

Safety information is for reference only and does not replace the supplier’s Safety Data Sheet (SDS), applicable regulations, or professional assessment.

Hazard information

Hazards Summary · 1 item

Hydrolyzes at room temperature into beryllium oxide and methane; [Ullmann] Produces flammable gases on contact with water; An irritant; May cause skin sensitization; Repeated or prolonged exposure may cause chronic beryllium disease; [MSDSonline] See CARBIDES. See Beryllium for one additional linked occupational disease.

Safety & protection

Threshold Limit Values (TLV)0.00005 [mg/m3], as Be, inhalable fraction
Permissible Exposure Limit (PEL)0.002 [mg/m3], as Be, Ceiling(OSHA) = 0.005 mg/m3, as Be(0.025 mg/m3,as Be,for 30 min.peak per 8-hr shift)
Immediately Dangerous to Life or Health (IDLH)4.0 [mg/m3], as Be

Toxicology

Adverse EffectsFibrogenic - Inducing tissue injury and fibrosis (scarring).

Safety data

tsca
TSCA listed
ridadr
1566
hazard_class
6.1(b)
packing_group
III

Chemistry & industry

Uses & manufacturing

UsesUsed in nuclear reactor cores; [Merck Index]
General Manufacturing InformationBeryllium carbide (Be2C): INACTIVE
Applications · 3 items

UsesBeryllium acetylide is used in a nuclear reactor as core material,Nuclear reactor core material: Schwartz.

UsesNuclear reactor core material: Schwartz, US 3170812 (1965 to USAEC).

UsesBeryllium carbide (Be2C) is used for the cores in nuclear reactors.

Preparation methods · 1 item

PreparationBeryllium carbide is prepared by heating the elements beryllium and carbon at elevated temperatures (above 900°C). It also may be prepared by reduction of beryllium oxide with carbon at a temperature above 1,500°C: 2BeO + 3C → (1500℃)→ Be2C + 2CO Beryllium carbide decomposes very slowly in water: Be2C + 2H2O → 2BeO + CH4 The rate of decomposition is faster in mineral acids with evolution of methane. However, in hot concentrated alkalies the reaction is very rapid, forming alkali metal beryllate and methane: Be2C + 4NaOH → 2Na2BeO2 + CH4

Upstream & downstream products

Upstream raw materials

BerylliumGraphiteAcetylene black

Suppliers2 total

Shaanxi Didu New Materials Co. Ltd

Related reactions

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Compound notes

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On this pageBasic informationNames & identifiersPropertiesSafety & regulationChemistry & industryRelated reactionsCompound notes
Beryllium carbide (Be2C) (506-66-1)
RIDADR
1566 · 1566
TSCA
TSCA listed
HazardClass
6.1 · 6.1(b)
PackingGroup
III
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