CAS 627-37-2 N-Methylallylamine (HCID 69391)

Names & identifiers

Preferred name: N-Methylallylamine
IUPAC: N-methylprop-2-en-1-amine
English name: N-Allylmethylamine
Molecular formula: C4H9N
Molecular weight: 71.12

Names & synonyms

N-MethylallylamineMethylallylamineRefChem:830664210-996-0N-Allylmethylamine627-37-22-Propen-1-amine, N-methyl-N-methylprop-2-en-1-amineAllylmethylamineN-Allyl-N-methylamineN-Methyl-2-propen-1-aminemethyl(prop-2-en-1-yl)amine

Show more names

Methylallylalminen-methyl-allylamin2-Propennylmethylamine

EINECS 210-996-0N-methyl-N-allylamineAllylamine, N-methyl-MFCD00008641allylmethyl amineAllylamine, N-methyl- (7CI,8CI)methyl allyl amineAllyl methyl amine

Database identifiers

CAS: 627-37-2
PubChem CID: 69391
DTXSID: DTXSID8073219
ChEMBL: CHEMBL3558338
UNII: JXA5N62PYD
EC Number: 210-996-0
Nikkaji: J514B

Properties

Computed structural properties

XLogP: 0.4
Topological polar surface area: 12 Å²
Hydrogen bond donors: 1
Hydrogen bond acceptors: 1
Rotatable bonds: 2
Heavy atoms: 5
Formal charge: 0
Complexity: 24.8

Experimental & physicochemical properties

SpringerMaterials PropertiesCoriolis coupling

Physicochemical properties

Boiling point: 64 · 64-66 °C(lit.)
Density: 0.741 g/mL · 0.741 g/mL at 25 °C(lit.)
refractive index: 20 · n20/D 1.412(lit.)
Flash point: 19 °F · −19 °F
storage temp.: 2 · 2-8°C
pka: 9.88 · 9.88±0.10(Predicted)
form: liquid
color: Clear, pale yellow
Water Solubility: Miscible with water.
BRN: 1098387 · 1098387
InChI: InChI=1S/C4H9N/c1-3-4-5-2/h3,5H,1,4H2,2H3
InChIKey: IOXXVNYDGIXMIP-UHFFFAOYSA-N
SMILES: C(NC)C=C
EWG's Food Scores: 1 · 1
NIST Chemistry Reference: 2 · CH2=CHCH2NHCH3(627-37-2)
EPA Substance Registry System: 2 · 2-Propen-1-amine, N-methyl- (627-37-2)
UNSPSC Code: 12352100 · 12352100
NACRES: 22 · NA.22
Symbol(GHS): 2 · GHS02,GHS05,GHS06
Signal word: Danger
Hazard statements: 225 · H225-H301+H311+H331-H314
Precautionary statements: 210 · P210-P233-P280-P303+P361+P353-P304+P340+P310-P305+P351+P338
PPE: Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
Hazard Codes: F,T
Risk Statements: 11 · 11-23/24/25-34
Safety Statements: 26 · 26-36/37/39-45-37/39
RIDADR: 3286 · UN 3286 3/PG 2
WGK Germany: 3 · 3
RTECS: 6632500 · UC6632500
F: 9 · 9-34
HazardClass: 3 · 3
PackingGroup: II
HS Code: 29211990 · 29211990
Storage Class: 3 · 3 - Flammable liquids
Hazard Classifications: 3 OralFlam · Acute Tox. 3 OralFlam. Liq. 2Skin Corr. 1B
Limited Quantities: 1 L · 1.0 L (0.3 gallon) (liquid)
Excepted Quantities: Max Inner Pack (30g or 30ml) and Max Outer Pack (500g or 500ml)

Safety & regulation

GHS classification

GHS Classification · 4 items

Danger

H225 (100%): Highly Flammable liquid and vapor [Danger Flammable liquids]

P210, P233, P240, P241, P242, P243, P260, P261, P262, P264, P270, P271, P280, P301+P316, P301+P330+P331, P302+P352, P302+P361+P354, P303+P361+P353, P304+P340, P305+P354+P338, P316, P321, P330, P361+P364, P363, P370+P378, P403+P233, P403+P235, P405, and P501 (click each P-code to see the statement)

Aggregated GHS information provided per 47 reports by companies from 3 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.

Hazard information

Hazard Classes and CategoriesFlam. Liq. 2 (100%)

Safety data

F: 9-34
PPE: Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
wgk: 3
rtecs: UC6632500
ridadr: UN 3286 3/PG 2
hs_code: 29211990
risk_code: 11-23/24/25-34
Signal word: Danger
Symbol(GHS): GHS02,GHS05,GHS06
hazard_code: F,T
safety_code: 26-36/37/39-45-37/39
hazard_class: 3
Storage Class: 3 - Flammable liquids
packing_group: II
Hazard statements: H225-H301+H311+H331-H314
Limited Quantities: 1.0 L (0.3 gallon) (liquid)
Excepted Quantities: Max Inner Pack (30g or 30ml) and Max Outer Pack (500g or 500ml)
Hazard Classifications: Acute Tox. 3 OralFlam. Liq. 2Skin Corr. 1B
Precautionary statements: P210-P233-P280-P303+P361+P353-P304+P340+P310-P305+P351+P338

Chemistry & industry

Applications · 1 item

UsesN-Allylmethylamine is used in the production of N-allyl-alfa,alfa-dichloro-N-methylacetamide. It is used as a functional monomer to coordinate with Cd(II)/Zn(II) ions to get the poly methyl methacrylate -butyl methacrylate - N-allylmethylamine (PMBA) films, which is useful as building blocks to fabricate a photo-catalytic cell.